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Consider the following substitution reaction: OH H2SO4 CHBОН + - Нао 1. (1 point) What type...
1.1 In which of the following solvents would the reaction of 1-bromobutane with sodium azide,NaN3, proceed...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
5.8 g of 1,4-di-t-butyl-2,5-dimethoxynezene (250.37 g/mol) were synthesized by reacting 10.5 mL of t-butyl alcohol (MW...
5.8 g of
1,4-di-t-butyl-2,5-dimethoxynezene
(250.37 g/mol) were synthesized by reacting
10.5 mL of t-butyl alcohol (MW 74.12 g/mol, D
0.79 g/mL), 25 mL of concentrated sulfuric
acid (MW 98.08 g/mol, D 1.84
g/mL), and 5.9 g of 1,4-dimethoxybenzene (MW
138.17 g/mol) together. Calculate the percent
yield of this reaction.
Question 1 2 pts 5.8 g of 1,4-di-t-butyl-2,5-dimethoxynezene (250.373/mol) were synthesized by reacting 10.5 mL oft- butyl alcohol (MW 74.12 3/mol. D 0.795/mL), 25 mL of concentrated sulfuric acid (MW 98.08...
Questions 2-10 please!! 1) A substitution reaction is: [2] a) A reaction during which an OH...
Questions 2-10 please!!
1) A substitution reaction is: [2] a) A reaction during which an OH group of a molecule is replaced by a halogen. b) A reaction during which water is the leaving group. c) A reaction during which a functional group of a molecule is replaced by an electrophile. d) A reaction during which a functional group of a molecule is replaced by another functional group. V 12 2) Substitution reactions are classified either as electrophilic or nucleophilic...
5.1 g of 1,4-di-t-butyl-2,5-dimethoxynezene (250.37 g/mol) were synthesized by reacting 9.7 mL of t-butyl alcohol (MW...
5.1 g of
1,4-di-t-butyl-2,5-dimethoxynezene
(250.37 g/mol) were synthesized by reacting
9.7 mL of t-butyl alcohol (MW 74.12 g/mol, D
0.79 g/mL), 25 mL of concentrated sulfuric
acid (MW 98.08 g/mol, D 1.84
g/mL), and 4.2 g of 1,4-dimethoxybenzene (MW
138.17 g/mol) together. Calculate the percent
yield of this reaction. Write your answer without a percent
sign and to 2 decimal places. MW=molecular weight, D=density of
liquid. PLEASE SHOW WORK
OH t-butanol 1,4-di-tert-butyl-2,5-dimethoxybenzene 1,4-dimethoxybenzene
please answer these questions 1: Which of the following is true for the reaction of (1R,...
please answer these questions 1: Which of the following is true for the reaction of (1R, 2R)-1-tert-butyl-1-fluoro-2-methylcyclohexane with potassium hydroxide? a: The product is (E)(6R)-1-tert-butyl-6-methyl-1-cyclohexene b: The product is (Z)(6R)-1-tert-butyl-6-methyl-1-cyclohexene c: The product is (Z)(6S)-1-tert-butyl-6-methyl-1-cyclohexene d: The product is (E)(6S)-1-tert-butyl-6-methyl-1-cyclohexene 2: Which of the following is not true for regioselective reactions? a: Generally, the selectivity lies to toward the Saytzeff product in elimination reactions. b: In a regioselective reaction, there is one product that predominates. c: The transition states of...
1. Write the OVERALL reaction for this lab. 2. Show the mechanism's steps for this reaction....
1. Write the OVERALL reaction for this lab. 2. Show the mechanism's steps for this reaction. Be sure to include the arrows showing where the electrons are being transferred. 3. What is(are) the intermediates in this mechanism? 4. Which step is the rate determining step? 13 SN1: Synthesis of tert-Butyl Chloride Alkyl halides can be prepared from their corresponding alcohols via an acid catalyzed substitution reaction. The mechanism of these acid catalyzed substitution reactions are labeled as Syl (substitution, nucleophilic,...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem Two. Start over. This time assume A is a solid and 423.6 mg of A was measured...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem One. Assume 168 uL A and 123 uL B and one drop of concentrated H2SO4 were allowed...
