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how much is a working solution will she need to neutralize 10.5 ML of 0.250MH3 PO four

C. How much of the working solution will she need to neutralize 10.5 mL of 0.250 M H3PO4?

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2. A student prepared a stock solution by dissolving 15.0 g of NaOH in enough water to make 150 mL of a stock solution. She t
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Answer #1

15 g NaOH is present in 150 mL of NaOH stock solution

Hence the molarity of stock solution, Ms = (weight/Molar mass)/Volume in L

                                                                = (15g/40 gmol-1)/0.150L

                                                                = 2.5 mol/L = 2.5 M

22.5 ml (Vs)of the stock solution is made to 250 mL solution

Hence the molarity of new solution can be calculated using the relation

MsVs = MWVW

MW and VW are molarity and volume of the working solution.

Hence Mw = MsVs / VW

                = 2.5 M x 22.5 mL / 250 ML                              (VW = 250 mL, given)

                = 0.225 M

Volume of working solution to neutralize the H3PO4 solution

We can use the equation

nwMwVw’ = npMpVp

where nw = valency of NaOH (working solution) = 1

np = valency of phosphoric acid = 3

Mp is molarity of phosphoric acid = 0.250 M

Vp is volume of phosphoric acid = 10.5 mL

Hence, the volume of the working solution,

Vw’ = npMpVp/nwMw

                                     = 3 x 0.250M x 10.5 mL/ (1x 0.225M)

                                     = 35 mL

Hence, the required volume of working solution for neutralization is 35 mL

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