Homework Answers
M and M+2 peaks intensities are 100 and 31.8 which are in ratio of 3:1 .
This is possible if we have Cl as Cl has two isotopes of 35 amu and 37 amu in 3:1 ratio. Now
if we remove 35 amu from M peak of 112 we get 77 amu.
This 77 amu consists of C , H. Taking CH2 ( molar mass of 14) we get total CH2 units = ( 77 /14) = 6 rounded value.
Thus we had 6 carbons , now atomic mass of C and Cl combined = ( 12 x 6) amu + 35 amu = 107 amu
remaining mass comes from H =112amu - 107 amu = 5 amu
H has 1 amu atomic mass , hence total H = 5
Thus formula is C6H5Cl
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15. The mass spectrum of a compound appears below. The molecular ion, M+1, and M+2 peaks...
16. A hydrocarbon with a molecular weight of 100 Da (and expected molecular ion at 100 m 2) was analyzed by mass...
16. A hydrocarbon with a molecular weight of 100 Da (and expected molecular ion at 100 m 2) was analyzed by mass spectrometry and gave the spectra shown below. Based on the MS spectrum and considering possible fragmentation of the hydrocarbon, which of the molecules provided corresponds to this spectrum? 100- m/z = 57 Da Relative Intensity m/z = 85 Da Expected molecular ion (not observed) 10 20 30 40 tillo el origen los 50 60 70 80 90 100...
1. Consider the Mass Spectrum below to answer the following questions: MS-NU-S495 Relative Intensity 0- 10...
1. Consider the Mass Spectrum below to answer the following questions: MS-NU-S495 Relative Intensity 0- 10 prote 20 30 40 t 50 to 60 70 m/z 80 90 100 110 a. (1 point) What is the m/z of the molecular ion peak: b. (1 point) What is the m/z value of the base peak: c. (2 point) Explain why do we observe the peak at m/z = 114 d. (2 points) The molecular formula of this compound is C.HSX. Identify...
label each major peak with a molecular formula (including charge) label the molecular ion peak as "M+" (if present) labe...
label each major peak with a molecular formula (including
charge)
label the molecular ion peak as "M+" (if present)
label major peaks other than the molecular ion with three
things:
1) the mass to charge ratio
2) the structure or formula for that charged fragment
3) another formula to show which fragment was lost by the molecular
ion to form that ion
Mass spec NEUTRAL COMPOUND 100- 80 2-6utanene 60 40 20- 75 60 65 70 35 40 45 10...
Use the mass spectrum to answer the questions below Does the compound contain chlorine or bromine...
Use the mass spectrum to answer the questions below
Does the compound contain chlorine or bromine or neither?
Explain.
Give the m/z value for the molecular ion peak.
Give the m/z value for the base peak.
The base peak is a common fragment – what is the most likely
chemical formula for the base peak?
Does the compound contain chlorine or bromine or neither?
Explain.
Give the m/z value for the molecular ion peak.
Give the m/z value for the...
. The peaks for 1.22. 21.16 The molecular ion for compound D does not appear in...
. The peaks for 1.22. 21.16 The molecular ion for compound D does not appear in its mass spectrum the important fragments from the molecular ion, however, are clearly seen in Figure 2 Assign a structure to compound D Compound D 100 80 60 40 20 120 140 160 100 (Adapted from Stenhagen et al. Reprinted by permission.) 20 40 60 80
Please label the peaks of the following graphs for the compound Acetophenone 100 Relative Intensity 100...
Please label the peaks of the following graphs for the compound
Acetophenone
100 Relative Intensity 100 110 120 Ortofritt 10 20 30 40 50 60 70 80 90 m/z f. NMR Spectrum: 11 10 9 8 5 4 2 1 ppm g. IR Spectrum: THESE TERCEIP HAVENUMERI
16. A hydrocarbon with a molecular weight of 100 Da (and expected molecular ion at 100...
16. A hydrocarbon with a molecular weight of 100 Da (and expected molecular ion at 100 m 2) was analyzed by mass spectrometry and gave the spectra shown below. Based on the MS spectrum and considering possible fragmentation of the hydrocarbon, which of the molecules provided corresponds to this spectrum? 100- m/z = 57 Da Relative Intensity m/z = 85 Da Expected molecular ion (not observed) 10 20 30 40 tillo el origen los 50 60 70 80 90 100...
Label the molecular ion and base peaks on the mass spectrui Delu 100 レase peak ion 1020 3o 40 o ...
need to fill the boxes
Label the molecular ion and base peaks on the mass spectrui Delu 100 レase peak ion 1020 3o 40 o 6O 70 B0 100 m/z What element does the analyte molecule likely contain? Propose one possible molecular formula for the analyte molecule. ELEMENT: POSSIBLE FORMULA: The mass spectrum of 2.2'-dibromobiphenyl is shown below, along with a proposed structure of the m/z 314 peak. Based on this information, propose structures for the other two peaks indicated....
Deduce the ester compound structure with M/Z=136 on this mass spectrum; significant peaks at 51, 77,...
Deduce the ester compound structure with M/Z=136 on this mass
spectrum; significant peaks at 51, 77, 105, 136.
