based on the reactivity of reagent and the conditions the products formed as follows
Starting Material Conditions OH PBr3 Eto C NaCN OMs DMF Br NaNH DMSO, 20°C 8 hr...
Conditions Starting Material Major Product(s) OH PBrg Et20 NaCN DMF OMs NaNH2 DMSO, 20'C 8 hr 1) NaH, DMF, -78°C 2) A ci NaOH Br OH
ETOH -Br heat - Br k. NaOH DMSO NaCN Br DMF m. OH Jones reagent
• Please provide the major organic product(s) of the reaction as described Account for all stereochemistry requirements for reaction and products. You need not include byproducts such as salts for this assignment, but you should be aware of their presence. "No reaction is NOT a possibility on this assignment Starting Material Conditions Major Product(s) ОН PBr3 Et20 NaCN DMF NaNH2 DMSO, 20'C 8 hr 1) NaH, DMF, -78°C 2) M ai NaOH
• Please provide the major organic product(s) of the reaction as described. Account for all stereochemistry requirements for reaction and products. You need not include byproducts such as salts for this assignment, but you should be aware of their presence. "No reaction" is NOT a possibility on this assignment. Starting Material Conditions Major Product(s) ОН PB13 Et20 NaCN OMs DMF Br NaNH2 DMSO, 20'C 8 hr
Hi I need help predicting the products for these reactions OEt NaOCH.CH CH,CH OH b. H, O/H,0 a. NaOCH.CH CH,CH,OH b. Br c. NaOHH O, beat d. H2O*/H2O 1. NaCN, DMSO 2. CH,MgBr, Eto 3. H.O/H,O EN 2. NaH, CH,Br chemoselective 1. a. NaOet, EtOH Br b. 2. a. NaOH/H,O, heat b. H30+/H20 CY.NECEN cy OH b. then add HC-NH2 a. NaCN, DMSO b. HO*/H,0
1. For the following Alkyl halide indicate which position will react under SN1 reaction conditions and under SN2 reaction conditions. Explain your answer. mer 2. Draw the complete mechanism and the products for of the following SN1 reaction paying close attention to stereochemistry. H3C CI CH OH CH2CH3 општироотип солио 3. Provide the product/s for the following reactions. Indicate if the reactions proceed via an SN1, or SN2 mechanism. Indicate proper stereochemistry if it is applicable. Show the mechanisms NaCN...
Devise the most efficient synthesis for the carboxylic acid below using a starting material and reagents from the tables. Give your route by specifying the number of the starting material followed by the letters of the reagents you would use beginning with the first step. The answer 4fh means treat t-butanol(4) with conc. HCl(f) then treat the product with KOH in alcohol(h). please write legible and circle answer OH rting materials Br Br ve tor OH нс 3 OH Он...
2) CHs LDA 1) LDA 3 2) Ci OH, H20 -OH, H2O CHO 1 LDA 2) CH3CH2Br Он, H2O 1) NaOEt 8 2) NaOEt OEt 10 Cl NaH 2 (excess) 12 HO Bra(excess) 13 HO LDA 14L THF, -78 C NaOEt, EtOH NaOEt, EtOH 16 NaOEt, EtOH 17 Br но 18 OOEt 1)NaOEt, EtOH 2) H3O 19 OEt 20 l HO o CHO + H20
Please show detailed mechanism or explain in words. DQ25.11 Homework Draw the starting material: . SOCI, DMF 2. (CH,CH),CuLi, THF Ph 3. H,O Hint: Note that organocuprates only add once to acyl chlorides. DQ25.12 Homework Draw the product of the following reactions: 0 O HN CH CI NaBH (1 equiv.) EtOH Hint: Think about the reactivity of the carboxylic acid derivatives. DQ25.13 Homework Draw the product of the following reaction. CH,NO cc, tBuOK, DMSO CCI Hint: The first step in...
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...