Derive equations for finding the following, during the titration of a weak base using a strong...
Derive equations for finding the following, during the titration of a weak base using a strong acid;
1. Initial pH
2. pH at any given point before equivalence point
3. pH at equivalence point
4. pH at any given point after equivalence point
Homework Answers
let the weak base be BOH
BOH ------------> B+ + OH-
Kb = [B+][OH-]/[BOH]
[OH-] = Kb[BOH]/[B+]
Kw = [OH-][H+]
[H+ ] = Kw / [OH-] = Kw/Kb[BOH]/[B+]
pH = 14 - log(Kb[BOH]/[B+])
2) At any point before equivalence point
its a basic buffer solution
Kb = [B+]salt[OH-]/[BOH]base
[OH-] = Kb[BOH]base/[B+]salt
taking negative log
pOH = pkb + log([B+]salt/[BOH]base)
pH = 14 - pOH = 14- {pkb + log([B+]salt/[BOH]base)}
3) At equivalence ,
its a case of Salt Hydrolsis so
pH = 7 -1/2pkb - logc
Add Answer to:
Derive equations for finding the following, during the titration
of a weak base using a strong...
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 67.3...
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 67.3 mL of 0.419 M hypochlorous acid (K-3.5x10-) by 0.419 M NaOH at the following points. (a) Before the addition of any NaOH (b) After the addition of 15.0 mL of NaOH (c) At the half-equivalence point (the titration midpoint) (d) At the equivalence point (e) After the addition of 101 mL of NaOH
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 59.3...
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 59.3 mlL of 0.335 M nitrous acid (K-4.5x104) by 0.335 M KOH at the following points. (a) Before the addition of any KOH (b) After the addition of 15.0 mL of KOH (c) At the half-equivalence point (the titration midpoint) (d) At the equivalence point (e) After the addition of 89.0 mL of KOH
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 60.9...
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 60.9 mL of 0.396 M hypochlorous acid (K4 = 3.5x10-8) by 0.396 M KOH at the following points. (a) Before the addition of any KOH (b) After the addition of 15.0 mL of KOH (c) At the half-equivalence point (the titration midpoint) (d) At the equivalence point (e) After the addition of 91.4 mL of KOH
Using the following pH curve for the titration of a weak acid with a strong base,...
Using the following pH curve for the titration of a weak acid with a strong base, if the pH at half-equivalence point is 4.75, what is the Ka of the weak acid? Equivalence Point Half-equivalence Point - 8 12 14 Volume of base added (in ml) 20 1.78 x 10-4 1.77 x 10-4 1.77 x 10-5 1.78 x 10-5
Which of the following is true for the titration of a weak acid with a strong base? O a. The pH at the equivalence...
Which of the following is true for the titration of a weak acid with a strong base? O a. The pH at the equivalence point is acidic. b. A buffer solution is formed before the equivalence point. OC. The initial pH equals -log (conc. of the acid). Od. The indicator changes its color at the half-neutralization point.
Titration of a weak acid (CH3COOH) and strong base (NaOH), the molarity of NaOH after titration...
Titration of a weak acid (CH3COOH) and strong base (NaOH), the
molarity of NaOH after titration = 0.167 M, I need help answering
to the blanks (Volume of base @ 1/2 equivalence point, pH @ 1/2
equivalence point, and pKa of the acid) on the following data
table,
11. Fill in the table below. Molarity of Acid 0.1204 M Volume of Acid 25.00 ml Volume of Base 17.959 ml Volume of Base @ 12 Equivalence Point pH @ 72 Equivalence...
Consider the curve shown here for the titration of a weak base with a strong acid and answer each question.
Consider the curve shown here for the titration of a weak base with a strong acid and answer each question. a. What is the pH and what is the volume of added acid at the equivalence point? b. At what volume of added acid is the pH calculated by working an equilibrium problem based on the initial concentration and Ks of the weak base? c. At what volume of added acid does pH = 14 - pka ? d. At what volume of added...
Tutored Practice Problem 17.3.2 COUNTS Calculate pH for a weak acid/strong base titration. Close Problem Determine...
Tutored Practice Problem 17.3.2 COUNTS Calculate pH for a weak acid/strong base titration. Close Problem Determine the pll during the titration of 57.0 ml of 0.303 M formie acid (K, - 1.8*10*) by 0.303 M N OH at the following points. (a) Before the addition of any NaOH (b) After the addition of 14.0 mL of NaOH (c) At the half-equivalence point the titration midpoint) (d) At the equivalence point (e) After the addition of 85.5 mL of NaOH Check...
Calculate pH for a strong acid/strong base titration. Determine the pH during the titration of 31.0...
Calculate pH for a strong acid/strong base titration. Determine the pH during the titration of 31.0 mL of 0.342 M HNO3 by 0.342 M NaOH at the following points: (a) Before the addition of any NaOH (b) After the addition of 15.5 mL of NaOH (c) At the equivalence point (d) After adding 40.0 mL of NaOH
2. Weak Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL...
2. Weak Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL of 0.100 M formic acid, HCHO2 (Ka 1.80 x 104) with 0.100 M N2OH. Calculate the pH for the following volumes of NaOH (0 mL, 10 mL, 25 mL, 40 mL, 50 mL, 55 mL, 60 mL). Volume of N2OH, in milliters pH (a) (b) (c) (d) (e) (f) (g) 0 10 25 40 50 55 60 pH at the equivalence point Specify your...
