Given:
V = 66.5 L
n = 36.5 mol
T = 473.0 K
use:
P * V = n*R*T
P * 66.5 L = 36.5 mol* 0.08206 atm.L/mol.K * 473 K
P = 21.3 atm
Answer: 21.3 atm
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