Answer: Low spin complex → 0(zero) unpaired electron=> hence [Zn(NH3)6]2+ and [Fe(CN)6]4- are Diamagnetic. Ans
[Mn(CN)6]3– has magnetic moment of two unpaired electrons while [Mn(CN)6]3–has a paramagnetic moment of four unpaired electrons.
[FeF6]3– has a paramagnetic moment of five unpaired electrons.
show all steps please If NH3 and CN are both strong field ligands, and F is...
If NH3 and CN* are both strong field ligands, and F is a weak field ligand, how many of the following complexes are diamagnetic? [Mn(CN)613- [Zn(NH3)612+ [Fe(CN),14- [FeF613- 3 o 4
If NH3 and CN are both strong field ligands, and F is a weak field ligand, how many of the following complexes are diamagnetic? [Mn(CN),13 [Zn(NH3).12 [Fe(CN). [FeF.1% O 3 0 1 2 O 04
Which of the following complexes is paramagnetic? Assume all ligands are strong field ligands. Select one: O A. More than one of the complexes is paramagnetic O B. [Ni(CN) 14 O C. [Fe(CN))" о D. (Mn(CN)," o E. [Co(NH,
show all steps please IF CN is a strong field ligand, rank the following coordination compounds in order of decreasing number of unpaired d-electrons: [Fe(CN) [Pd(CN) [Mo(CN)
From the following list of metal ions and ligands, construct metal complexes with properties which match that described in each part of the question and provide a brief explanation. (Only one example is required for each part of the question, e.g. [Fe(H20)6]21). Metal ions Ligands (in order of increasing ligand field strength) [ < Br< <C1° <NO3 <OH <ox?- <H2O< Ti(IV), V(III), V(IV), Cr(II), Cr(III), Mn(II), NH3 <en <bpy < PPh3< CN=CO Mn(III), Mn(IV), Fe(II), Fe(III), Co(II), Co(III), en =...
1. Answer all parts to this question. From the following list of metal ions and ligands, construct metal complexes with properties which match that described in each part of the question and provide a brief explanation (Only one example is required for each part of the question, eg [Fe(H:01) Metal ions Ligands in order of increasing ligand field strength) I <Br <C<NO, <OHOXH.0 Ti(IV), V(III), V(IV), CHIT), CHIIT), Min(II). NH<em<bry<PPh<N =CÓ Mn(III). Mn(IV), Fe(II) Fe(III). CoII), COIIT) en = ethylenediamine...
Which one of the following octahedral complex ions is diamagnetic? Note: NH3 is a strong-field ligand. (a) [Fe(NH3)6] 3+ (b) [Fe(NH3)6] 2+ (c) [Cr(NH3)6] 3+ (d) [Cr(NH3)6] 2+ (e) [Co(NH3)6] 2+
3. According to the textbook (p. 115). the electron transfer reaction rate between [Co(NH3)]** and (Co(NH3).]?(eq. 5.41) is extremely slow whereas that between [Fe(CN).74 and [Fe(CN).]" (eq. 5.42) is very fast. By using the established facts in the box in answering the following questions. 1. According to the molecular orbital theory, the eg orbitals of an MLO octahedral complex are, in fact, M-L anti-bonding orbitals and the tza orbitals are non-bonding orbitals. 2. According to the spectrochemical series, CN is...
We discussed in class how ligands can affect the A. energy splitting. a. Categorize these complexes by whether their ligands are mainly i acceptors, i donors, or o donors. [Cr(CN)6]4-, [Fe(H20)6]2+, [CO(NH3)6]2+, [Cu(H20).]2+ b. Draw the tag-eg splitting and show the electron count for each complex from part a. Categorize each as high or low spin or write neither if both electron filling methods give the same result. Assume all o and i donors given here are weak-field ligands.
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in order from least to greatest according ability to split the d orbital energy level. A) CN-, OH, H2O, Br- C) Br,H20, CN-, OH- B) Br., OH, H2O, CN- D) None of the above 25. The charge on the central metal ion in (Cr(NH3)(CO3)2+ is A)-1. B) 0. C) 1. D) 3. E) 5 26....