1. The following reaction was recently reported along with a proposed catalytic cycle below! co Pd(PPhals...
name the mechanistic step that converts E to D 1. The following reaction was recently reported along with a proposed catalytic cycle below: co Pd(PPha (1 mol %) CsOAC (1.0 equiv.) THF, 60 °C, 16 h NO 3-4 32 examples up to 99% yields .PdL₂1 RL, co NHR Csi Асон CsOC S NHR C
name the mechanistic step that converts D to A 1. The following reaction was recently reported along with a proposed catalytic cycle below: CO Pd(PPhal. (1 mol %) CsOAC (1.0 equiv.) NH (co. THF, 60 °C, 16 h - 32 examples up to 99% yields Pd'LL NHR DOLO CO CsOAC "polli NHRC
what is the role of CsOAc? 0 1. The following reaction was recently reported along with a proposed catalytic cycle below: co Pd(PPhg) (1 mol %) CsOAC (1.0 equiv) THF, 60 °C, 16 h Na 32 examples up to 99% yields , co PdLI NHR ACOH CO2 COAC NHRC
name the mechanistic step that converts B to C 1. The following reaction was recently reported along with a proposed catalytic cycle below: O CO Pd(PPh3)le (1 mol %) CSOAC (1.0 equiv + THF, 60 °C, 16 h NH (Co. R 32 examples up to 99% yields PdL A NHR Co2 L Pg . Pd' L CO -Pd'L2 O NHR E R в D Rv Csl ACOH со CO2 СВОАС NHR C zac
what transformation needs to occur to convert the Pd-catalyst added, Pd(PPh3)4, to the active catalyst A? what number(s) could n equal in Pd0Ln? 0 1. The following reaction was recently reported along with a proposed catalytic cycle below: co Pd(PPhg) (1 mol %) CsOAC (1.0 equiv) THF, 60 °C, 16 h Na 32 examples up to 99% yields , co PdLI NHR ACOH CO2 COAC NHRC