Using the first law of thermodynamics
∆U = ∆q+∆W
∆Q = - 5.00×102kJ ( negative sign indicate that heat released by system)
∆W =+ 4.50×102kJ ( positive sign indicate that work done on the system by the surrounding)
Putting both value in formula
∆U = -2.00×102kJ + 4.5×102 kJ = 2.5×102kJ
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