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One mole of solid Cr2O3 at 2500 K is dissolved in a large volume of a...

One mole of solid Cr2O3 at 2500 K is dissolved in a large volume of a liquid Raoultian solution of Al2O3 and Cr2O3 in which xCr2O3 = 0.2 and which is also at 2500 K. Calculate the changes in enthalpy and entropy caused by the addition. The normal melting temperature of Cr2O3 is 2538 K; assume that the ΔSm,Al2O3 = ΔSm,Cr2O3 [= 46.25 J/(mol.K)].

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solution. ginen mole of solid (820₂,n=1mol, T = 2500k mol fraction of c82oz in solution (Al2O3+ (203) x7203 -0.2 Dsmi = 46.25change In entropy of mixing Dsmix =nRsnoluxi As mix = - nR (x luxta luxa) Xr203 0.2 Mones 0,2 smol 02 DSmix smol x 81314 I (0

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