Question

Consider four beakers labeled A, B, C, and D, each containing an aqueous solution and a...

Consider four beakers labeled A, B, C, and D, each containing an aqueous solution and a solid piece of metal. Identity the beakers in which a chemical reaction will occur and those in which no reaction will occur.

  1. Mn(s)+CaCl2(aq)                            [ Select ]                       ["Reaction", "No reaction"]      
  2. KCl(aq)+Fe(s)                            [ Select ]                       ["Reaction", "No reaction"]      
  3. AgCl(aq)+Cu(s)                            [ Select ]                       ["Reaction", "No reaction"]      
  4. Cr(s)+HCl(aq)                            [ Select ]                       ["Reaction", "No reaction"]
  5.      

Calculate the standard free-energy change at 25 C for the following reaction:

Mg2+(aq) + Zn(s) → Mg(s) + Zn2+(aq)

Express your answer to three significant figures and in units of kJ/mol.

Which of the following redox reactions do you expect to occur spontaneously in the forward direction under standard conditions?

Check all that apply.

Group of answer choices

Ni(s)+Zn2+(aq)→Ni2+(aq)+Zn(s)

Pb(s)+Mn2+(aq)→Pb2+(aq)+Mn(s)

Ni(s)+Pb2+(aq)→Ni2+(aq)+Pb(s)

Cr(s)+3Ag+(aq)→Cr3+(aq)+3Ag(s)

None of the above

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Answer #1

Solution:

1) Mn (s) + CaCl2 (aq) = No reaction

Mn can not displace Cl2 from aqueous solution of CaCl2 becuse Mn is weaker reducing agent than Mn.

2) KCl (aq) + Fe (s) = No reaction

Fe can not be able to displace Cl from KCl because Fe is weaker reducing agent than K.

3) 2AgCl (s) + Cu (s) = CuCl2 (aq) + 2Ag (s)

The reaction is single displacement reaction.It is feasible because Cu is stronger reducing agent than Ag.

4) 2Cr (s) + 6HCl (aq) = 2CrCl3 (aq) + 3H2 (g)

This is an example of single displacement reaction. Feasiblity of reaction is due to stronger reducing capacity of Cr than H.

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