Label each Peak in the NMR (ppm) to the correct location in the morphine molecule present...
Label each peak on your carbon- and proton-NMR; and label only
the principle peaks found in the compound. All peaks are presented
in the 4000-1000 wavenumber range.
Copyright 1994 Proton NMR 60 140 Carbon 13 NMA 120 100 2H 80 MF 8H11 MW 137 %C70.0 EH 8.1 N 10.2 2 PPM 20 PPM
5. a. Attach a copy of your NMR. Label each peak in the NMR with the letter of the equivalent hydrogen(s) it represents in your product (see diagram below). b. Which peak(s) are present in the NMR that are due only to the product and not the reactant? (6) А CH, Hoc CH CH B с CH O 4- c B CH HyC CH CH, A BRE 1010 1800 5.92 209 12 10 6 16 PPM USER DATE: 07/29/16-02)
Predicting the Spectrum MR and C NMR) the expected 'H NMR number of si spectrum for the following molecule. Be sure to include appropriate for the following molecule. Be sure to er of signals, show spisina ar try to indicate relative Integration by arca un (label peak with some splitting and try to indicate relative Integration by area under peak peak with correct number for clarity in tabel all the unique hydrogens with letters and assign them to the peaks...
5. The 'H NMR spectrum of 2-bromo-1-ethoxy-4-nitrobenzene is shown below, and the peak list has been assembled in the table. In the structure of the product, each proton has been labeled with a letter. NO2 6 (ppm) H NMR spectrum of 2-bromo-1-ethoxy-4-nitrobenzene Proton(s) in Peak FrequencyPeak Multiplicity Peak Integration Number of Protons s, d, etc t, J- 7.0 Hz q, J 7.0 Hz dd, J - 8.4, 0.4 Hz dd, J - 8.4, 1.7 Hz dd, J-1.7, 0.4 Hz Molecule...
Page - 8 - of 9 B Solvent • ppm 8A) MATCH the proton (1H) NMR spectrum above to the CORRECT molecule (1, 2, 3, or 4). 8B) In the table below, ASSIGN each signal in the spectrum to the corresponding hydrogen atom(s) in the compounds. Use this format example: 3.0 ppm ЗН singlet (fictitious) -CH SIGNAL ppm (x scale) Integration Splitting Assignment A B с D E
NMR worksheet: H-1 (proton) NMR -COOH کد 11 وه اسط .)= X For each compound: 4. Then try to match the compound to the correct NMR spectrum ! بر ♡ na = = = | ۲۲ OMIT this peak added in error) small broad peak (OH) $ PPM We were unable to transcribe this image
based on 13c nmr find unknown compound and label each peak.
ppm 200 180 160 140 120 80 60 40 20 100 165 160 155 150 145 140 135 130 125 P
I’m
supposed to label each peak with the correct letter but I’m
struggling to understand it. I’m not sure if I’m doing these
correctly. I don’t know how to do the 13C NMR.
Problem K: CHCIO IR: shows stretch at 1740 cm -ester MS: parent ions at 136 and 138; base peak at 101; abundant peaks at 91 and 93 'H NMR 3 H 2 H 2H 2 H PPM PC NMR 180 160 140 120 100 PPM 80 60...
(4 pts) Factoring in the spin-spin coupling, draw the expected NMR spectrum of the methyl protons (H* and H) of the propane molecule in this sample. Assume that the coupling constant (J) of the proton H* or H' by Hy is 0.01 ppm. Label each peak with its chemical shift value and specify their relative peak area. d.
the
first photo has the questions, the second are the H-nmr, C-nmr, and
IR.
6. 'H-NMR spectrum On the proton spectrum, interpretate ACTUAL 1H-NMR data, detailing chemical shifts, integrations, and splittings. Draw the structure of the unknown compound and label hydrogens (a, b, orc, etc...) for which signals. 7. 13C-NMR spectrum Draw the structure of your molecule and label carbons (a, b, or c, etc...) are responsible for which signals. 8. IR spectrum • Draw the structure of your molecule...