Consider four beakers labeled A, B, C, and D, each containing an aqueous solution and a solid piece of metal. Identity the beakers in which a chemical reaction will occur and those in which no reaction will occur.
Calculate the standard free-energy change at 25 ∘C for the following reaction:
Mg2+(aq) + Zn(s) → Mg(s) + Zn2+(aq)
Express your answer to three significant figures and in units of kJ/mol.
Which of the following redox reactions do you expect to occur spontaneously in the forward direction under standard conditions?
Check all that apply.
Group of answer choices
Ni(s)+Zn2+(aq)→Ni2+(aq)+Zn(s)
Pb(s)+Mn2+(aq)→Pb2+(aq)+Mn(s)
Ni(s)+Pb2+(aq)→Ni2+(aq)+Pb(s)
Cr(s)+3Ag+(aq)→Cr3+(aq)+3Ag(s)
None of the above
Solution:
1) Mn (s) + CaCl2 (aq) = No reaction
Mn can not displace Cl2 from aqueous solution of CaCl2 becuse Mn is weaker reducing agent than Mn.
2) KCl (aq) + Fe (s) = No reaction
Fe can not be able to displace Cl from KCl because Fe is weaker reducing agent than K.
3) 2AgCl (s) + Cu (s) = CuCl2 (aq) + 2Ag (s)
The reaction is single displacement reaction.It is feasible because Cu is stronger reducing agent than Ag.
4) 2Cr (s) + 6HCl (aq) = 2CrCl3 (aq) + 3H2 (g)
This is an example of single displacement reaction. Feasiblity of reaction is due to stronger reducing capacity of Cr than H.
Consider four beakers labeled A, B, C, and D, each containing an aqueous solution and a...
Calculate the standard cell potential and determine if the reaction is spontaneous in the forward direction(as written). Identify each oxidizing agent and reducing agent. Ni (s) + Zn2+(aq) ----> Ni2+(aq) + Zn (s) Ni (s) + Pb2+(aq) -------> Ni2+(aq) + Pb (s) Al (s) + 3 Ag+(aq) ---------> Al3+(aq) + Ag (s) Pb (s) + Mn2+(aq) ----------> Pb2+(aq) + Mn (s)
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
Part A Which of the following redox reactions do you expect to occur spontaneously in the fowd dreetiont Check all that apply. O Cd2+ (aq) +Co(a)-Co2+ (aq) +Cd(a) O Fe+ (aq)+Zn(s)-+Fe (s) + Zn2+ (aq) O Cr(s)+3Ag (aq)Cr3 (aq) + 3Ag(s) O Fe (aq) +Cd(a)-+Fe(s) + Cd2+ (aq) Request Answer Submit ovide Feedback
Step 1: Determine whether or not each redox reaction occurs spontaneously in the forward direction using only the relative postion of the half reactions on table 18.1. (No numbers in this step.) Step 2: Then, calculate the voltage of each of the reactions. (a) Ca2+(aq) + Zn(s) Ca(s) + Zn2+(aq) (b) 2Ag+(aq) + Ni(s) 2Ag(s) + Ni2+(aq) (c) Fe(s) + Mn2+ Fe2+(aq) Mn(s)
Using the activity series, select all REDOX REACTIONS that should occur A) Mn(s) + Ni2+(aq) --> Ni(s) + Mn2 (aq) B) 2Ag(s)+ Fe2+(aq) --> Fe(s) + 2Ag (aq) C) Ni(s) + Mn2t(aq) --> Mn(s) + Ni2 (aq) D) Sn(s) + Fe2+(aq) --> Fe(s) + Sn2 (aq) E) Zn(s) + Cu2 (aq)-> Cu(s) + Zn2 (aq) F) Fe(s)+Sn2 (aq) --> Sn(s) + Fe2 (aq)
21) Which of these species is the strongest reducing agent? Given Standard Reduction Potentials Mg2+ (g)+2eMg (s) 2.37v Zn2+ (g) +2e Zn (s) 0.76 v Cr3 (aq) +3e Cr (s) E0.73 v Mn2+ (aq) + 3e-→ Mn (s) E。=-1.18 V A. Cr C. Mn D. Zn E. None of These
Use the tabulated electrode potentials to calculate K for the oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g) Express your answer using two significant figures. Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V) Half-reaction E∘ (V) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) −0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) −0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) −0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) −0.76 Cu2+(aq)+2e−→Cu(s) 0.34 Mn2+(aq)+2e−→Mn(s) −1.18 2H+(aq)+2e−→H2(g) 0.00 Al3+(aq)+3e−→Al(s) −1.66 Fe3+(aq)+3e−→Fe(s) −0.036 Mg2+(aq)+2e−→Mg(s) −2.37 Pb2+(aq)+2e−→Pb(s) −0.13 Na+(aq)+e−→Na(s) −2.71 Sn2+(aq)+2e−→Sn(s) −0.14 Ca2+(aq)+2e−→Ca(s) −2.76 Ni2+(aq)+2e−→Ni(s) −0.23 Ba2+(aq)+2e−→Ba(s) −2.90 Co2+(aq)+2e−→Co(s) −0.28 K+(aq)+e−→K(s) −2.92 Cd2+(aq)+2e−→Cd(s)...
help with these please, the standard reduction are provided in the last three pictures What is the calculated value of the cell potential at 298K for an electrochemical cell with the following reaction, when the Pb2+ concentration is 9.05X10 M and the AP concentration is 1.48 M? 3Pb2+(aq) + 2Al(s) 3Pb(s) + 2A13+ (aq) Answer: The cell reaction as written above is spontaneous for the concentrations given: What is the calculated value of the cell potential at 298K for an...
1. which of the following is the strongest oxidizing agent? (in an acidic solution) (pick one) PbO2(s) Mg(s) Ba2+(aq) NO3-(aq) MnO2(s) 2. what element is being oxidized in the following redox reaction? Co2+(aq)+NH4+(aq)=Co(s)+NO3-(aq) Choices are: O,N,Co,Xe, or H 3. which of the following reactant pairs would result in a spontaneous redox reaction? (pick one) Al(s)+Pb2+(aq) Pb(s)+Mn2+(aq) Ni(s)+Zn2+(aq) Ag(s)+Ni2+(aq)
4. (a) Use the standard reduction potentials at 25° C in Table 18.1 in Tro, Fridgen and Shaw, and calculate the standard emf E° of an electrochemical cell described by the following reaction: 3 Zn + 2 Cr3+ + 2 Cr + 3 Zn? (b) What is n? (c) What is AGº for this reaction at 25°? (d) What is the equilibrium constant for this reaction at 25°? TABLE 18.1 Standard Reduction Potentials at 25°C EV) 2.87 1.61 1.51 1.36...