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Compounds X and. Y both produce mass spectra in which the M peak appears at m/z122....
An organic compound contains carbon, hydrogen, and two other element(s). Its mass spectrum has M+ peak...
An organic compound contains carbon, hydrogen, and two other element(s). Its mass spectrum has M+ peak at m/z=121 and M+2 peak at m/z=123. Their relative intensities are 3:1. What are the two other elements in the compound?
The molecular weight of a compound is typically indicated by the heaviest peak on a mass...
The molecular weight of a compound is typically indicated by the heaviest peak on a mass spectrum, which i presumed to correspond to the molecular ion (M*). For smaller compounds, the heaviest peak tends to also be the most intense peak. The lighter peaks in the spectrum result from fragmentation of the molecule into smaller ions. Since peak intensity correlates to the relative stability of the ions produced, the peaks of the ionized fragments can be more intense than the...
1) Which compound gives the following spectra? For the 'H-NMR assign all signals. Interpret base peak and mole pea...
1) Which compound gives the following spectra? For the 'H-NMR assign all signals. Interpret base peak and mole peak in the mass spectrum if a mole peak exists. Assign at least two "C signals. How does the IR spectrum support your findings? (12 pts.) 100- Relative Intensity 0- 20 40 60 80 100 140 160 180 200 220 120 m/ 200 180 160 140 120 100 80 60 40 20 0 ppm t6H 9,4H 11H d, 2 H 9 8...
Problem 12-10 Ethers are not easily differentiated by their infrared spectra, but they tend to form...
Problem 12-10 Ethers are not easily differentiated by their infrared spectra, but they tend to form predictable fragments in the mass spectrum. The following compounds give similar but distinctive mass spectra. VO butyl isopropyl ether butyl propyl ether Both compounds give prominent peaks at m/2 116, 73, 57, and 43. But one compound gives a distinctive strong peak at 87, and the other compound gives a strong peak at 101. Determine which compound gives the peak at 87 and which...
using the following mass spectra data, answer the following questions 2. Using the following mass spectra...
using the following mass spectra data, answer the following
questions
2. Using the following mass spectra data, answer the following questions 43 70 50 85 57 30 20 101 29 71 100 0 20 30 4 500 TO 100 110 m/z a. Given that the compound contains only Carbon and hydrogen, what would be the molecular formula? b. Which peak is represents the molecular ion? c. Which peak represents the base peak?
15. The mass spectrum of a compound appears below. The molecular ion, M+1, and M+2 peaks...
15. The mass spectrum of a compound appears below. The molecular ion, M+1, and M+2 peaks have intensities of 100, 6.8, and 31.8 respectively. Use the information provided to determine the formula of the compound 100 MS-NW-5495 80 60 40 20 шшшl 110 10 20 30 40 50 60 70 80 90 100 m/z Relative Intensity
15. The mass spectrum of a compound appears below. The molecular ion, M+1, and M+2 peaks have intensities of 100, 6.8, and 31.8 respectively....
The mass spectrum of compound A shows molecular ion peak at m/z 88. The IR spectrum...
The mass spectrum of compound A shows molecular ion peak at m/z 88. The IR spectrum of this compound has a broad peak between 3200 and 3550 cm-1. The 1H NMR spectrum of A shows the following peaks: a triplet at d 0.9, a singlet at d 1.1, one more singlet at d 1.15, and a quartet at d 1.6. The area ratio of these peaks is 3:6:1:2. The 13C NMR contains 4 signals. In the space below, propose a...
5. Identify the base peak in your mass spectrum. 6. Are there other significant isotope patterns...
5. Identify the base peak in your mass spectrum. 6. Are there other significant isotope patterns in your mass spectrum? If so, what do they indicate? 7. Provide at least one fragment (not the parent ion) that was useful in determining (or confirming) the structure of the unknown and briefly explain how it was useful. Compound 14 is a liquid (b.p. 85") which finds its greatest application as an aprotic solvent UV-transparent; IR-liquid fim. MASS SPECTRAL DATA 99 100 Mass...
assign the major absorptions in the IR spectra, assign chemical shifts in both NMR, designate the...
assign the major absorptions in the IR spectra, assign chemical
shifts in both NMR, designate the parent peak in the mass spectra
data and assign the major fragments to their corresponding peaks,
and finally provide the structure for the formula.
