(3 pt) For the following reactions:
a) Label the substrate (1°, 2°, 3°), reagent (Good/Poor Nu, Strong/Weak Base) and solvent (protic, aprotic).
b) Determine what mechanism will predominate (SN1, SN2, E1, or E2).
c) Draw the product(s) you would expect to form, paying attention to regioselectivity and stereoselectivity.
Homework Answers
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(3 pt) For the following reactions:
a) Label the substrate (1°, 2°, 3°), reagent (Good/Poor Nu,...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Base...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group c. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e Draw the product of the reaction, based upon your categorization, remember...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group C. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e. Draw the product of the...
5. REACTIONS (30PTS, 6PT EA): For the following reactions indicate what substituted alkyl halide sol are...
5. REACTIONS (30PTS, 6PT EA): For the following reactions indicate what substituted alkyl halide sol are provided and choose indicated reaction conditions, 2) then provide the major product or indicate dicate what substituted alkyl halide, solvent, and nucleopa cmajor product or indicate NO REACTION Closed Inuci NaOEt alkoi halide: 1.1.3 Salt Polar Proti Polar Agrote Noclegile strong wak Br EtOH Of Shade one — SI E2 S 2 EI Circle one cach alky balide 1º, 2º, 3º Solvent Polar Prote/Polar...
Please help! for each reaction a)assess the substrate b) classify reagent (strong or weak; nuc or...
Please help!
for each reaction
a)assess the substrate
b) classify reagent (strong or weak; nuc or base)
c) solvent type if not indicated
d)mechanism type
e) major & minor products; proper stereochemestry &
geometry..
sn1,sn2,e1,e2
Lot (E2) O NÁSH (SN a NUC on Etoho Weak nuc Tb xs Nal XS Nal (SN22 H2O ignore Nuc/base effects of water weakbase good nuc tBuOK (potassium t-butóxide) strong Oa ge conc. H2SO4 30 heat elminator 6. но 7. DBN Br (strong base) -OEt...
Dropdown Menus: 1. methyl, primary (unhindered), primary (hindered), secondary, tertiary 2. poor, weakly basic, strong...
Dropdown Menus:
1. methyl, primary (unhindered), primary (hindered), secondary,
tertiary
2. poor, weakly basic, strongly basic (hindered), strongly basic
(unhindered)
3. protic, aprotic
4. SN2, SN1, E1, E2, SN2 AND E2, SN1 AND E1, No Reaction
5. randomized, inverted, predictable but not inverted,
unchanged
6. a planar carbocation intermediate, backside attack transition
state, anti-periplanar transition state, other
CH3CH2ONa ??? CH3CH2OH Br OH OH OH De on an or rega ang Look at the given reaction and select the most appropriate...
Compare and contrast SN1, SN2, E1 and E2 reactions. What are some obvious similarities and differences...
Compare and contrast SN1, SN2, E1 and E2 reactions. What are some obvious similarities and differences between each reaction pathway? What are the requirements for each reaction to work? Discuss why SN2 is in direct competition with E2 while SN1 is in direct competition with the E1 reaction pathway. What is the rate expression for each? Which reactions are concerted? Which reactions are step-wise? Which reactions are stereospecific and what is the stereospecificity of each that are? How do the...
2. Predict the product(s) of each of the reaction conditions below. Specify the substrate type (primary,...
2. Predict the product(s) of each of the reaction conditions
below. Specify the substrate type (primary, secondary, or tertiary
alkyl halide), nucleophile (strong or poor), and the solvent type
(protic or aptrotic). Specify the type of reaction mechanism (SN1
or SN2), show the curved arrow mechanism and draw the products as
3D structures to illustrate stereochemistry.
Predict the product(s) of each of the reaction conditions below. Specify the substrate type (1º, 2º, or 3 alkyl halide). mucleophile (strong or poor),...
please help! a)asses substrate b) classify reagents (nuc/base, strong or weak) c)solvent used if not indicated...
please help!
a)asses substrate
b) classify reagents (nuc/base, strong or weak)
c)solvent used if not indicated
d)mechanism type
e)major & minor products including stereochemistry &
geometry
sn1,sn2, e1,e2
Weak nuc 4. xs Nal (SN2 H2O ignore Nuc/base effects of water weakbase good nuc tBuOK (potassium t-butoxide strong base conc. H2SO4 SO I heat HO elimina DONI
Dropdown Menus: 1. methyl, primary (unhindered), primary (hindered), secondary, tertiary 2. poor, weakly basic, strongly basic...
