Ans 7.76 :
Part A :
Mol Al = mass / molar mass
= 25.0 g / 26.98 g/mol = 0.926 mol
4 mol Al makes 2 mol Al2O3
so 0.926 mol Al will form : 0.926 mol /2 = 0.463 mol Al2O3
then mass of Al2O3 produced = mol x molar mass
= 0.463 mol x 101.96 g/mol
= 47.2 g
Part B :
Mol O2 = mass / molar mass
= 25.0 g / 31.999 g/mol = 0.781 mol
3 mol O2 needs 2 mol Al
so 0.781 mol O2 will need : (0.781 mol x 2 mol) / 3 mol = 1.04 mol Al
but here only 0.926 mol Al is present , so Al is limiting reagent
so here again mass of Al2O3 produced will be 47.2 g
Part E : NO2
Mol NO2 = mass / molar mass
= 25.0 g / 46.0055 g/mol = 0.543 mol
Mol H2O = 25.0 g / 18.01528 g/mol = 1.39 mol
each mol H2O needs 3 mol NO2 , here NO2 present is less , so limiting reactant here is NO2
Part F :
3 mol NO2 produces 2 mol HNO3
so 0.543 mol NO2 will produce : (0.543 mol x 2 mol) / 3 mol
= 0.362 mol HNO3
mass of HNO3 = mol x molar mass
= 0.362 mol x 63.01 g/mol
= 22.8 g
Part G : O2
Mol C2H6O = mass / molar mass
= 25.0 g / 46.07 g/mol = 0.543 mol
Mol O2 = 25.0 g / 31.999 g/mol = 0.781 mol
each mol C2H6O needs 3 mol O2
so 0.543 mol C2H6O will need : 0.543 mol x 3 = 1.6 mol O2
here only 0.781 mol O2 is present , so limiting reactant is : O2
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