Question

1. (15 pts.) Give the organic product(s) for than one product is possible on c). a) (2 pts.) Telllon 1 HUMEWORK #7 Chp. 9 Due Oct. 29, 2019 by 2:50 PM!!! nic product(s) for the following reactions (place answer on the line). More НО- b) (2 pts.) OH AICI: D -CO,H HNO; H2SO4 c) (3 pts.) AICI: d) (2 pts.) ON H2SO4 e) (2 pts.) NH2 f) (2 pts.) g) (2 pts.)

Answer 1

a) This is fridal crafts acylation reaction in this reaction hydroxy group is ortho-para directing group here para position already blocked so we will get Ortho substituted product.

ار Ho HO- AlCl3 NO2 ΗΛΙΟ 3 IcooH O-COOH H₂SO4 c om a proto sentet Alclz H2SO4 -S0gH NH2 C12 Pecla By Bra NC OOH Ne olOH febra Coo M004 * Hooc

b) This nitration reaction of Benzoic acid, acid functionality is meta directing so we will get m-nitrobenzoic acid.

c) This is fridal crafts alkylation reaction here isopropanol group is ortho-para directing group so we will get Ortho and para substituted products.

d) This sulphonation reaction of nitrobenzene, here nitro group is meta directing group so we will get meta substituted product.

e) Here amine is ortho-para directing group but para position already blocked so we will get ortho substituted product.

f) Here hydroxy group is ortho-para para directing but para position is already blocked so we will get ortho substituted product.

g) KMnO4 will oxidise primary, secondary and tertiary carbon to get acid functional group. So we have one secondary and one tertiary carbon which will get oxidised while quaternary carbon will be unreacted.