Dropdown Menus:
1. methyl, primary (unhindered), primary (hindered), secondary,
tertiary
2. poor, weakly basic, strongly basic (hindered), strongly basic
(unhindered)
3. protic, aprotic
4. SN2, SN1, E1, E2, SN2 AND E2, SN1 AND E1, No Reaction
5. randomized, inverted, predictable but not inverted,
unchanged
6. a planar carbocation intermediate, backside attack transition
state, anti-periplanar transition state, other
OH Hom 유 용 The Tone The ♡ ♡ Tñ y OH H OH E OH F HO3 G Look at the given...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group c. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e Draw the product of the reaction, based upon your categorization, remember...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group C. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e. Draw the product of the...
5. REACTIONS (30PTS, 6PT EA): For the following reactions indicate what substituted alkyl halide sol are provided and choose indicated reaction conditions, 2) then provide the major product or indicate dicate what substituted alkyl halide, solvent, and nucleopa cmajor product or indicate NO REACTION Closed Inuci NaOEt alkoi halide: 1.1.3 Salt Polar Proti Polar Agrote Noclegile strong wak Br EtOH Of Shade one — SI E2 S 2 EI Circle one cach alky balide 1º, 2º, 3º Solvent Polar Prote/Polar...
Please help!
for each reaction
a)assess the substrate
b) classify reagent (strong or weak; nuc or base)
c) solvent type if not indicated
d)mechanism type
e) major & minor products; proper stereochemestry &
geometry..
sn1,sn2,e1,e2
Lot (E2) O NÁSH (SN a NUC on Etoho Weak nuc Tb xs Nal XS Nal (SN22 H2O ignore Nuc/base effects of water weakbase good nuc tBuOK (potassium t-butóxide) strong Oa ge conc. H2SO4 30 heat elminator 6. но 7. DBN Br (strong base) -OEt...
Dropdown Menus:
1. methyl, primary (unhindered), primary (hindered), secondary,
tertiary
2. poor, weakly basic, strongly basic (hindered), strongly basic
(unhindered)
3. protic, aprotic
4. SN2, SN1, E1, E2, SN2 AND E2, SN1 AND E1, No Reaction
5. randomized, inverted, predictable but not inverted,
unchanged
6. a planar carbocation intermediate, backside attack transition
state, anti-periplanar transition state, other
CH3CH2ONa ??? CH3CH2OH Br OH OH OH De on an or rega ang Look at the given reaction and select the most appropriate...
2. Predict the product(s) of each of the reaction conditions
below. Specify the substrate type (primary, secondary, or tertiary
alkyl halide), nucleophile (strong or poor), and the solvent type
(protic or aptrotic). Specify the type of reaction mechanism (SN1
or SN2), show the curved arrow mechanism and draw the products as
3D structures to illustrate stereochemistry.
Predict the product(s) of each of the reaction conditions below. Specify the substrate type (1º, 2º, or 3 alkyl halide). mucleophile (strong or poor),...
please help!
a)asses substrate
b) classify reagents (nuc/base, strong or weak)
c)solvent used if not indicated
d)mechanism type
e)major & minor products including stereochemistry &
geometry
sn1,sn2, e1,e2
Weak nuc 4. xs Nal (SN2 H2O ignore Nuc/base effects of water weakbase good nuc tBuOK (potassium t-butoxide strong base conc. H2SO4 SO I heat HO elimina DONI
Dropdown Menus:
1. methyl, primary (unhindered), primary (hindered), secondary,
tertiary
2. poor, weakly basic, strongly basic (hindered), strongly basic
(unhindered)
3. protic, aprotic
4. SN2, SN1, E1, E2, SN2 AND E2, SN1 AND E1, No Reaction
5. randomized, inverted, predictable but not inverted,
unchanged
6. a planar carbocation intermediate, backside attack transition
state, anti-periplanar transition state, other
OH Hom 유 용 The Tone The ♡ ♡ Tñ y OH H OH E OH F HO3 G Look at the given...
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