The following are all
relatively inexpensive aromatic compounds that could have been used
as substrates in this reaction. Predict the product or products, if
any, that would be obtained an acylation of each of them using
acetyl chloride.
Homework Answers
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The following are all
relatively inexpensive aromatic compounds that could have been used
as substrates in...
52. Arrange the relative pKa's of the following compounds:( P (2 pts) соон соон COOH pKa's: 53. Arrange th compounds: (2 pts) e relative reaction rates for the electrophilic aromatic subst...
52. Arrange the relative pKa's of the following compounds:( P (2 pts) соон соон COOH pKa's: 53. Arrange th compounds: (2 pts) e relative reaction rates for the electrophilic aromatic substitution of the following CH3 OCHa NO2 Reaction rates: 54. Arrange the relative base strength of the following compounds: (2 pts) NHCOCH3 NH2 NH2 NH2 NH. OCH3 OCH3 Basicity 55. What is the splitting pattern for the labeled hydrogens in the following compounds? (5 pt CH CH 56. Provide one...
please help in all sections asap!! In a Clemmensen reduction, an aryl ketone is reduced to...
please help in all sections asap!!
In a Clemmensen reduction, an aryl ketone is reduced to an Oaryl aldehyde Caryl alkane aryl carboxylic acid aryl ester aryi anhydride Identify the electrophile for the Friedel-Crafts acylation of benzene. O aluminum tetrachloride anion aluminum chloride acylium ion carbocation carbanion Which of the following criteria is necessary for a nucleophilic aromatic substitution reaction? © A. The ring must contain a very strong electron withdrawing group. B. The ring must contain a leaving group....
ch 22 In both series below the three aromatic compounds illustrated undergo the electrophilic substitution reaction...
ch 22
In both series below the three aromatic compounds illustrated undergo the electrophilic substitution reaction shown NH2 A B Reaction: Bromination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest А B с Reaction: Chlorination Next Reaction: Bromination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? v do 000!! ZI Reaction: Chlorination Which compound (A, B, or C) reacts the...
h both series below the three aromatic compounds ilhestrated undergo the electrophilic substitution reaction show NHCCHE...
h both series below the three aromatic compounds ilhestrated undergo the electrophilic substitution reaction show NHCCHE A B Reaction: Bromination Which compound (A, B, C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? O OCH COH A B C Reaction: Chlorination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? h both series below the three stomatic compounds ilhestrated undergo the electrophilic substitution reaction shown -C-CH2CH3 OH...
Organic Chemistry please help asap 70. What nucleophiles wou cleophiles would form the following compounds as...
Organic Chemistry please help asap
70. What nucleophiles wou cleophiles would form the following compounds as a result of reacting with l-iodobutane? OH SH 11. Draw (R)-2-bromopentane + CHO b. (R)-3-bromo-3-methylheptane + CH,OH c. benzyl chloride + CH CH OH te tollowing reactions: if the products can exist as stereoisomers, show what striscmers are obtained d. allyl chloride + CHOH e. 1-bromo-2-butene + CHO 1. l-bromo-2-butene + CH OH the products obtained from the solvolysis of each of the following...
Nil 1. Which of the following compounds is least reactive by electrophilic aromatic nitration or sulfonation?...
Nil 1. Which of the following compounds is least reactive by electrophilic aromatic nitration or sulfonation? Briefly explain why. 2. Give the major product(s) of the following SpAr reactions. For an o-/p-director, show both products. If no reaction occurs, state why the reaction does not occur. CO,H HNO, H2SO4 +CH.CLAICH SOH Zn(Hg) AICI ? HỌC-CH-C-Cl + HCI/Heat CH3
The structures of the four compounds that could have been in your sample are given below....
The structures of the four compounds that could have been in your sample are given below. Do you see any trends in the structures that might correlate with retention times? ( You will need to consult some reference books, be sure to list them in your report). CH3 CH3 CH2CH3
17. Which of the following aromatic compounds reacts the fastest in a halogenation reaction? CH3 A....
17. Which of the following aromatic compounds reacts the fastest in a halogenation reaction? CH3 A. B. C. D. 18. What would be the major product('s) of the following reaction? HSO,, heat o,N IV -19. Arrange the following compounds in order of decreasing reactivity in electrophilic substitution: a) V > II > I > III > Ⅳ b) 11 > V > 111 > 1 > rv c) IV>I> III> V>I d) 111 > 11 > 1 > IV >...
6. Which of the following reagents can be used to complete the reaction shown below? CH,CH,...
6. Which of the following reagents can be used to complete the reaction shown below? CH,CH, CH2-CECH CH,CHCHECH b. H2O with H2SO/HgSo. a. BH, followed by H2O2 d. None of the above. c. O, in CH,COOH 7. Which of the following is the major product of the reaction shown below? pyridine 8. Which of the following aromatic substitution reactions is most likely to give a polysubstituted product with benzene as a reactant? a. Friedel-Crafts Acylation b. Friedel-Crafts Alkylation c. Nitration...
please help in all sections asap!! Which of the following reactions would produce isopropylbenzene as the...
please help in all sections asap!!
