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4. Draw the organic product of these reactions. Note that in so some cases, a 2-step...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. HI H) 1) CH3Li CrO3, H2SO4 1) H 2) H30+ H20 (xs) CI mCPBA (CH3)3COK J) (CH3)3COH CHCI2 K) H2SO4, 1800C OH Nah, DMSO...
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH ....
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH . (E2) 1.BH 2. H2O NaOH, HÔ PCC HB/ROOR how many stereoisomers? how many stereoisomers? PCC Excess H2O H CH2C12 HB Nal SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 HO H2SO mCPBA NaOEt (E2) H2SO4 (cat) don't worry about this reaction OH OH KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH Рcc CH2C12 HI (SN1)
Draw the major product and label as SN2, SN1, E2, or E1 7. Draw the major...
Draw the major product and
label as SN2, SN1, E2, or E1
7. Draw the major products of the following reactions, and label the reaction as SN2, SN1, E2 E1. (Darkly shaded bonds are wedged) Br NaOMe NaCN H2SO4 OTs NaSH OTs H20 NaOMe Br KOtBu OH HBr HBr OH
For each of the reactions supply the missing final major product(s) in the boxes provided. Clearly...
For each of the reactions supply the missing final major product(s) in the boxes provided. Clearly show stereochemisty where appropriate. If a reaction produces a mixture of enantiomers draw both. Supply the name of the mechanism (Sn1, Sn2, E1, E2) by which the requested reaction occurs by. NaOH 80 °C, H20 Mechanism ОН HCI 0°C, Ether ОН CrO3 H2SO4
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. Predict the major product (only one product) in each of the following reactions and indicate...
3. Predict the major product (only one product) in each of the
following reactions and indicate the type of mechanism.
3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism Sn2 Sn1 HO HBr moy ng heo 0°C, H2O E2 E1 Mechanism Sn2 Sn1 H2SO4 E2 E1 Mechanism HBr SN2 Sn1 rt, H20 E2 E1 OH
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H ) 1) CH3Li CrO2, H2S04 1) H 2) H30+ H2O (xs) CI mCPBA (CH3)3COK J) (CH3)3COH CH2Cl2 K) H2SO4, 1800C OH NaH,...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Base...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH3)2 (E2)...
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH3)2 (E2) 1. BH3 2. H2O2, NaOH, H2O PCC HBr/ROOR how many stereoisomers? PCC ad Excess H, H CH2Cl2 OT_HBr SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction ОН PCC CH2Cl2 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH PCC CH2Cl2 HI (SN1)
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. HI H) 1) CH3Li CrO3, H2SO4 1) H 2) H30+ H20 (xs) CI mCPBA (CH3)3COK J) (CH3)3COH CHCI2 K) H2SO4, 1800C OH Nah, DMSO...
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH . (E2) 1.BH 2. H2O NaOH, HÔ PCC HB/ROOR how many stereoisomers? how many stereoisomers? PCC Excess H2O H CH2C12 HB Nal SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 HO H2SO mCPBA NaOEt (E2) H2SO4 (cat) don't worry about this reaction OH OH KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH Рcc CH2C12 HI (SN1)
Draw the major product and
label as SN2, SN1, E2, or E1
7. Draw the major products of the following reactions, and label the reaction as SN2, SN1, E2 E1. (Darkly shaded bonds are wedged) Br NaOMe NaCN H2SO4 OTs NaSH OTs H20 NaOMe Br KOtBu OH HBr HBr OH
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. Predict the major product (only one product) in each of the
following reactions and indicate the type of mechanism.
3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism Sn2 Sn1 HO HBr moy ng heo 0°C, H2O E2 E1 Mechanism Sn2 Sn1 H2SO4 E2 E1 Mechanism HBr SN2 Sn1 rt, H20 E2 E1 OH
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H ) 1) CH3Li CrO2, H2S04 1) H 2) H30+ H2O (xs) CI mCPBA (CH3)3COK J) (CH3)3COH CH2Cl2 K) H2SO4, 1800C OH NaH,...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH3)2 (E2) 1. BH3 2. H2O2, NaOH, H2O PCC HBr/ROOR how many stereoisomers? PCC ad Excess H, H CH2Cl2 OT_HBr SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction ОН PCC CH2Cl2 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH PCC CH2Cl2 HI (SN1)
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