Question

The equilibrium constant, K. for the following reaction is 2.20x104 at 723K 2NH3(8) N2(g) + 3H2(8) If an equilibrium mixture
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Answer:

Step 1: Explanation

Kp is the equilibrium constant calculated from the partial pressures of a reaction equation. It is used to express the relationship between product pressures and reactant pressures

Step 2: Write the balanced the chemical equation

, 2NH3 (g) <--------------> N2(g) + 3H2(g)

Given, PNH3  = 0.693 atm , PN2 = 1.02 atm , PH2 = we need to calculate

Step 3: Calculation of KP

2NH3 (g) <--------------> N2(g) + 3H2(g)

we know, The Kp expression can be written as

Kp = ( P3H2 × PN2 ) / P2NH3  

on substituting the values of partial pressure and Kp = 2.20  × 104

=> 2.20  × 104 = ( P3H2 × 1.02) / (0.693 )2

=> P3H2 = ( 2.20  × 104 × (0.693 )2  ) / 1.02 = 10358.31176

=>  PH2 = ∛10358.33176 = 21.8 atm [ note:  if Kp = 2.20  × 104 then PH2 = 21.8 atm ]

[ note: if Kp = 2.20  × 10-4 then PH2 = 0.047 atm ]

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