Supply the missing products or reagents for the following reaction.
In the 1st step NH2 is substituted by CH3
In the next step double bond is created in between last two alkyl groups
Supply the missing products or reagents for the following reaction. 12. CH2NH2 xs CH 2. Δ
fill missing reagents
Roadmap Ch.10 #3 xs NaNH Br Br *S HBT Na MIC) 19-BRN 2. 42, ND UD Br₂ HO 12 OW nd OH للر
Fill in missing reagents
12. Fill in the missing reagents or products in the following scheme. (14 pts) Ma OH HCI NaOE! NaOEL
2.(20) The following five reactions show reactants, reagents and products. In each reaction one of the categories is missing (represented by a letter). Supply the missing reactant, reagents or product where appropriate in each reaction. In your structures, be sure to indicate stereochemistry where warranted. A= a) b) H2, 5%Pt/C CH212. Zn(Cu) in ether c) C : CH Br2 in H20 d) D : phase transf. cat OH 1) Hg(OAc)2, H20 2) NaBH4 e)
2. (12 pts) Reactions Give the reagents or products to the following systems. If a reaction does not give a product, write "NR" for No Reaction. Provide the product with the highest yield. Assume 1 to 1 stoichiometry unless otherwise stated. Provide stereochemistry if applicable. NC heat но но H ETOH 1. SOCI2 2. Heat, Hас -о н Но H но ETOH 1. TsCl NC H но но Н 2. CH,ок, CH,он
The following four reactions show reactants, reagents, and products. In each reaction one of the categories is missing. Supply the missing compound or reagents in each of the reactions. Be sure to indicate stereochemistry where warranted.
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH . (E2) 1.BH 2. H2O NaOH, HÔ PCC HB/ROOR how many stereoisomers? how many stereoisomers? PCC Excess H2O H CH2C12 HB Nal SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 HO H2SO mCPBA NaOEt (E2) H2SO4 (cat) don't worry about this reaction OH OH KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH Рcc CH2C12 HI (SN1)
Fill in the missing products or reagents (above blank arrows) for the following reaction schemes. No charged species should be drawn anywhere in this assignment. Acidic workup steps are assumed and are NOT explicitly included. Scheme 1: 10 pts EC- H2 KMnO4 Lindlar OH O ملتين NAOMe MeOH Scheme 2:12 pts 1) LDA H2O MgBr 2) O H2SO4 NaH Br LINHA mCPBA
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1) The following three schemes are missing reagents or products. Each missing reagent is 2 pts, each missing product is 3 pts. Do not add any reagents if something is already specified. Each scheme is independent. mCPBA DMP HN 2) Draw the mechanism of the acyl substitution reaction shown below. (8 pts)
1) The following three schemes are missing reagents or products. Each missing reagent is 2 pts, each missing product is 3 pts. Do not add any reagents if something is already specified. Each scheme is independent. mCPBA Ą — men of — Toque — 29 - - Y- DMP - -
2. Provide the missing products/reagents for the following reactions (2 pts each, 12 pts) 3. Protecting groups are important in Organic synthesis. We have seen 3 different protecting groups so far. Pick one and show how it is added, how it is removed, and what unwanted reactivity of the starting functional group it avoids. 4 pts) It is actually possible to oxidize ketones to esters using a reaction we have not talked about the Baeyer Villager reaction - which uses...