13 SN1: Synthesis of tert-Butyl Chloride Alkyl halides can be prepared from their corresponding alcohols via...
13 SN1: Synthesis of tert-Butyl Chloride Alkyl halides can be prepared from their corresponding alcohols via an acid catalyzed substitution reaction. The mechanism of these acid catalyzed substitution reactions are labeled as Syl (substitution, nucleophilic, unimolecular) and S2 (substitution, nucleophilic, bimolecular). Tertiary alcohols follow the Snl route, primary alcohols follow the S2 route, and secondary alcohols can follow either path. Under acidic conditions, the mechanism (Figure 1) of the Sul reaction involves rapid protonation of the alcohol, followed by the...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem One. Assume 168 uL A and 123 ul B and one drop of concentrated H2SO4 were allowed...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
5.8 g of
1,4-di-t-butyl-2,5-dimethoxynezene
(250.37 g/mol) were synthesized by reacting
10.5 mL of t-butyl alcohol (MW 74.12 g/mol, D
0.79 g/mL), 25 mL of concentrated sulfuric
acid (MW 98.08 g/mol, D 1.84
g/mL), and 5.9 g of 1,4-dimethoxybenzene (MW
138.17 g/mol) together. Calculate the percent
yield of this reaction.
Question 1 2 pts 5.8 g of 1,4-di-t-butyl-2,5-dimethoxynezene (250.373/mol) were synthesized by reacting 10.5 mL oft- butyl alcohol (MW 74.12 3/mol. D 0.795/mL), 25 mL of concentrated sulfuric acid (MW 98.08...
Questions 2-10 please!!
1) A substitution reaction is: [2] a) A reaction during which an OH group of a molecule is replaced by a halogen. b) A reaction during which water is the leaving group. c) A reaction during which a functional group of a molecule is replaced by an electrophile. d) A reaction during which a functional group of a molecule is replaced by another functional group. V 12 2) Substitution reactions are classified either as electrophilic or nucleophilic...
5.1 g of
1,4-di-t-butyl-2,5-dimethoxynezene
(250.37 g/mol) were synthesized by reacting
9.7 mL of t-butyl alcohol (MW 74.12 g/mol, D
0.79 g/mL), 25 mL of concentrated sulfuric
acid (MW 98.08 g/mol, D 1.84
g/mL), and 4.2 g of 1,4-dimethoxybenzene (MW
138.17 g/mol) together. Calculate the percent
yield of this reaction. Write your answer without a percent
sign and to 2 decimal places. MW=molecular weight, D=density of
liquid. PLEASE SHOW WORK
OH t-butanol 1,4-di-tert-butyl-2,5-dimethoxybenzene 1,4-dimethoxybenzene
1. Write the OVERALL reaction for this lab. 2. Show the mechanism's steps for this reaction. Be sure to include the arrows showing where the electrons are being transferred. 3. What is(are) the intermediates in this mechanism? 4. Which step is the rate determining step? 13 SN1: Synthesis of tert-Butyl Chloride Alkyl halides can be prepared from their corresponding alcohols via an acid catalyzed substitution reaction. The mechanism of these acid catalyzed substitution reactions are labeled as Syl (substitution, nucleophilic,...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem Two. Start over. This time assume A is a solid and 423.6 mg of A was measured...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem One. Assume 168 uL A and 123 uL B and one drop of concentrated H2SO4 were allowed...
13 SN1: Synthesis of tert-Butyl Chloride Alkyl halides can be prepared from their corresponding alcohols via an acid catalyzed substitution reaction. The mechanism of these acid catalyzed substitution reactions are labeled as Syl (substitution, nucleophilic, unimolecular) and S2 (substitution, nucleophilic, bimolecular). Tertiary alcohols follow the Snl route, primary alcohols follow the S2 route, and secondary alcohols can follow either path. Under acidic conditions, the mechanism (Figure 1) of the Sul reaction involves rapid protonation of the alcohol, followed by the...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem One. Assume 168 uL A and 123 ul B and one drop of concentrated H2SO4 were allowed...
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