Ans :-
Formal Charge (F.C) = Number of valance electrons on central atom (V) - Number of shared electrons (S)/2 -Number of unshared electrons.
(a).
F.C on first N = 5 - 4/2 - 4 = - 1
F.C on second N = 5 - 8/2 - 0 = 5 - 4 = +1
F.C on O in second resonance structure = 6 - 2/2 - 6 = -1
F.C on first N in second resonance structure = 5 - 6/2 - 2 = 0
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