In class we solved the quantum harmonic oscillator problem for a diatomic molecule. As part of...
In the lecture notes, we only solved the TISE for the quantum harmonic oscillator 1 Now, write down the actual solution of the wavefunction of the quantum harmonic oscillator, i.e. the solution that solves TDSE not TISE. 2. We consider the Quantum Harmonic Oscillator In Heisenberg Picture: (a) Hamiltonian to use is the quantum harmonic oscillator Hamiltonian Solve the Heisenberg equations of motion for the operators X (t) and P(t) where the Calculate the commutator [X(t), X (0)] and show...
We study the vibrations in a diatomic molecule with the reduced mass m. Let x = R − Re, which is the bonding distance deviation from equilibrium distance. Hamiltonian operator consist of two parts: H = H(0) + H(1), where H(0) is the Hamiltonian operator to a harmonic oscillator with force constant k, and H(1) = λx3 (λ is a constant < 0). * Calculate the first order correction to the energy state v.
6 The Fermionic Oscillator Suppose that we constructed a harmonic oscillator Hamiltonian H in terms of raising and lowering operators a+,a in the usual way, such that but now whereaa obey the anticommutation relationn (Be careful! The a+,a are operators, rather than numbers.) (a) Suppose I give you a wavefunction that solves the time-independent Schrödinger equation, i.e. such that HUn-EUn-hw (n + ) ψη. Is a+Un also a solution to the time-independent Schrödinger equation If so, what is its energy...
3 Problem Three [10 points] (The Quantum Oscillator) We have seen in class that the Hamiltonian of a particle of a simple Harmonic oscillator potential in one dimension can be expressed in term of the creation and annihilation operators àt and à, respectively, as: or with In >, n = 0,1,..) are the nth eigenstates of the above Hamiltonian. Part A A.1. Show that the energy levels of a simple harmonic oscillator are E,' Aw (nti), n=0, 12, A.2. Calculate...
3. The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator. Because an arbitrary potential can usually be approximated as a harmonic potential at the vicinity of a stable equilibrium point, it is one of the most important model systems in quantum mechanics. Consider an electron trapped by a one-dimensional harmonic potential V(x)=-5 mo?x” (where m is the electron mass, o is a constant angular frequency). In this case, the Schrödinger equation takes the following form, **...
2. [10 points] For a Simple Harmonic Oscillator: a) Draw ψ(x) and ψ2(x) for the u, and v-6 states. Make sure to include as much detail as possible. b) Show that 2(3) is normalized. 3. [5] A certain non-halogen diatomic molecule was found to have a force constant of 99 N/m and an observed vibrational frequency of 162.2 cm1 Determine the identity of the unknown diatomic 4. [10 points) a) What is the difference between commuting and non-commuting operators? What...
Quantum mechanics. A Hamiltonian of the form , is equivalent to the Hamiltonian of a harmonic oscillator with its equilibrium point displaced where and C are constant, find them. With the previous result, find the exact spectrum of H. Calculate the same spectrum using the theory of disturbances to second order with . Compare your results. Calculate the wave functions up to first order using as a perturbation. P2 22 P2 Tm We were unable to transcribe this imageWe were...
The three-dimensional harmonic oscillator Cartesian wave functions that you found in Prob. 4.46 are simultaneous eigenfunctions of H and parity (i.e., r →-r), but they are not also simultaneous eigenfunctions of L' and Lz. However, we know that it's possible to construct eigenfunctions of H for the 3D harmonic oscillator that are also eigenfunctions of L, Lz, and parity. Combine the Gaussian factors that appear in your Prob. 4.46 eigenfunctions into a function of r that is independent of θ...
4. Let us revisit the shifted harmonic oscillator from problem set 5, but this time through the lens of perturbation theory. The Hamiltonian of the oscillator is given by * 2m + mw?f? + cî, and, as solved for previously, it has eigenenergies of En = hwan + mwra and eigenstates of (0) = N,,,a1 + role of (rc)*/2, where Do = 42 and a=(mw/h) (a) By treating the term cî as a perturbation, show that the first-order correction to...
10) The wave functions obtained by solving the Schrodinger equation for the simple harmonic motion is: v.(E) = A e-y-2/2 (y). Here y = (a)"25, normalization constant A = [(a/ 2/(2" n!)]"2 and n=0, 1, 2, ... are the vibrational quantum numbers. H.(y) is the Hermite polynomial and it is defined as: Hly)= (-1)" ey^2 (d" e-y^2? (dyn J a) Calculate the fourth (i.e. n = 3) wave function, using the above formulas.