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Solutions containing both Fe3+ and Al3+ can be selectively analyzed for Fe3+ by buffering to a...

Solutions containing both Fe3+ and Al3+ can be selectively analyzed for Fe3+ by buffering to a pH of 2 and titrating with EDTA. The pH of the solution is then raised to 5 and an excess of EDTA added, resulting in the formation of the Al3+- EDTA complex. The excess of EDTA is then back titrated using a standard solution of Fe3+, providing an indirect determination of Al3+. Show that at a pH of 2, the formation of the Fe3+-EDTA complex is favorable, while the formation of the Al3+-EDTA complex is not.

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