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13. 1. LDA 2. CHI 14. [Hint: think alpha carbon, first.] 0 1) Brz/PBrg OH 2)...
9-17. Syntheses (continued): 13. 1. LDA 2. CH 14. [Hint: think alpha carbon, first.) 1) Brz/PBry OH 2) CH3NH2 15. React PhCH2CHO with hydroxide and provide its aldol-addition product. Then, apply heat to produce its final product. (6 pts) 16. React with methoxide, then heat. Be sure to show the intermediate carbanion, then the Dieckmann product. Finally, hydrolize and provide the final product. CO CHE 1. NaOCH 2. H30 CO, CHE 17. Perform a crossed Claisen condensation reaction with methyl...
biologi 14. [Hint: think alpha carbon, first.) 1) Brz/PBT3 2) CH3NH2 он 15. React PhCH2CHO with hydroxide and provide its aldol-addition product. Then, apply heat to produce its final product. (6 pts) 16. React with methoxide, then heat. Be sure to show the intermediate carbanion, then the Dieckmann product. Finally, hydrolize and provide the final product. COUCHE 1. NaOCH, 2. H,0 .COCH 17. Perform a crossed Claisen condensation reaction with methyl benzoate and cyclohexanone under basic conditions.
10-18. Syntheses (continued): 14 1. LDA 2 сны 15. (Hint: think alpha carbon, first.) 1) Brz/PBry 2) CH3NH2 OH 16. React PhCH2CHO with hydroxide and provide its aldol-addition product. Then, apply heat to produce its final product 17. Perform the Claisen reaction using methyl phenylacetate. (6 pts) 18. React with methoxide, then heat. Be sure to show the intermediate carbanion, then the Dieckmann product. Finally, hydrolize and provide the final product. CO CH 1. NaOCH 2. H,0 CO.CH
10-18. Syntheses (continued): 14. 1. LDA 2 оны 15. (Hint: think alpha carbon, first.) 1) Brz/Per 29 CHẠNH OH 16. React PhCH2CHO with hydroxide and provide its aldol-addition product. Then, apply heat to produce its final product 17. Perform the Claisen reaction using methyl phenylacetate. (6 pts) 18. React with methoxide, then heat. Be sure to show the intermediate carbanion, then the Dieckmann product. Finally, hydrolize and provide the final product. Cook CO.CH 1. NOCH 2. H,0
14. [Hint: think alpha carbon, first.]
14. [Hint: think alpha carbon, first.] 1) Brz/PB3 OH 2) CH3NH2
HW 22: Enolates 1. Provide a detailed, stepwise mechanism for the base-catalyzed enolization (keto enol tautomerism) of acetaldehyde. 2. Provide the major organic product of the folowing reaction. 3. Provide the major organic product of the following reaction LDA 4. Which of the following ketones will give a positive iodoform test? A) 4-heptanone D) cyclohexanone B) 3-hexanone C)2-hexanone 5. Provide the major organic product of the following reaction. 6. Provide the structure of the major organic product which results when...