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Sodium is a body centered cubic crystal with a single 3s valence electron and a lattice...

Sodium is a body centered cubic crystal with a single 3s valence electron and a lattice parameter a = 0.4225 nm. Assuming the electron effective mass in sodium to be m∗ = 1.26 me where me is the mass of a free electron in vacuum, use Eq.(2) to estimate the value of γ for the 3s electron band in sodium. State your answer in eV. Hint: Taylor expand Eq. (2) to second order in kx, ky, and kz.

Ek = Ev − 8γ cos(akx/2 ) cos(aky/ 2 ) cos(akz/2 ) -------------------------------- Eq.(2)

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3s vatencee 2,,2 2. 4X4 бу feuup. 2 nm AK de a Av 9225) Xo2 m a 2

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