Which of the following reactions would produce isopropylbenzene as the major product? ОН AICI: H2SO4 H2SO4 AICI3 IV I all of these Predict the product for the following reaction fuming H2SO4 SO3H Predict the structure of the major product for the following reaction Which of the following compounds will not undergo nucleophilic aromatic substitution? 1-chloro-2,4-dinitrobenzene 1-bromo-4-nitrobenzene O-chloronitrobenzene m-chloronitrobenzene p-chloronitrobenzene Choose the correct sequence of reagents for the following transformation. 2) 3 . NH2 2)...
52. Arrange the relative pKa's of the following compounds:( P (2 pts) соон соон COOH pKa's: 53. Arrange th compounds: (2 pts) e relative reaction rates for the electrophilic aromatic substitution of the following CH3 OCHa NO2 Reaction rates: 54. Arrange the relative base strength of the following compounds: (2 pts) NHCOCH3 NH2 NH2 NH2 NH. OCH3 OCH3 Basicity 55. What is the splitting pattern for the labeled hydrogens in the following compounds? (5 pt CH CH 56. Provide one...
please help in all sections asap!!
In a Clemmensen reduction, an aryl ketone is reduced to an Oaryl aldehyde Caryl alkane aryl carboxylic acid aryl ester aryi anhydride Identify the electrophile for the Friedel-Crafts acylation of benzene. O aluminum tetrachloride anion aluminum chloride acylium ion carbocation carbanion Which of the following criteria is necessary for a nucleophilic aromatic substitution reaction? © A. The ring must contain a very strong electron withdrawing group. B. The ring must contain a leaving group....
ch 22
In both series below the three aromatic compounds illustrated undergo the electrophilic substitution reaction shown NH2 A B Reaction: Bromination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest А B с Reaction: Chlorination Next Reaction: Bromination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? v do 000!! ZI Reaction: Chlorination Which compound (A, B, or C) reacts the...
h both series below the three aromatic compounds ilhestrated undergo the electrophilic substitution reaction show NHCCHE A B Reaction: Bromination Which compound (A, B, C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? O OCH COH A B C Reaction: Chlorination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? h both series below the three stomatic compounds ilhestrated undergo the electrophilic substitution reaction shown -C-CH2CH3 OH...
Organic Chemistry please help asap
70. What nucleophiles wou cleophiles would form the following compounds as a result of reacting with l-iodobutane? OH SH 11. Draw (R)-2-bromopentane + CHO b. (R)-3-bromo-3-methylheptane + CH,OH c. benzyl chloride + CH CH OH te tollowing reactions: if the products can exist as stereoisomers, show what striscmers are obtained d. allyl chloride + CHOH e. 1-bromo-2-butene + CHO 1. l-bromo-2-butene + CH OH the products obtained from the solvolysis of each of the following...
Nil 1. Which of the following compounds is least reactive by electrophilic aromatic nitration or sulfonation? Briefly explain why. 2. Give the major product(s) of the following SpAr reactions. For an o-/p-director, show both products. If no reaction occurs, state why the reaction does not occur. CO,H HNO, H2SO4 +CH.CLAICH SOH Zn(Hg) AICI ? HỌC-CH-C-Cl + HCI/Heat CH3
The structures of the four compounds that could have been in your sample are given below. Do you see any trends in the structures that might correlate with retention times? ( You will need to consult some reference books, be sure to list them in your report). CH3 CH3 CH2CH3
17. Which of the following aromatic compounds reacts the fastest in a halogenation reaction? CH3 A. B. C. D. 18. What would be the major product('s) of the following reaction? HSO,, heat o,N IV -19. Arrange the following compounds in order of decreasing reactivity in electrophilic substitution: a) V > II > I > III > Ⅳ b) 11 > V > 111 > 1 > rv c) IV>I> III> V>I d) 111 > 11 > 1 > IV >...
6. Which of the following reagents can be used to complete the reaction shown below? CH,CH, CH2-CECH CH,CHCHECH b. H2O with H2SO/HgSo. a. BH, followed by H2O2 d. None of the above. c. O, in CH,COOH 7. Which of the following is the major product of the reaction shown below? pyridine 8. Which of the following aromatic substitution reactions is most likely to give a polysubstituted product with benzene as a reactant? a. Friedel-Crafts Acylation b. Friedel-Crafts Alkylation c. Nitration...
please help in all sections asap!!
Which of the following reactions would produce isopropylbenzene as the major product? ОН AICI: H2SO4 H2SO4 AICI3 IV I all of these Predict the product for the following reaction fuming H2SO4 SO3H Predict the structure of the major product for the following reaction Which of the following compounds will not undergo nucleophilic aromatic substitution? 1-chloro-2,4-dinitrobenzene 1-bromo-4-nitrobenzene O-chloronitrobenzene m-chloronitrobenzene p-chloronitrobenzene Choose the correct sequence of reagents for the following transformation. 2) 3 . NH2 2)...
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