Please show how these complexes be changed in terms of energy level. 1. when pt(II) d8...
Please show how these complexes be changed in terms of energy level.
1. when pt(II) d8 metal ion meets CO ligand
2. when cu(II) d9 metal ion makes complex (maybe Octahedral to D4h
energy level?)
3. when Co(II) d7 metal ion makes [MX4]2- complex
Thanks.
Homework Answers
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Please show how these complexes be changed in terms of
energy level.
1. when pt(II) d8...
1. For each of the following complexes, give the electron configurations of the d-type M Os,...
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
i can't solve this question of coordination chemistry, could someone hlep me please Exercise 1: 1. What kind(s) o...
i
can't solve this question of coordination chemistry, could someone
hlep me please
Exercise 1: 1. What kind(s) of interaction between the ligand and the metal ion is(are) considered in the crystal field approach? 2. Give and justify the degeneracy lifting for a tetrahedral complex. Would it be the same for an octahedral complex? 3. Let us consider hexaaquacopper(II) ion. Justify the elongation of two opposite Cu-O bonds (along z for example) compared to the other four Cu-O bonds using...
What is the coordination number for each of the following complexes or compounds? [Co(NH3)4Cl2]+ [Ca(EDTA)]2− [Pt(NH3)4]2+...
What is the coordination number for each of the following
complexes or compounds?
[Co(NH3)4Cl2]+
[Ca(EDTA)]2−
[Pt(NH3)4]2+
Na[Ag(CN)2]
Enter the coordination numbers, in the order that the complexes
are listed, as four integers separated by commas (e.g.,
1,2,3,4).
What is the charge on each of the following complex ions?
hexaaquairon(II), [Fe(H2O)6]?
tris(carbonato)aluminate(III), [Al(CO3)3]?
amminepentachloroplatinate(IV), [Pt(NH3)Cl5]?
Express the charges numerically, in the order that the complexes
are listed, separated by commas. For a nonzero charge, be sure to
include the sign (e.g.,...
Could you show how to do step by step,please? 2. Consider (Cr((Cl).]": (donor/acceptor) --Cl is a...
Could you show how to do step by step,please?
2. Consider (Cr((Cl).]": (donor/acceptor) --Cl is a strong/weak)-field ligand because of interactions with the metal ion --In this complex, Cr-* is a d ion Therefore, the number of unpaired electrons in Cr((Cl).].is Draw an orbital diagram showing the distribution of electrons: Calculate the spin-only magnetic moment of Cr((Cl).]" (in His units): Calculate (i) the Ligand-Field Stabilization Energy (as a function of Ao), (ii) the Coulombic energy (as a function of II.)...
1) In molecular spectroscopy, the energy of a transition is usually expressed in terms of wavenumbers(cm-1)...
1) In molecular spectroscopy, the energy of a transition is usually expressed in terms of wavenumbers(cm-1) instead of Hertz.(a)Show that 83.6 cm-1 is equivalent to 1 kJ/mol.(b)Calculate the energy (in kJ/mol) of a transition that occurs at 2100 cm-1. 2) Beside using mass spectrometry, suggestone spectroscopic methodfor differentiatingCH3(C=O)CH3(acetone) from CH3CH(OH)CH3 (isopropanol). 3) Octahedral geometry is a common molecular structure in transition metal chemistry. Draw all isomeric forms of six-coordinated (a) MA2B4, and (b) MA3B3 complexes. 4) (i)The [Fe(H2O)6]3+cationic complexis paramagnetic....
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in o...
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in order from least to greatest according ability to split the d orbital energy level. A) CN-, OH, H2O, Br- C) Br,H20, CN-, OH- B) Br., OH, H2O, CN- D) None of the above 25. The charge on the central metal ion in (Cr(NH3)(CO3)2+ is A)-1. B) 0. C) 1. D) 3. E) 5 26....