MF CHE MW 68 %C88.2 *H 11.8 Mass Spec. Data relative m/ abund. 21 3H .. Copyright © 1994 Note 'long-range' coupling. T TTTTTTTTTTTTTTTTT 2.4 2.2 2.0 Proton NMR 1.8 1.6 1.4 1.0 0.8 PPM Carbon 13 NMR
(34)The mass spectra of acid derivatives follow the principles shown for other carbonyl compounds and for...
(34)The mass spectra of acid derivatives follow the principles shown for other carbonyl compounds and for alkoxy groups. Both McLafferty rearrangements and alpha-cleavages are common. The mass spectrum for butyl butanoate shows two prominent even-mass fragments at m/z 88 and m/z 60. Propose structures for these two fragments, and show what fragmentations produce them.
The molecular weight of a compound is typically indicated by the heaviest peak on a mass spectrum, which i presumed to correspond to the molecular ion (M*). For smaller compounds, the heaviest peak tends to also be the most intense peak. The lighter peaks in the spectrum result from fragmentation of the molecule into smaller ions. Since peak intensity correlates to the relative stability of the ions produced, the peaks of the ionized fragments can be more intense than the...
1) Which compound gives the following spectra? For the 'H-NMR assign all signals. Interpret base peak and mole peak in the mass spectrum if a mole peak exists. Assign at least two "C signals. How does the IR spectrum support your findings? (12 pts.) 100- Relative Intensity 0- 20 40 60 80 100 140 160 180 200 220 120 m/ 200 180 160 140 120 100 80 60 40 20 0 ppm t6H 9,4H 11H d, 2 H 9 8...
Problem 12-10 Ethers are not easily differentiated by their infrared spectra, but they tend to form predictable fragments in the mass spectrum. The following compounds give similar but distinctive mass spectra. VO butyl isopropyl ether butyl propyl ether Both compounds give prominent peaks at m/2 116, 73, 57, and 43. But one compound gives a distinctive strong peak at 87, and the other compound gives a strong peak at 101. Determine which compound gives the peak at 87 and which...
using the following mass spectra data, answer the following
questions
2. Using the following mass spectra data, answer the following questions 43 70 50 85 57 30 20 101 29 71 100 0 20 30 4 500 TO 100 110 m/z a. Given that the compound contains only Carbon and hydrogen, what would be the molecular formula? b. Which peak is represents the molecular ion? c. Which peak represents the base peak?
15. The mass spectrum of a compound appears below. The molecular ion, M+1, and M+2 peaks have intensities of 100, 6.8, and 31.8 respectively. Use the information provided to determine the formula of the compound 100 MS-NW-5495 80 60 40 20 шшшl 110 10 20 30 40 50 60 70 80 90 100 m/z Relative Intensity
15. The mass spectrum of a compound appears below. The molecular ion, M+1, and M+2 peaks have intensities of 100, 6.8, and 31.8 respectively....
5. Identify the base peak in your mass spectrum. 6. Are there other significant isotope patterns in your mass spectrum? If so, what do they indicate? 7. Provide at least one fragment (not the parent ion) that was useful in determining (or confirming) the structure of the unknown and briefly explain how it was useful. Compound 14 is a liquid (b.p. 85") which finds its greatest application as an aprotic solvent UV-transparent; IR-liquid fim. MASS SPECTRAL DATA 99 100 Mass...
assign the major absorptions in the IR spectra, assign chemical
shifts in both NMR, designate the parent peak in the mass spectra
data and assign the major fragments to their corresponding peaks,
and finally provide the structure for the formula.
MF CHE MW 68 %C88.2 *H 11.8 Mass Spec. Data relative m/ abund. 21 3H .. Copyright © 1994 Note 'long-range' coupling. T TTTTTTTTTTTTTTTTT 2.4 2.2 2.0 Proton NMR 1.8 1.6 1.4 1.0 0.8 PPM Carbon 13 NMR
(34)The mass spectra of acid derivatives follow the principles shown for other carbonyl compounds and for alkoxy groups. Both McLafferty rearrangements and alpha-cleavages are common. The mass spectrum for butyl butanoate shows two prominent even-mass fragments at m/z 88 and m/z 60. Propose structures for these two fragments, and show what fragmentations produce them.
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