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(aq) and Calculate A Gº for a redox reaction between Sns and Cr+3(aq) to produce Sn+2...
Use standard reduction potentials to calculate the equilibrium constant for the reaction: 2Cr (aq)+Sn(s)2 Cr (aq) + Sn2 (aq) Hint: Carry at least 5 significant figures during intermediate calculations to avoid round off error when taking the antilogarithm. Equilibrium constant than zero. AGo for this reaction would be
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
use tabulated standard electrode potential to calculate the standard cell potential for the reaction occurring in an electrochemical cell at 25 C. (The equation is balanced.) 3Ni^2+(aq)+2Cr(s)--->3Ni(s)2Cr^3+(aq) Express your answer to two significant figures and include the appropriate units. em 26 E (V) -0.45 -0.50 -0.73 -0.76 -1.18 Standard reduction half-cell potentials at 25°C Half-reaction E° (V) Half-reaction Aul+ (aq) + 3e +Au(s) 1.50 Fe2+ (aq) + 2eFe(s) Ag+ (aq) +e-Ag(s) 0.80 Cr3+ (aq) + Cr²+ (aq) Fe+(aq) + 3e...
Is #3 correct? "Sn(s)/Sn+2(aq) // Cu+2(aq)/Cu(s)" Also, I need help with #4 and #5. Thanks! (will rate!) Section A. Constructing a Small-Scale Electrochemical Cell Objective To construct a small-scale electrochemical cell using a redox system, to measure the cell potential and derive thermodynamic quantities. Procedures 1. Connect the red and black alligator clips to the multimeter to read voltage. Set up the multimeter to read DC (direct current) voltage using the tab at the top. 2. Cut the filter paper...
2. Using the decay chain for 238U, calculate the amount of time it takes 5.0 kg of 238U to decay to 2.5 kg. What mass of 206Pb is produced? (5 points) (V) Helpful Stuff Thermodynamics: AG° = AH-TAS Nernst Equation: 6 = 6 - (RT/nF)InQ AG=RTIK At 25°C: 8 = 6 - (0.0591/n)logQ ΔGIRT Ke=e AGⓇ = -nF8° Units/Constants: Volt: 1 V=1/C Faraday: 1 F -96,485 C/mol e Arrhenius Equation: k = Ae Ea/RT R= 8.314 J/mol K Integrated Rate...
5. How much faster would a reaction be if a catalyst is used that lowers the activation energy from 20.0 kJ/mol to 10.0 kJ/mol? Do the calculation at two temperatures: first at 25.0°C and then at 0.0°C. (20 points) (V) Helpful Stuff Thermodynamics: AG° = AH-TAS Nernst Equation: 6 = 6 - (RT/nF)InQ AG=RTIK At 25°C: 8 = 6 - (0.0591/n)logQ AGRT Ke=e AGⓇ =-nF8° Units/Constants: Volt: 1 V = 1 J/C Faraday: 1 F = 96,485 C/mole Arrhenius Equation:...
helpp 3. For the hypothetical reaction A+B → C the following rate data (with and without catalyst) were obtained: Rate, M/s Rate, M/s ALM B., Muncatalyzed) (catalyzed) 0.100 0.200 3.51 x 10 7.14 x 10 0.100 0.100 1.75 x 10 7.14 x 10 0.0500 0.200 1.76 x 10 3.57 x 10 0.0500 0.100 8.80 x 10 3.57 x 10 Based on these data: a. Determine the uncatalyzed and catalyzed rate laws for this reaction, and the corresponding rate constants. (16...
7. Using the following reaction progress diagram, answer the questions below: wiring Energy A G Rxn. a. How many steps are in the reaction? How do you know? (4 points) b. Which letter corresponds to the rate-determining-step? Explain your choice. (6 points) c. Is the reaction exothermic or endothermic? How do you know? (4 points) d. If the energy at point B is lowered, what will happen to the rate of the reaction will it increase, decrease, or stay the...
Using data found in Appendix E of your textbook calculate the nonstandard emf for each of the following reactions if the concentration of each of the ions in these reactions is 0.0005 molar and everything else is standard (use 298 K for the temperature, R = 8.314 J/mol-K, and F = 96,485 C/mol): Using data found in Appendix E of your textbook calculate the nonstandard emf for each of the following reactions if the concentration of each of the ions...
1. How do I read the half reaction table? 2. If im asked for the best reducing agent from Cu+, Ag+, F2, and Fe3+, where do I look first in the table? before the arrow or after the arrow? 3. Sometimes a value that has originally a positive (V) from the table it will have the negative sign in a homework problem, and viceversa, so the question is, how do I use the positive and negative signs in respect to...