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The rate constant for some reaction has the following temperature dependence. a) Determine slope. b) Calculate...
The temperature dependence of the acid-catalysed hydrolysis of penicillin is investigated. This is a first order...
The temperature dependence of the acid-catalysed hydrolysis of penicillin is investigated. This is a first order reaction that only depends on the concentration of the penicillin. The dependence of the rate constant, k, as a function of temperature is given in the following table: Temperature (K) k(s-1) 290 2.9e-5 320 2.61e-4 Determine the activation energy of this reaction. Express your answer in kJ mol-1 to the first decimal place (XX.X). Determine the Arrhenius pre-factor, A for this reaction. Express your...
#14 Rate Constant and Temperature 1. The rate constant (k) for a reaction was measured as...
#14 Rate Constant and Temperature 1. The rate constant (k) for a reaction was measured as a function of temperature. A plot of lnk versus 1/T (in K) is linear and has a slope of -1.01 x 104 K. Calculate the activation energy for this reaction. 2. The rate constant of a reaction at 32.0oC is 0.0550 s-1. If the frequency factor is 1.20 x 1013 s-1, what is the activation energy? 3. A reaction has a rate constant of...
Some reaction has an activation energy of 44 kJ/mol and a rate constant of 4.0 ×...
Some reaction has an activation energy of 44 kJ/mol and a rate constant of 4.0 × 10₋4 s-1 at 37 oC. In the presence of a catalyst, the same reaction has an activation energy of 9.1 kJ/mol. Calculate the rate constant (s-1) of the catalyzed reaction at 37 oC. Enter your answer as an integer.
Suppose that data relating the rate constant and temperature results in a line the slope for...
Suppose that data relating the rate constant and temperature results in a line the slope for the linear form of the Arrhenius equation of -8,177 K, determine the activation energy for the process in kJ/mol. State the number without the unit.
1) Calculate the activation energy in kJ/mol for the following reaction if the rate constant for...
1) Calculate the activation energy in kJ/mol for the following reaction if the rate constant for the reaction increases from 93.5 M-1s-1 at 497.7 K to 1349.3 M-1s-1 at 636.7 K. do not include units, but make sure your answer is in kJ/mol! 2) A chemist constructs a plot of ln k vs. 1/T for a chemical reaction. The slope of the trendline for the data is -746 K. What is the activation energy for this reaction in kJ/mol? R...
The rate of the elementary reaction C2H2 + O2C2H + HO2 has been studied as a...
The rate of the elementary reaction
C2H2 +
O2C2H
+ HO2
has been studied as a function of temperature between
300 and 2500 K. The following
data were obtained for the rate constant k:
Temperature (K)
k (L mol-1 s-1)
300
6.25×10-45
740
1.19×10-12
1180
1.91×10-4
1620
1.07
(a) Calculate the activation energy of this
reaction. kJ mol-1
(b) Calculate the factor A in the Arrhenius equation for the
temperature dependence of the rate constant. L
mol-1 s-1
A reaction has a rate constant of 0.0177 s-1 at 400.0 K. If the reaction has...
A reaction has a rate constant of 0.0177 s-1 at 400.0 K. If the reaction has activation energy of 125 kJ/mol, calculate the rate constant at 500.0 K.A reaction has a rate constant of 0.0177 s-1 at 400.0 K. If the reaction has activation energy of 125 kJ/mol, calculate the rate constant at 500.0 K.
The temperature dependence of the acid-catalysed hydrolysis of penicillin is investigated. This is a first order...
The temperature dependence of the acid-catalysed hydrolysis of penicillin is investigated. This is a first order reaction that only depends on the concentration of the penicillin. The dependence of the rate constant, k, as a function of temperature is given in the following table: Data Temperature Irek (51) - (K) 285 1.42e – 4 316 0.00138 Determine the activation energy of this reaction. Express your answer in kJ mol-' to the first decimal place (XX.X). 55.0 Your last answer was...
Calculate the rate constant at 200.°C for a reaction that has a rate constant of 4.10...
Calculate the rate constant at 200.°C for a reaction that has a rate constant of 4.10 × 10−4 s−1 at 90.°C and an activation energy of 57.3 kJ/mol.
12) The rate of the elementary reaction CS2 + O2 ---> CS + SO2 has been...
12) The rate of the elementary reaction CS2 + O2 ---> CS + SO2 has been studied as a function of temperature between 1500 and 2100 K. The following data were obtained for the rate constant k: Temperature (K) k (L mol-1 s-1) 1500 2.18×104 1620 4.82×104 1740 9.57×104 1860 1.74×105 (a) Calculate the activation energy of this reaction. ___ kJ mol-1 (b) Calculate the factor A in the Arrhenius equation for the temperature dependence of the rate constant. ___...
The temperature dependence of the acid-catalysed hydrolysis of penicillin is investigated. This is a first order reaction that only depends on the concentration of the penicillin. The dependence of the rate constant, k, as a function of temperature is given in the following table: Data Temperature Irek (51) - (K) 285 1.42e – 4 316 0.00138 Determine the activation energy of this reaction. Express your answer in kJ mol-' to the first decimal place (XX.X). 55.0 Your last answer was...
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