Question 41 (2 points) Which of the following would you expect to function as the best...
Question 23 (2 points) Predict the major product for the following reaction. CH CH3CI AICI: 1. KMnO4/-OH 2. H30* ? AICI: OH OH 07 ОН - 11 IV a) 1 Ob) IV Oc) III d) II Question 24 (2 points) What is the product of the reaction below? ОН PCC ОН I II ОН III IV O a) 11 Ob) III Oc) IV Od)
Question 41 (2 points) Which of the following carbocations is (are) likely to undergo rearrangement through a methyl shift? H2C CH3 H3C CH3 H3C CH3 III a) both II and III Ob) both I and II Oc) Od) Question 42 (2 points) For the reaction shown, select the expected major organic product. 1. 1 eq HCI 2. 1 eq HBr Br. CI -Br -CI Ha CI Br + enantiomer + enantiomer + enantiomer CI Br + enantiomer IV 11 III...
Question 17 (2 points) Predict the structure of the major product for the following reaction. CH.CH Zn (Hg) CHCE AICI "NH TV oa) 11 ob) IV oc) III od) Question 18 (2 points) What is the product of the reaction below? POC OH o o od ol OH IV Oa) 111 ob) 11 Oc) IV od)
Question 7 (2 points) A compound with a molecular formula of C10H1202 has the following TH NMR spectrum. Which of the following structures is consistent with this spectrum? OCH CH.CH CH,CH.CH 1 OOH OH CH,CH,CH, CH2CH.CH IV Oa) III Ob) IV Oc) 11 od) Question 8 (2 points) Predict the product(s) for the following reaction: NH, 14H NH $ NH2 Oa) I and II ob) I, II and III Oc) III and I od) II and III
Question 31 (2 points) What are the expected major products of the reaction sequence shown below? 1. O 2. H70 OH o OH 11 III IV v Oa) I and IV ob) I and II oc) I, III and IV od) II, III and IV Question 32 (2 points) Which one of the following dienophiles is least reactive in the Diels-Alder reaction? NO, phony HCO 11 IV Oa) III ob) IV Oc) 1 od) 11
Question 9 (2 points) Identify the final product for the following reaction. 1. BH THE 2. O2, NaOH OH OH doy HII oa) IV ob) III OC) od) 11 Question 10 (2 points) Provide the structure of the expected major organic product generated upon completion of the following reaction scheme: (CH)CCH_CH=CH, HB HO H (CH)CCH.CH (снуусан,он- 1 Br (CH2jcChych do (touche con IV oa) IV ob) 11 oc) od) DI
Question 45 (2 points) For which of the following compounds will the M+2 peak intensity be equal to the intensity of the molecular ion peak M? oa) CH3CH2CH2NH2 ob) CH3CH2CH2Br OC) CH3CH2CH2C1 od) CH3CH2CH2OH Question 46 (2 points) Predict the major product(s) of the following reaction. Br2 light Ar o Br CHB CH-Br CHUB Br III IV Br Oa) IV Ob) III OC) 11 od) 1
Question 11 (2 points) Choose a major product for the reaction below. Cl2/AICI: OCH3 CI OCH3 OCH3 HI OCH3 HI 1 O a) 11 Ob) III O c) I, II and III Od)! Question 12 (2 points) Predict the structure of the major product for the following reaction. CH3CH2CCI Zn (Hg) CHCI AICI NH2 11 III IV O a) IV Ob) III Oc) O d) II
Question 13 (2 points) Predict the reactants for the following Diels- Alder product: OB 0: co 0:41 oa) IV ob) Oc) III od) 11 Question 14 (2 points) Calculate the degree of unsaturation for CgH9N04. oa) 8 ob) 6 OC) 9 od) 4
Question 43 (2 points) A triple bond is composed of Oa) Two sigma and one pi bond ob) Three sigma bonds Oc) Three pi bonds od) One sigma and two pi bonds Question 44 (2 points) Identify the major product for the following reaction. (CH) CHCH.C=CH HO, H2SO4 HgSO4 OH III IV Oa) IV ob) Oc) II od) III