The E? values for two low-spin iron complexes in acidic solution are as follows: [Fe(o?phen)3]3+(aq)+e? ?[Fe(o?phen)3...
The E? values for two low-spin iron complexes in acidic solution are as follows:
[Fe(o?phen)3]3+(aq)+e? ?[Fe(o?phen)3]2+(aq) E?=1.12V
[Fe(CN)6]3?(aq)+e? ?[Fe(CN)6]4?(aq) E?=0.36V
Part A
Which complex is more difficult to reduce?
| [Fe(o-phen)3]3+ | |
| [Fe(CN)6]3? |
PArt B
Is it thermodynamically favorable to reduce both Fe(III) complexes to their Fe(II) analogs?
| yes | |
| no |
Homework Answers
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The E? values for two low-spin iron complexes in acidic solution are as follows: [Fe(o?phen)3]3+(aq)+e? ?[Fe(o?phen)3...
BACKGROUND: Synthesis of Potassium Iron (III) Oxalate Hydrate Salt The iron(II) ions from Fe(NH4)2(SO4)2•6H2O will be precipitated as iron(II) oxalate. Fe^2+(aq) + C2O4^2-(aq) --> FeC2O4 (s) The su...
BACKGROUND: Synthesis of Potassium Iron
(III) Oxalate Hydrate Salt
The iron(II) ions from
Fe(NH4)2(SO4)2•6H2O
will be precipitated as iron(II) oxalate.
Fe^2+(aq) + C2O4^2-(aq) --> FeC2O4 (s)
The supernatant liquid, containing the ammonium and sulfate
ions, as well as excess oxalate ions and oxalic acid will be
decanted and discarded. The solid will then be re-dissolved and the
iron(II) ions will be oxidized to iron(III) ions by reaction with
hydrogen peroxide.
2Fe^2+(aq) + H2O2(aq) --> 2Fe^3+(aq) +2 OH^ - (aq)
The...
i can't solve this question of coordination chemistry, could someone hlep me please Exercise 1: 1. What kind(s) o...
i
can't solve this question of coordination chemistry, could someone
hlep me please
Exercise 1: 1. What kind(s) of interaction between the ligand and the metal ion is(are) considered in the crystal field approach? 2. Give and justify the degeneracy lifting for a tetrahedral complex. Would it be the same for an octahedral complex? 3. Let us consider hexaaquacopper(II) ion. Justify the elongation of two opposite Cu-O bonds (along z for example) compared to the other four Cu-O bonds using...
just part d please 1. For the following complexes: i) give the formal oxidation state of...
just part d please
1. For the following complexes: i) give the formal oxidation state of the metal ii) the d count for the metal ions (e.g. Fe → d). iii) sketch the compound iv) give its point group v) provide a qualitative o-only d-orbital splitting diagram indicating the correct symbols for the point group (i.e. a10) vi) Indicate if you would predict a Jahn-Teller distortion (no need to distort to splitting diagram) vii) Calculate the spin-only value of Weft,...
Can't figure out the concentration of the complex of solns. 10, 11, 12, 13, & 14. Modern...
Can't figure out the concentration of the complex of
solns. 10, 11, 12, 13, & 14.
Modern Experimental Chemistry Chemistry 153 The Iron(III) Thiocyanate Complex Purpose of the Experiment To determine the chemical formula of a complex ion and measure its formation equilibrium constant Equipment Spectro Vis spectrophotometer and LabQuest, cuvette, 25-mL buret (3), ring stand, buret clamp (2), 50-mL beaker (3), small plastic beakers Reagents SCN, as KSCN, 0.00200 M solution Fe; as Fe(NO), 0.00200 M solution and a...
Please help with solving Question 1 (A-C) Thank you! Unless otherwise specified in the problem, you...
Please help with solving Question 1 (A-C) Thank you!
Unless otherwise specified in the problem, you may assume that all solutions are at 25°C. 1. 50.0 mL of a pH 6.00 carbonic acid buffer is titrated with 0.2857 M NaOH, requiring 17.47 mL to reach the second equivalence point. a. Calculate the molarity of carbonic acid and bicarbonate in the original buffer. Carbonic acid: Bicarbonate: b. Calculate the pH of the solution after a total of 100.0 mL of 0.2857...