Relative Abundance M(136) 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 mz
This is the mass spectrum of dichlorocyclohexylmethylsilane. Explain the relative intensity for peaks at m/e 196.0...
This is the mass spectrum of dichlorocyclohexylmethylsilane. Explain the relative intensity for peaks at m/e 196.0 (13.5), 197.0 (1.8), 198.0 (9.1),199.0 (1.1), 200.0 (1.7)and 201.0 (0.2) 1 00 - MS-IW-7601 C1 80 $i-CH3 60 40 mtt O 40 zO 60 140 160 180 200 100 1ZO m/z Relative Intensity
This is the mass spectrum of dichlorocyclohexylmethylsilane. Explain the relative intensity for peaks at m/e 196.0 (13.5), 197.0 (1.8), 198.0 (9.1),199.0 (1.1), 200.0 (1.7)and 201.0 (0.2) 1 00 - MS-IW-7601 C1...
16. A hydrocarbon with a molecular weight of 100 Da (and expected molecular ion at 100 m 2) was analyzed by mass spectrometry and gave the spectra shown below. Based on the MS spectrum and considering possible fragmentation of the hydrocarbon, which of the molecules provided corresponds to this spectrum? 100- m/z = 57 Da Relative Intensity m/z = 85 Da Expected molecular ion (not observed) 10 20 30 40 tillo el origen los 50 60 70 80 90 100...
1. Consider the Mass Spectrum below to answer the following questions: MS-NU-S495 Relative Intensity 0- 10 prote 20 30 40 t 50 to 60 70 m/z 80 90 100 110 a. (1 point) What is the m/z of the molecular ion peak: b. (1 point) What is the m/z value of the base peak: c. (2 point) Explain why do we observe the peak at m/z = 114 d. (2 points) The molecular formula of this compound is C.HSX. Identify...
label each major peak with a molecular formula (including
charge)
label the molecular ion peak as "M+" (if present)
label major peaks other than the molecular ion with three
things:
1) the mass to charge ratio
2) the structure or formula for that charged fragment
3) another formula to show which fragment was lost by the molecular
ion to form that ion
Mass spec NEUTRAL COMPOUND 100- 80 2-6utanene 60 40 20- 75 60 65 70 35 40 45 10...
Use the mass spectrum to answer the questions below
Does the compound contain chlorine or bromine or neither?
Explain.
Give the m/z value for the molecular ion peak.
Give the m/z value for the base peak.
The base peak is a common fragment – what is the most likely
chemical formula for the base peak?
Does the compound contain chlorine or bromine or neither?
Explain.
Give the m/z value for the molecular ion peak.
Give the m/z value for the...
. The peaks for 1.22. 21.16 The molecular ion for compound D does not appear in its mass spectrum the important fragments from the molecular ion, however, are clearly seen in Figure 2 Assign a structure to compound D Compound D 100 80 60 40 20 120 140 160 100 (Adapted from Stenhagen et al. Reprinted by permission.) 20 40 60 80
Please label the peaks of the following graphs for the compound
Acetophenone
100 Relative Intensity 100 110 120 Ortofritt 10 20 30 40 50 60 70 80 90 m/z f. NMR Spectrum: 11 10 9 8 5 4 2 1 ppm g. IR Spectrum: THESE TERCEIP HAVENUMERI
16. A hydrocarbon with a molecular weight of 100 Da (and expected molecular ion at 100 m 2) was analyzed by mass spectrometry and gave the spectra shown below. Based on the MS spectrum and considering possible fragmentation of the hydrocarbon, which of the molecules provided corresponds to this spectrum? 100- m/z = 57 Da Relative Intensity m/z = 85 Da Expected molecular ion (not observed) 10 20 30 40 tillo el origen los 50 60 70 80 90 100...
need to fill the boxes
Label the molecular ion and base peaks on the mass spectrui Delu 100 レase peak ion 1020 3o 40 o 6O 70 B0 100 m/z What element does the analyte molecule likely contain? Propose one possible molecular formula for the analyte molecule. ELEMENT: POSSIBLE FORMULA: The mass spectrum of 2.2'-dibromobiphenyl is shown below, along with a proposed structure of the m/z 314 peak. Based on this information, propose structures for the other two peaks indicated....
Deduce the ester compound structure with M/Z=136 on this mass
spectrum; significant peaks at 51, 77, 105, 136.
Relative Abundance M(136) 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 mz
This is the mass spectrum of dichlorocyclohexylmethylsilane. Explain the relative intensity for peaks at m/e 196.0 (13.5), 197.0 (1.8), 198.0 (9.1),199.0 (1.1), 200.0 (1.7)and 201.0 (0.2) 1 00 - MS-IW-7601 C1 80 $i-CH3 60 40 mtt O 40 zO 60 140 160 180 200 100 1ZO m/z Relative Intensity
This is the mass spectrum of dichlorocyclohexylmethylsilane. Explain the relative intensity for peaks at m/e 196.0 (13.5), 197.0 (1.8), 198.0 (9.1),199.0 (1.1), 200.0 (1.7)and 201.0 (0.2) 1 00 - MS-IW-7601 C1...
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