Question

This is the mass spectrum of dichlorocyclohexylmethylsilane. Explain the relative intensity for peaks at m/e 196.0 (13.5), 19

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Solution:

The intensity and their peaks are due to differences in isotopes of Cl (Cl-35 , Cl-37) and C (C12,C13).

The peaks and their fragment ions are given in attached sheet.

1 Si- cu2+12) -22) Si-cM3 L 1 CI molecula n peak, 1t: C1 -Si-Cn3 Si-ch3 Si-ch3 1 1 C135 C137 e13 196 e 200 8b1 One-ei 32 One

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