1. What is the crystal field stabilisation energy (CFSE) of a d5 metal ion in an...
1. What is the crystal field stabilisation energy (CFSE) of a d5 metal ion in an octahedral ligand field surrounded by weak field ligands? +5Dq -20Dq 0Dq -5Dq -20Dq + P 2. The relative ordering of the d orbital energy levels for a complex such as [Cu(H2O)6]2+ which exhibits tetragonal elongation due to the Jahn-Teller Effect is: Group of answer choices xz = yz = xy < x2-y2 = z2 xy < xz = yz < x2-y2 < z2 xz...
Prelab questions 1,2, and 3 and Part E questions Also, write a flowchart of the experiments...
Prelab questions 1,2, and 3 and Part E questions Also, write a flowchart of the experiments process in each part. EXPERIMENT 3 DETERMINATION OF Δo The d orbitals of a metal ion in an octahedral ligand or crystal field are split into a higher energyset (eg) and a lower energy set (t2g) as shown in the following energy level diagram. 11 The energy difference between the upper and lower energy levels is Δo, the octahedral crystal field splitting. The degree...
CHEM 1033, Sample Exam II (Homework) Chapters 3,4,6 Name: 1. What volume of 0.132 M KOH...
CHEM 1033, Sample Exam II (Homework) Chapters 3,4,6 Name: 1. What volume of 0.132 M KOH solution would react completely with 25.8 ml. of 0.198 M HCl according to the following cquation? HCI+KOH --->KCI+H.O a) 86.4 ml. b) 25.7 ml. c) 38.7 ml d) 17.2 ml. 2. Which one of the following is a strong soluble base? a) Ni(OH): b) Mg(OH): c) RLOH d) ChOH) c) Fe(OH) 3. Which one of the following is a strong acid? a) HF b)...
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
i
can't solve this question of coordination chemistry, could someone
hlep me please
Exercise 1: 1. What kind(s) of interaction between the ligand and the metal ion is(are) considered in the crystal field approach? 2. Give and justify the degeneracy lifting for a tetrahedral complex. Would it be the same for an octahedral complex? 3. Let us consider hexaaquacopper(II) ion. Justify the elongation of two opposite Cu-O bonds (along z for example) compared to the other four Cu-O bonds using...
What is the coordination number for each of the following
complexes or compounds?
[Co(NH3)4Cl2]+
[Ca(EDTA)]2−
[Pt(NH3)4]2+
Na[Ag(CN)2]
Enter the coordination numbers, in the order that the complexes
are listed, as four integers separated by commas (e.g.,
1,2,3,4).
What is the charge on each of the following complex ions?
hexaaquairon(II), [Fe(H2O)6]?
tris(carbonato)aluminate(III), [Al(CO3)3]?
amminepentachloroplatinate(IV), [Pt(NH3)Cl5]?
Express the charges numerically, in the order that the complexes
are listed, separated by commas. For a nonzero charge, be sure to
include the sign (e.g.,...
Could you show how to do step by step,please?
2. Consider (Cr((Cl).]": (donor/acceptor) --Cl is a strong/weak)-field ligand because of interactions with the metal ion --In this complex, Cr-* is a d ion Therefore, the number of unpaired electrons in Cr((Cl).].is Draw an orbital diagram showing the distribution of electrons: Calculate the spin-only magnetic moment of Cr((Cl).]" (in His units): Calculate (i) the Ligand-Field Stabilization Energy (as a function of Ao), (ii) the Coulombic energy (as a function of II.)...
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in order from least to greatest according ability to split the d orbital energy level. A) CN-, OH, H2O, Br- C) Br,H20, CN-, OH- B) Br., OH, H2O, CN- D) None of the above 25. The charge on the central metal ion in (Cr(NH3)(CO3)2+ is A)-1. B) 0. C) 1. D) 3. E) 5 26....
CHEM 1033, Sample Exam II (Homework) Chapters 3,4,6 Name: 1. What volume of 0.132 M KOH solution would react completely with 25.8 ml. of 0.198 M HCl according to the following cquation? HCI+KOH --->KCI+H.O a) 86.4 ml. b) 25.7 ml. c) 38.7 ml d) 17.2 ml. 2. Which one of the following is a strong soluble base? a) Ni(OH): b) Mg(OH): c) RLOH d) ChOH) c) Fe(OH) 3. Which one of the following is a strong acid? a) HF b)...
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