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3. Iron(II) nitrate and hydrocyanic acid react to form the hexacyanoferrate(II) ion, [Fe(CN).]*(aq), with a formation...
Iron(II) nitrate and hydrocyanic acid react to form the hexacyanoferrate(II) ion, [Fe(CN)6] -4 (aq), with a formation constant of 1.438x1035 . This complex ion has an intense blue color in solution . a. If you add 182.734g of iron(II) nitrate solid to 750.0mL of 0.8324M CN-1 (aq) solution, what is the concentration of CN-1 (aq) still in solution when the reaction reaches equilibrium? b. Copper(II) also forms a complex ion with cyanide ions, tetracyanocuprate(II) ion, [Cu(CN)4] -2 (aq), with a...
Iron(II) nitrate and hydrocyanic acid react to form the hexacyanoferrate(II) ion, [Fe(CN)6] -4 (aq), with a formation constant of 1.438x1035 . This complex ion has an intense blue color in solution . a. If you add 182.734g of iron(II) nitrate solid to 750.0mL of 0.8324M CN-1 (aq) solution, what is the concentration of CN-1 (aq) still in solution when the reaction reaches equilibrium? b. Copper(II) also forms a complex ion with cyanide ions, tetracyanocuprate(II) ion, [Cu(CN)4] -2 (aq), with a...
Consider the insoluble compound iron(II) sulfide , Fes. The iron(II) ion also forms a complex with cyanide ions. Write a balanced net ionic equation to show why the solubility of FeS (s) increases in the presence of cyanide ions and calculate the equilibrium constant for this reaction. For Fe(CN),4-, Ke-7.7x1036. Use the pull-down boxes to specify states such as (aq) or (s). K =
please help What is the approximate concentration of free Cu* ion at equilibrium when 1.57x102 mol copperII) nitrate is added to 1.00 L of solution that is 1.380 M in NH3. For [Cu(NH3)4j2, Kf 2.1 1013 [Cu2 м What is the approximate concentration of free Fe2* ion at equilibrium when 1.42x102mol iron(II) nitrate is added to 1.00 L of solution that is 1.38so M in CN. For [Fe(CN)6]4, Kf=1.0x1035 [Fe"]= In the presence of excess OH, the Al*(aq) ion forms...
18. A 200.0-mL sample of a 0.0015 M copper(II) nitrate solution is mixed with a 250.0-mL sample of 0.20 M NH3. After the solution reaches equilibrium, what concentration of copper(II) ion remains? You will have to look up the appropriate complex formation constant.
The metathesis reaction between iron (III) nitrate and sodium sulfide is shown below 2 Fe(NO3)3(aq) + 3 Na2S (aq) ➝ 6 NaNO3(aq) + Fe2S3(s) How many grams of solid iron (III) sulfide can be produced by the reaction of 250.0 ml of 0.400 M iron (III) nitrate solution with 350.0 ml of 0.250 M sodium sulfide solution? Determine the final concentration of each ion in solution at the end of the precipitation reaction. Na+ NO3– Fe+3 S–2
Consider the following equilibrium: ⇌ Fe[CN]63−(aq) + 6H2O(l) John was trying to prepare his famous tye-dyed t-shirts. He knows that he can control the cyanide concentration in solution by using the complex ion and his knowledge of equilibrium. To get the most intense colors, he needs more cyanide in solution. The equilibrium above is exothermic as written. Explain whether John should make his shirts in hot or cold water. Explain why controlling the pH of the solution would help/hurt John’s...
12. The Cd(CN), ion has a formation constant, Ky, of 3 x 1018. Ca²+ (aq) + 4CN (aq) = C(CN).- (aq) What is the concentration of CN in a 0.01 M aqueous solution of K Cd(CN).?
An aqueous solution of 0.40 M silver nitrate, AgNO3, and 0.40 M iron(II) nitrate, Fe(NO3)2, is allowed to reach equilibrium according to the following chemical reaction. Ag+(aq) + Fe2+(aq) equilibrium reaction arrow Fe3+(aq) + Ag(s) If the equilibrium constant, Kc, for the reaction is 1.7 at a certain temperature, determine the equilibrium concentrations of Ag+, Fe2+, and Fe3+.
The E? values for two low-spin iron complexes in acidic solution are as follows: [Fe(o?phen)3]3+(aq)+e? ?[Fe(o?phen)3]2+(aq) E?=1.12V [Fe(CN)6]3?(aq)+e? ?[Fe(CN)6]4?(aq) E?=0.36V Part A Which complex is more difficult to reduce? [Fe(o-phen)3]3+ [Fe(CN)6]3? PArt B Is it thermodynamically favorable to reduce both Fe(III) complexes to their Fe(II) analogs? yes no