5. What was the purpose of the NaNO3 solution in this experiment? 6. Could a solution...
5. What was the purpose of the NaNO3 solution in this experiment? 6. Could a solution of NaCl be used instead of NaNO3? 7. What was the purpose of FeSO4 solution in this experiment? 8. Could a solution of FeCl, be used instead of FeSO4? 9. Could a solution of NaSO4 be used instead of FeSO4? 10. Calculate the standard cell potential for the spontaneous redox reaction between a Pb(s)/Pb(NO3)2(aq) half-cell and a Ag(s)/AgNO3(aq) half-cell. Which metal would be oxidized?...
10. Write a one-page summary of the attached paper? INTRODUCTION Many problems can develop in activated...
10. Write a one-page summary of the attached paper? INTRODUCTION Many problems can develop in activated sludge operation that adversely affect effluent quality with origins in the engineering, hydraulic and microbiological components of the process. The real "heart" of the activated sludge system is the development and maintenance of a mixed microbial culture (activated sludge) that treats wastewater and which can be managed. One definition of a wastewater treatment plant operator is a "bug farmer", one who controls the aeration...
BACKGROUND: Synthesis of Potassium Iron
(III) Oxalate Hydrate Salt
The iron(II) ions from
Fe(NH4)2(SO4)2•6H2O
will be precipitated as iron(II) oxalate.
Fe^2+(aq) + C2O4^2-(aq) --> FeC2O4 (s)
The supernatant liquid, containing the ammonium and sulfate
ions, as well as excess oxalate ions and oxalic acid will be
decanted and discarded. The solid will then be re-dissolved and the
iron(II) ions will be oxidized to iron(III) ions by reaction with
hydrogen peroxide.
2Fe^2+(aq) + H2O2(aq) --> 2Fe^3+(aq) +2 OH^ - (aq)
The...
i
can't solve this question of coordination chemistry, could someone
hlep me please
Exercise 1: 1. What kind(s) of interaction between the ligand and the metal ion is(are) considered in the crystal field approach? 2. Give and justify the degeneracy lifting for a tetrahedral complex. Would it be the same for an octahedral complex? 3. Let us consider hexaaquacopper(II) ion. Justify the elongation of two opposite Cu-O bonds (along z for example) compared to the other four Cu-O bonds using...
just part d please
1. For the following complexes: i) give the formal oxidation state of the metal ii) the d count for the metal ions (e.g. Fe → d). iii) sketch the compound iv) give its point group v) provide a qualitative o-only d-orbital splitting diagram indicating the correct symbols for the point group (i.e. a10) vi) Indicate if you would predict a Jahn-Teller distortion (no need to distort to splitting diagram) vii) Calculate the spin-only value of Weft,...
Can't figure out the concentration of the complex of
solns. 10, 11, 12, 13, & 14.
Modern Experimental Chemistry Chemistry 153 The Iron(III) Thiocyanate Complex Purpose of the Experiment To determine the chemical formula of a complex ion and measure its formation equilibrium constant Equipment Spectro Vis spectrophotometer and LabQuest, cuvette, 25-mL buret (3), ring stand, buret clamp (2), 50-mL beaker (3), small plastic beakers Reagents SCN, as KSCN, 0.00200 M solution Fe; as Fe(NO), 0.00200 M solution and a...
Please help with solving Question 1 (A-C) Thank you!
Unless otherwise specified in the problem, you may assume that all solutions are at 25°C. 1. 50.0 mL of a pH 6.00 carbonic acid buffer is titrated with 0.2857 M NaOH, requiring 17.47 mL to reach the second equivalence point. a. Calculate the molarity of carbonic acid and bicarbonate in the original buffer. Carbonic acid: Bicarbonate: b. Calculate the pH of the solution after a total of 100.0 mL of 0.2857...
5. What was the purpose of the NaNO3 solution in this experiment? 6. Could a solution of NaCl be used instead of NaNO3? 7. What was the purpose of FeSO4 solution in this experiment? 8. Could a solution of FeCl, be used instead of FeSO4? 9. Could a solution of NaSO4 be used instead of FeSO4? 10. Calculate the standard cell potential for the spontaneous redox reaction between a Pb(s)/Pb(NO3)2(aq) half-cell and a Ag(s)/AgNO3(aq) half-cell. Which metal would be oxidized?...
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