a ) Alcohol from the alkyl halide can be formed by Nuclephilic substitution of OH- on the desired position. and this is a SN2 type reaction , so non protic solvents is also used in it to optimise the yield .
b) desired alcohol from alkene can be formed by the attack on H+ from H2SO4 by the carbocation intermediate which stabilize itself by 1,2 methyl shift then by attack of OH- desired alcohol can be obtained
Mechanisms is mentioned below :
1. (5 points) Required Reagents. For each of these reactions: Draw the structure named as the...
(a) Draw and label with required reagents, the reactions of conversion of an alkene into: i. Alcohol ii. Aldehyde iii. Ketone iv. Carboxylic acid v. Epoxide vi. Gem diol vii. Alkyl halide viii. Alkyl dihalide Where appropriate, show the correct stereochemistry of the final products (b) Draw and label with appropriate reagents the carboxylate reaction series
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. КОН (alc) Br b) KOtBu HOtBu Br THE H2SO4 OTS КОН (ale) CH,CH Show Specific Stereochemistry CH(CH3)2 HCI H- CH CH_CH KOH (ale) Show Specific Stereochemistry NaOCH HOCH KO:Bu HOBu
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. ETOA earrangement Oceurs H,PO Reagement Our KOCH.CH HOCH-CH, Show Specific Stereochemistry CH,CHE + CH -CH NaOCH, HOCH OCH) Show Specific Stereochemistry KOCH.CH HOCH.CH KOB HO.Bu Provide a complete, stepwise mechanism to explain the following transformation. Be...
Write balanced equations and draw the structure for any reactions undergone by each alkyl halide with Nal/Acetone: 2-bromobutane, 2-bromo-2-methylpropane, 1- bromobutane, bromocyclohexane, 1-bromoadamantane and write out mechanism for the reaction 2-bromobutane in NaO/Acetone
Write balanced equations and draw the structure for any reactions undergone by each alkyl halide with AgNO3/ethanol 2-bromobutane, 2-bromo-2-methylpropane, 1-bromobutane, bromocyclohexane, 1-bromoadamantane and write out mechanism for the reaction of 2-bromobutane in AgNO3/Ethanol
Write balanced equations and draw the structure for any reactions undergone by each alkyl halide with NaI/Acetone: 2-bromobutane, 2-bromo-2-methylpropane, 1-bromobutane, bromocyclohexane, 1-bromoadamantane and write out mechanism for the reaction 2-bromobutane in NaO/Acetone
Draw the structure of each compound 1. Draw the structure of each compound: (a) cis-1,2-Cyclohexanediol (b) Isobutanol (c) 2,4,6-Trinitrophenol (d) (R)-2,2-Dimethyl-3-heptanol (e) Ethylene glycol (0) (s)-2-Methyl-1-butanol 2. Acid-catalyzed hydration of 3,3-dimethyl-1-butene produces 2,3-dimethyl-2-butanol. Show a mechanism for this reaction 3. Acid-catalyzed hydration of 1-methylcyclohexene yields two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain. 4. Using 2-propanol as your only source of carbon, show how you would prepare 2-methyl- 2-pentanol. 5. Identify...
1. (7 points) Draw the major, organic product generated for each of the reactions regiochemistry and stereochemistry. Be sure to indicate if more than one enantiomer is formed. below. Pay particular attention to the CI dilute H2SO4 KCN C2, H20 (dark) 1. BH3 THF 2. H2O2, KOH 1. NaH 2. allyl chloride (e) Draw the stereoisomer of 2,3-diphenylbut-2-ene that yields meso-2,3-dibromo-2,3-diphenylbutane on reaction with Br2 in the cold, darkness. 2.(2 points) Complete the following synthesis by filing in the missing...
1.(a) (2pts.) Draw the structural formula for each amine. (b) provide the IUPAC name the structure below 4-aminobutanal (R)-2-butanamine 2. (6 pts.) Consider the Grignard reaction shown below which forms a C-C bond via an Aw step. In box A, draw the structure of the nucleophile involved in the A step and highlight the nucleophilic atom. In box B, draw the structure of the electrophile involved in the Aw" step and circle the electrophilic atom. In box C, draw the...
**(left structure)****(right structure)** The two structures for the assignment are above and the task is: 1. Perform a retrosynthetic analysis on the two target molecules assigned to you. In each case the organic starting material (what you have to work backwards toward) depends upon the target. For the structure given above (structure on left), the starting material is either malonic ester or acetoacetic ester and any halide. For the structure given above (structure on right), the starting material is any...