Given the information below, calculate ∆?∘?,298.15? and ∆?∘?,400? for the following reaction:
??(?) + 2???(?) → ?2(?) + ????2(?)
Assume that heat capacities are constant over the desired temperature range. All molar enthalpies of formation are at 298.15K.
∆?∘ Mg(g) ? = 147.1 kJ/mol
∆?∘ HCl(g) ? = -92.3 kJ/mol
∆?∘ H2(g) ? = 0 kJ/mol
∆?∘ MgCl2(s) = -641.3 kJ/mol
Cp,m Mg(g) = 20.8 J mol-1 K-1
Cp,m HCl(g) = 29.1 J mol-1 K-1
Cp,m H2(g) = 28.8 J mol-1 K-1
Cp,m MgCl2(s) = 71.4 J mol-1 K-1
Cp,m MgCl2(s) = 71.4 J mol-1 K-1
Given the information below, calculate ∆?∘?,298.15? and ∆?∘?,400? for the following reaction: ??(?) + 2???(?) →...
Using the table of standard entropies and enthalpies of formation, calculate AH°, ASº, and AG° for the following reactions at 298.15 K. (Use only the table of standard entropies and standard enthalpies of formation, not the table of standard Gibbs free energies.) kJ AH; () AS; mol-K mol Compound C(s) 5.7 CO(g) -110.5 197.7 The equation SiO2(s) + 2 Mg(s) Si(s) + 2 CO2(g) -393.5 213.8 MgO(s) C2(g) 223.1 H2(g) 130.7 • AH° kJ HCl(g) 186.9 -92.3 • AS° MK...
Use the data below, for 298.15 K, to calculate the thermodynamic equilibrium constant, kp, at 839 K for the following reaction. NH4Cl(s) NH3(g) + HCl(g) ΔΗ 7 kJ mol-1 -314.4 -45.9 -92.3 Smº JK-1 mol-1 94.6 192.8 186.9 Cp,m 84.1 35.1 29.1 /JK-1 mol-1 Do not use the Van't Hoff equation, In(K /K1) = -(AHR/R) (T2-1 - 7,-1) The value of the thermodynamic equilibrium constant is Kp= 7.6e14
Predict the signs, comment and then calculate the enthalpy and entropy changes for the reaction of combustion ofmethane at 500 K. Will the reaction be spontaneous at 500 K? CH4(g) + 2 O2(g) → CO2(g) + 2H2O(g) We give: The enthalpies of formation of the products at 298.15 K in kJ/mol are: ∆Hf(CO2) = - 393.51; ∆Hf(H2O) = - 241.82; ∆Hf(CH4) = -74.81. The heat capacities at constant pressure in J.mol-1.K-1: Cp(CO2) = 37.11; Cp(H2O) = 33.58; Cp(CH4) = 35.31;...
Part A Several reactions and their standard reaction enthalpies at 298.15 K are given here: AH (kJ · mol-?) CaC2 (s) + 2H2O(1) + Ca(OH)2 (s) + C2H2 (g) –127.9 Ca(s) + O2(g) → Cao(s) CaO(s) +H2O(1) + Ca(OH)2(s) -65.2 -635.1 The standard enthalpies of combustion of graphite and C2H2(g) are –393.51 and — 1299.58 kJ · mol-? respectively. Calculate the standard enthalpy of formation of CaC2(s) at 25°C. Express your answer to one decimal place and include the appropriate...
(6 pts.) Using Hess’s Law and the values for Standard Enthalpies of Formation from the table provided, calculate the enthalpy of reaction ΔH°rxn (in kJ) for each of the following reactions: Standard Enthalpies of Formation substance ΔHf° in kJ/mol Mg(s) 0 MgO(s) -601.6 HCl(aq) -167.2 MgCl2(aq) -801.2 H2(g) 0 H2O(l) -285.8 Reaction #1: Mg (s) + 2HCl (aq) è MgCl2 (aq) + H2 (g) Reaction #2: MgO (s) + 2HCl (aq) è MgCl2 (aq) + H2O (l) 2. (4 pts.)...
Calculate the ΔH0 for the following reaction: NH4Cl(s) → NH3(g) + HCl(g) Given the following standard enthalpies of formation ΔHf0 (298 K, 1 atm) NH3(g) -46.2 kJ mol-1 ; HCl(g) -92.3 kJ mol-1 ; NH4Cl(s) -315.0 kJ mol-1
Part A Several reactions and their standard reaction enthalpies at 298.15 K are given here: Al_C3(s) + 12H2O(l) + 4Al(OH),(s) + 3CH4(g) 2Al(s) + O2(g) + Al2O3(s) 1 A1,03(s) + H2O(l) + Al(OH)3(s) AH (kJ. mol-?) –1683.0 -1675.7 -9.6 The standard enthalpies of combustion of graphite and CH4(8) are -393.51 and --890.35 kJ. molº respectively. Calculate the standard enthalpy of formation of Al4C3(s) at 25°C.
Use standard enthalpies of formation (in Appendix G in text) to calculate ∆H°rxn for each reaction. ∑ m∆H°f (products) - ∑n∆H°f (reactants), where m and n are coefficients. C2H4(g) + H2(g) ----- > C2H6(g) CO (g) + H2O (g) ----- > H2(g) + CO2(g) 3NO2(g) + H2O (l) ----- > 2HNO3(aq) + NO (g) 2SO2(g) + O2(g) -----------> 2SO3(g) 2C4H10 (g) + 13O2 (g) -----------> 8CO2 (g) + 10H2O (g) Substance --- ΔH° (kJ mol–) --- ΔG° (kJ mol–1) --- S°298 (J K–1 mol–1) C2H4 52.4 86.4 219.3 H2 0 0 130.7 C2H6 -84.0 -32.0 229.2 CO -110.52 -137.15 197.7 H2O -285.83 -237.1 70.0 CO2 -393.51 -394.36 213.8 NO2 33.2 51.30 240.1 NO 90.25 87.6 210.8 SO2 -296.83 -300.1 248.2 O2 0 0 205.2 SO3 -395.72 -371.06 256.76
need help with 2. Use the following enthalpies of formation to calculate an approximate enthalpy of reaction, AHrxn for: (5 pts) C3H8 (g) + 502 (g) → 3CO2 (g) + 4 H20 (1) C(s) + O2 (g) - CO2 (g); AH = - 393.5 kJ/mol H2(g) + 42 02 (g) - H20 (1); AH = - 285.5 kJ/mol 3 C(s) + 4 H2(g) → C3H8 (g); AH r = - 103.8 kJ/mol
Calculate the AG" value at 500 K for the reaction given below. Is the reaction voluntary under conditions where the pressure of each H2 (g) and H20 (g) gas is 1 atm each? Cu (S) + H20 (g) → CuO (S) + H2 (g) 500K AHºf (kJ/mol) Sº (J/mol K) Cu (S). 0 33.3 H2O (g.hu -241.8 188.7 CuO (S) -155.2 43.51 H2 (g) 0 130.6