The concentration of the Br sample = 0.865 mM = 0.865*10-3 mol/L.
Hence, 1 L of the Br - solution has 0.865*10-3 mol Br.
Atomic mass of Br- = 79.904 g/mol
Therefore, mass of Br- in the sample = (0.865*10-3 mol)*(79.904 g/mol) = 0.0691 g = (0.0691 g)*(1000 mg/1 g) = 69.1 mg.
Density of solution = 1.025 g/mL; therefore, mass of 1 L = 1000 mL of seawater = (1.025 g/mL)*(1000 mL) = 1025 g = (1025 g)*(1 kg/1000 g) = 1.025 kg.
Concentration of Br- in ppm = (milligrams of Br)/(kilograms of seawater) = (69.1 mg)/(1.025 kg) = 67.4 mg/kg = 67.4 ppm (ans)
Ans: (E) 67.4 ppm
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