predict the product(s) for the following reactions. Indicate proper stereochemistry when needed. if more than one stereoisomer forms, draw each one separately.
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predict the product(s) for the following reactions.
Indicate proper stereochemistry when needed. if more than one...
1. (9 pts.) Predict the product(s) for the following reactions. Indicate proper stereochemistry when needed. If a...
1. (9 pts.) Predict the product(s) for the following reactions. Indicate proper stereochemistry when needed. If a mixture of stereoisomers forms, draw each of them. 1) (CH), CHCH,MgBr 2) H2O M Y 1) LIAIHA 237,0 1) DIBAL-H 2) H0
1. (9 pts.) Predict the product(s) for the following reactions. Indicate proper stereochemistry when needed. If a mixtu...
1. (9 pts.) Predict the product(s) for the following reactions. Indicate proper stereochemistry when needed. If a mixture of stereoisomers forms, draw each of them. 1) (CH3)2CHCH2MgBr 2) H20 1) LIAIH 2) H,о 1) DIBAL-H 2) H20 CI
1. (6 pts.) Predict the products for the following reactions. If no reaction occurs, write “NR”....
1. (6 pts.) Predict the products for the following reactions. If no reaction occurs, write “NR”. Indicate proper stereochemistry where appropriate. If more than one product can form, indicate the major product(s). If more than one stereoisomer forms, draw each stereoisomer separately. 1) PPhz 2) n-BuLi / THE Br i 2) 420 1) LIAIHA 2) H20 HONG HO
member that the lobby will close late afternoon. (25 pts.) Predict the product(s) for the following...
member that the lobby will close late afternoon. (25 pts.) Predict the product(s) for the following reactions. Include proper stereochemistry where appropriate. Be specific- if there is more than one stereoisomer, draw each one. (Note-you should have 2 pages for this problem HCI m-CPBA Br2 H20 1) BH3 THF 2) H202 /NaOH(aa)
4. Complete the following reactions, providing the proper stereochemistry where required. If more than one product...
4. Complete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) Bry CH Но b) 1) ВН THF CH3 2) Н,О, NaOH Hа сн, Pd сн, d) Нer ROOR e) RCO H 1) Hg(OAch, H2O 2) NaBH З/19
4. Complete the following reactions, providing the proper stereochemistry where required. If more than one product...
4. Complete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) Bry CH Но b) 1) ВН THF CH3 2) Н,О, NaOH Hа сн, Pd сн, d) Нer ROOR e) RCO H 1) Hg(OAch, H2O 2) NaBH З/19
plete the following reactions, providing the proper stereochemistry where required. If more than one product is...
plete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) ros. Br CH3 -CH; 1) BH THE 2) H20. NaOH -CH₂ ROOR RCO,H t.tt 1T 1) Hg(OA), H2O 2) NaBH 1. Provide the IUPAC name for the following molecule: 2. Draw the structure of Z-4-Bromo-5-methyl-4-hepten-2-yne: 3. Write down the major product(s), or the other reactant(s), of the following rea stereochemistry (wedge-and-dash) where appropriate: Xs HBr
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii...
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
2. Predict the product for the following transformations (show proper stereochemistry). Pd/C, H2 Me Me Pd/C,...
2. Predict the product for the following transformations (show proper stereochemistry). Pd/C, H2 Me Me Pd/C, H2 Me Ph 4. Draw an abbreviated mechanism of the reaction shown below (you can symbolize the Pd/C as a surface, like the one drawn below) Hint. draw an intermediate similar to this: R H MeO H H2 (gas) R MeO metal surface metal surface Pd/C) (Pd/C)
1. (9 pts.) Predict the product(s) for the following reactions. Indicate proper stereochemistry when needed. If a mixture of stereoisomers forms, draw each of them. 1) (CH), CHCH,MgBr 2) H2O M Y 1) LIAIHA 237,0 1) DIBAL-H 2) H0
1. (9 pts.) Predict the product(s) for the following reactions. Indicate proper stereochemistry when needed. If a mixture of stereoisomers forms, draw each of them. 1) (CH3)2CHCH2MgBr 2) H20 1) LIAIH 2) H,о 1) DIBAL-H 2) H20 CI
1. (6 pts.) Predict the products for the following reactions. If no reaction occurs, write “NR”. Indicate proper stereochemistry where appropriate. If more than one product can form, indicate the major product(s). If more than one stereoisomer forms, draw each stereoisomer separately. 1) PPhz 2) n-BuLi / THE Br i 2) 420 1) LIAIHA 2) H20 HONG HO
member that the lobby will close late afternoon. (25 pts.) Predict the product(s) for the following reactions. Include proper stereochemistry where appropriate. Be specific- if there is more than one stereoisomer, draw each one. (Note-you should have 2 pages for this problem HCI m-CPBA Br2 H20 1) BH3 THF 2) H202 /NaOH(aa)
4. Complete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) Bry CH Но b) 1) ВН THF CH3 2) Н,О, NaOH Hа сн, Pd сн, d) Нer ROOR e) RCO H 1) Hg(OAch, H2O 2) NaBH З/19
4. Complete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) Bry CH Но b) 1) ВН THF CH3 2) Н,О, NaOH Hа сн, Pd сн, d) Нer ROOR e) RCO H 1) Hg(OAch, H2O 2) NaBH З/19
plete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) ros. Br CH3 -CH; 1) BH THE 2) H20. NaOH -CH₂ ROOR RCO,H t.tt 1T 1) Hg(OA), H2O 2) NaBH 1. Provide the IUPAC name for the following molecule: 2. Draw the structure of Z-4-Bromo-5-methyl-4-hepten-2-yne: 3. Write down the major product(s), or the other reactant(s), of the following rea stereochemistry (wedge-and-dash) where appropriate: Xs HBr
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
2. Predict the product for the following transformations (show proper stereochemistry). Pd/C, H2 Me Me Pd/C, H2 Me Ph 4. Draw an abbreviated mechanism of the reaction shown below (you can symbolize the Pd/C as a surface, like the one drawn below) Hint. draw an intermediate similar to this: R H MeO H H2 (gas) R MeO metal surface metal surface Pd/C) (Pd/C)
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