EtOH heat NaOH DMSO NaCN DMF Jones reagent reagent(s) OAC reagent(s); reagent(s); reagent(s);
1. Predict the product(s) (or no reaction) and reagent(s).
j. ETOH Br heat k. Br NaOH DMSO NaCN Br DMF m. РСС Н n. О H2SO4, H20 Н
Starting Material Conditions OH PBr3 Eto C NaCN OMs DMF Br NaNH DMSO, 20°C 8 hr 1) NaH, DMF, -78°C 2) A ci NaOH
Conditions Starting Material Major Product(s) OH PBrg Et20 NaCN DMF OMs NaNH2 DMSO, 20'C 8 hr 1) NaH, DMF, -78°C 2) A ci NaOH Br OH
1. Predict the product(s) (or no reaction) and reagent(s). (17 pts) KI DCM ЕТОН heat H2O heat DBU DCM Testos e sot KNE DMF KOME DMF KOET HMPA LDA THF NaO'Bu toluene EtOH heat NaOH DMSO NaCN reagent(s); OH reagents) reagents):
Predict the product & reagent.
-Br ki DCM EtOH heat &송당송당 H2O heat DBU Br DCM KN3 DMF
4. Determine if Syl or Sn2 and the product formed. CH3OH CH3OH CH,OH CH3OH өОН DMF өОН 1112 DMSO NaCN DMSO
O X Br NaCN DMSO H30+ OH, A 21 pts. Culi NC CN base, A CH3 H (no workup) 19 pts.
1. Predict the product(s) (or no reaction) and reagent(s). (17 pts DCM EtOH heat BU DCM Br tot & ob 8 6 6 KN, DMF Коме DMF ΚΟΕΙ HMPA LDA THF NaO Bu toluene
1. Provide the missing reagent(s) and major product(s) for the following reactions. NaCN DMSO HO Br (CH3)3COK (CH3),COH OH HCro, Acetone 2. Provide a structure of each of the following. a. 4-ethyl-3-hexen-1-ol b. meta-ethylfluorobenzene C. R-3-methyl-3-ethoxyheptane 3. Rank the following: a. According to boiling point, 1 being the highest and 4 the lowest. он Л лон он F b. According to reactivity in an electrophilic aromatic substitution reaction, 1 being the most reactive and 4 the least. c. According to...