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 67.3 mL of 0.419 M hypochlorous acid (K-3.5x10-) by 0.419 M NaOH at the following points. (a) Before the addition of any NaOH (b) After the addition of 15.0 mL of NaOH (c) At the half-equivalence point (the titration midpoint) (d) At the equivalence point (e) After the addition of 101 mL of NaOH
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 59.3 mlL of 0.335 M nitrous acid (K-4.5x104) by 0.335 M KOH at the following points. (a) Before the addition of any KOH (b) After the addition of 15.0 mL of KOH (c) At the half-equivalence point (the titration midpoint) (d) At the equivalence point (e) After the addition of 89.0 mL of KOH
Calculate pH for a weak acid/strong base titration. Determine the pH during the titration of 60.9 mL of 0.396 M hypochlorous acid (K4 = 3.5x10-8) by 0.396 M KOH at the following points. (a) Before the addition of any KOH (b) After the addition of 15.0 mL of KOH (c) At the half-equivalence point (the titration midpoint) (d) At the equivalence point (e) After the addition of 91.4 mL of KOH
Using the following pH curve for the titration of a weak acid with a strong base, if the pH at half-equivalence point is 4.75, what is the Ka of the weak acid? Equivalence Point Half-equivalence Point - 8 12 14 Volume of base added (in ml) 20 1.78 x 10-4 1.77 x 10-4 1.77 x 10-5 1.78 x 10-5
Which of the following is true for the titration of a weak acid with a strong base? O a. The pH at the equivalence point is acidic. b. A buffer solution is formed before the equivalence point. OC. The initial pH equals -log (conc. of the acid). Od. The indicator changes its color at the half-neutralization point.
Titration of a weak acid (CH3COOH) and strong base (NaOH), the
molarity of NaOH after titration = 0.167 M, I need help answering
to the blanks (Volume of base @ 1/2 equivalence point, pH @ 1/2
equivalence point, and pKa of the acid) on the following data
table,
11. Fill in the table below. Molarity of Acid 0.1204 M Volume of Acid 25.00 ml Volume of Base 17.959 ml Volume of Base @ 12 Equivalence Point pH @ 72 Equivalence...
Tutored Practice Problem 17.3.2 COUNTS Calculate pH for a weak acid/strong base titration. Close Problem Determine the pll during the titration of 57.0 ml of 0.303 M formie acid (K, - 1.8*10*) by 0.303 M N OH at the following points. (a) Before the addition of any NaOH (b) After the addition of 14.0 mL of NaOH (c) At the half-equivalence point the titration midpoint) (d) At the equivalence point (e) After the addition of 85.5 mL of NaOH Check...
Calculate pH for a strong acid/strong base titration. Determine the pH during the titration of 31.0 mL of 0.342 M HNO3 by 0.342 M NaOH at the following points: (a) Before the addition of any NaOH (b) After the addition of 15.5 mL of NaOH (c) At the equivalence point (d) After adding 40.0 mL of NaOH
2. Weak Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL of 0.100 M formic acid, HCHO2 (Ka 1.80 x 104) with 0.100 M N2OH. Calculate the pH for the following volumes of NaOH (0 mL, 10 mL, 25 mL, 40 mL, 50 mL, 55 mL, 60 mL). Volume of N2OH, in milliters pH (a) (b) (c) (d) (e) (f) (g) 0 10 25 40 50 55 60 pH at the equivalence point Specify your...
Most questions answered within 3 hours.
-
Kyle, a 95.0 kg football player, leaps straight up into the air
(with no horizontal velocity)...
asked 7 minutes ago -
Which of the following is a measure of profitability?
A.
Quick (acid-test) ratio
B.
Net sales...
asked 9 minutes ago -
Find the total pressure exerted by 2 grams of ethane and 3 grams
of CO2 contained...
asked 11 minutes ago -
A fireman standing on a 5.2 m high ladder operates a water hose
with a round...
asked 7 minutes ago -
A cream formulation is studied for accelerated stability study.
Creaming was observed when formulation was tested...
asked 10 minutes ago -
A 1,150 lumen light bulb is placed 37 cm in front of a mirrored
wall, whose...
asked 20 minutes ago -
Given that z is a standard normal random variable, compute the
following probabilities (to 4 decimals)....
asked 27 minutes ago -
You begin preparation of the calibration curve to measure
absorbance vs concentration of FeSCN2+. To do...
asked 44 minutes ago -
When you speak after breathing helium, in which the speed of
sound is much greater than...
asked 37 minutes ago -
3. Stock Valuation: You are the CEO of Under Armour, Inc. and
are thinking about how...
asked 41 minutes ago -
Choose a brand. Critique the brand in terms of its brand
positioning, brand identity and brand...
asked 44 minutes ago -
A vertical curve has grades G1 = 2.8% (downgrade) and
G2 = 2.2 (upgrade) Assume design...
asked 44 minutes ago