When N,N-dimethylaniline is treated with bromine, ortho and para products are observed. Yet, when N,N-dimethylaniline is...
Question 1 (10 pts). When N,N-dimethylaniline is treated with bromine, ortho and para products are formed. Note that this ring is so activated that a Lewis acid catalyst is not needed. Yet, when this material is treated with nitric/sulfuric acids, only the meta product is formed indicative of a very deactivated ring). Explain these curious results. z Br2 Br HNO, H2SO4 NO
Please predict the ortho/para products, including major and minor. (Write major/minor beside your products) Also, explain briefly why you would expect one product to be major and one to be minor. HNO3 H2SO4 predicted products compound in brown bottle
When ethoxybenzene is treated with a mixture of nitric acid and sulfuric acid, two products are obtained, each of which has the molecular formula C8H9NO3. Please draw the mechanism of each product in detail
When trans 1 phenylpropene is treated with bromine, some syn addition is observed. Explain why the presence of a phenyl group causes a loss of stereospecificity. When trans-1-phenylpropene is treated with bromine, some syn addition is observed. Explain why the presence of a phenyl group causes a loss of stereospecificity. cod. trans-Phenylpropene anti addition products yn addition products
Hi please can you help me understand how to answer this question "If p-nitrophenol is treated with chlorine in the presence of ALCL3 the only trisubstituted product observed is: 2 chloro -4nitrophenol I am confused because p nitrophenol has both an OH group which is an ortho and para activating group and a NO2 which is a deactivating meta group. Which one would take priority when undergoing the reaction?
Reaction 1: Nitration HNO3 NO2 H2SO4, H20 NO2 toluene NO2 ortho meta para Procedure for Reaction 1: 1) To a stirred solution of 3 mL (44.7 mmoles) 67 % HNO3 in 3.75 mL of water, H2SO4 (9 mL) was slowly added at 10-15 °C. 2) This nitrating solution was added dropwise with vigorous stirring to 4 mL (37.5 mmoles) of toluene while cooling in ice-water in order to maintain the reaction temperature between 15 and 25 °C. 3) Stirring was...
1. please check what is wrong. Thank you! Determine the product formed when each compound is treated with Br2 and FeBr3. Drag the atom labels to their appropriate positions. CN Atom labels H H Br Br2 A. FeBr Br H OH OH Br Br. Br2 FeBr3 H H Br Br H Br2 FeBr H1 H Reset T Rank the compounds in each group in order of decreasing reactivity in electrophilic aromatic substitution. CI Decreasing reactivity Rank the compounds in each...
1. Predict the major products formed when benzene reacts with the following reagents. (a). tert-butyl bromide, ALCl3 (b) bromine + a nail (c) iodine + HNO3 (d) carbon monoxide, HCl, and AlCl3/CuCl (e) nitric acid + sulfuric acid. 2. Predict the major products of the following reactions. (a.) nitrobenzene + ethyl chloride/AlCl3 (b). p-methylanisole + acetyl chloride + AlCl3 (c). nitrobenzene + fuming sulfuric acid (d) benzene + CH3CH2COCl in the presence of (1) ALCl3 followed by...
29. Which are the major reaction products of the following reaction, which is carried out in an inert solvent? AICI: solvent NO2 Oló - o 02 a) I and II b) III and IV c) I and IV d) II and III 30. Which is the major product of the following reactions? CH3CI Cl2 K2Cr207 FeCl3 FeCl3 H2SO4 a) para-chlorobenzoic acid b) meta-chlorobenzoic acid c) a mixture of para- and meta-chlorobenzoic acid d) a mixture of ortho- and para-chlorobenzoic acid...
JI) Name the compounds or draw the structures from their names. (2 pts) 1,2-chovo mul COOH a) NO2 b) CI c) 4-phenyl-2-pentanol; •DH d) 1-bromo-2-chloro-4-ethylbenzene; 2. Arrange the compounds in each set in order of decreasing reactivity (fastest to slowest) toward EAS. Explain. (2 pts) 0-C-CH3 -C-0-CH3 a) (A) (B) (C) CH2CH3 -NH2 ( C1) do nosotros (B) b) (A) 3. Account for the observation that trifluoromethyl groups is meta directing, as shown in the following example. (1 pt) CF3...