for the Explore the stereochemistry following 1.CH I xs 2. Agzo 3.D Nmez
What are the products (with stereochemistry) of these rxns? (CH3) CHCCI AIC b) NaOCH,CH CH CH,OH c) Br2 CH,NH NO FeBry d) o O 1. NaOCH CHs 2. (CH) CHCH2Br 3. HCKaq). A CH,CH OCCH COCH CH e) CH2CH3 1. KMnO4(aq) 2. SO3. H2S04 NaOH triglceride CH,CH2NH2 (large xs) Br h)
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH
MOBI (1eq.) 1. Mgº, CH.CH,OCH,CH, 2 Å 3. H,O, HCI 1. CH,MgBr(xs) O 2 H,O, HCI 1. Mg. CH,CH,OCH,CH, 2. 0,0
Name the following compound below with correct stereochemistry. CH Br r -H H-CH, CH,CH, (25,3S)-2-bromo-3-methylpentane (20,35)-2-bromo-3-methylpentane (25,3R)-2-bromo-3-methylpentane (2R 3R)-2-bromo-3-methylpentane
Supply the missing products or reagents for the following reaction. 12. CH2NH2 xs CH 2. Δ
for c and d 2. Indicate the preferred product for the following reactions. (Include stereochemistry) HBr, CH 0OCH 1. PhCO,H 2. H'/CH OH H/KMnO Br2, H20
provide major organic product(s). watch for stereochemistry. m.) 1. Pr-CI, AICI 2. NBS, CCU A n.) -OH XS HỌCrO4 acetone OH OH XS Bobbitt's SiO2, CH2Cl2 OH P.) 1. Ch. AICI 2. NaOH, 350°C 4,000 psi 3. HCI SCH, -9CH3 2Na, EtOH, NH,
plete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) ros. Br CH3 -CH; 1) BH THE 2) H20. NaOH -CH₂ ROOR RCO,H t.tt 1T 1) Hg(OA), H2O 2) NaBH 1. Provide the IUPAC name for the following molecule: 2. Draw the structure of Z-4-Bromo-5-methyl-4-hepten-2-yne: 3. Write down the major product(s), or the other reactant(s), of the following rea stereochemistry (wedge-and-dash) where appropriate: Xs HBr
d and SHOWS ures. 3. Consider the following nucleophilic substitution: CH3 CH CH3 CH Br + HBr CH iPrOH (xs) Calculate the theoretical yield of the product if 35.50 grams of the reactant 2- bromomethylcyclohexane is used. a) b) Determine the percent yield if the actual yield is 29.75 grams. 4·The reaction in the isomerization experiment performed has a carbocation intermediate. Explain why carbocation rearrangement does not occur.
Complete the following 1.) (xs) OH 2.) H30*C 3) A