Standard solutions of [Fe(SCN)2-] were prepared and their absorbance measured in order to study the Keq for the reaction
Fe3+ + SCN- <=> FeNCS2+
A plot of absorbance verses concentration of [Fe(SCN)2-] is shown below.
To determine the Keq for the above reaction, 10.00 mL of 0.00200 M Fe(NO3)3 solution is mixed with 5.00 mL of 0.0020 M KSCN and diluted with 5.0 mL 0f 0.10 M HNO3. The absorbance of this red solution is found to be 0.322. Answer the following questions in sequence to determine Keq:
What is the mole of SCN- initially placed in the reaction mixture?
Question 7 options:
1.11 x 10-4 |
|
2.22 x 10-6 |
|
2.22 x 10-4 |
|
1.00 x 10-5 |
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Standard solutions of [Fe(SCN)2-] were prepared and their absorbance measured in order to study the Keq...
Keq determination 1 0.9 2900X 0.00 R -0.9985 08 Absorbance 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 0.00005 0.0003 0 0.00035 0.0001 0.00015 0.0002 0.00025 Concentration of Fe(SCN)2-(M) To determine the Key for the above reaction, 10.00 mL of 0.00200 M Fe(NO3); solution is mixed with 5.00 ml of 0.0020 M KSCN and diluted with 5.0 ml of 0.10 M HNO3. The absorbance of this red solution is found to be 0.322. Answer the following questions in sequence to...
For the reaction Fe3+ + SCN 1- FeSCN2+ 9.00 mL of 0.00800M Fe(NO3)3 were diluted to a volume of 450.0 ml, then... 4.00 mL of the diluted Fe(NO3)3 were mixed with 4.00 mL of KSCN and 4.00 mL of HNO3. Calculate the initial concentration of Fe3+ at the time of mixing. Short answer LE- _ (no extra Scientific notation format spaces) How many mL of 0.00200 M Fe(NO3)3 are required to prepared 12.50 mL total volume with a concentration of...
help with finding the equilibrium of [Fe(SCN)^2+] morality value Equilibrium Solutions Data 1. Use your "Absorbance of Solution" values and the graph you made above to interpolate the "Equilibrium [Fe(SCN)]" molarity values. 2. Calculate both the "Initial [Fe ]" and the "Initial [SCN']" molarity values using then dilution equation CiVi C2V2. 3. Calculate the "Equilibrium [Fe ]" molarity values by subtracting the "Equilibrium [Fe(SCN) " molarity values from the "Initial [Fe'" molarity values. 4. Calculate the "Equilibrium [SCN']" molarity values...
How do I calculate [SCN-]i given that: Stock [Fe3+] = 0.00200 M Stock [SCN-] = 0.00200 M [Fe+3] [SCN]: of Table 2. Initial Data to Determine Keq Trial Volume Volume Total | Absorbance of Fe+3 volume KSCN(mm) (mm) (mL) hao 5.00 10.00 10.110 | 2 200 5.00 10.00 0.225 3 3.00 5.00 10.00 0.359 4 4.00 5.00 10.00 0.479 5 5.00 5.00 10.00 0.626 11.00×10 -3 2.00x104
Im still not understanding how to calculate the molarity of Fe(SCN)^2+ I have the absorbance for them but I dont know what to do from there. I would really appreciate the help. please and thank you. H115 lab manual_rev2016_MOD19AUG18_JSchesser.pdf (2.82 MB) Page < 65 > of 130 Tortas experiment unless you can measure their absorbance values within one hour 0 - ZOOM + Label 6 screw top test tubes A-F Using pipets, measure the solutions as outlined in the table...
4.81 mL of 0.00200 M Fe(NO3)3, 2.85 mL of 0.00200 M KSCN and 2.34 mL of distilled water were mixed. The resulting solution was allowed to attain equilibrium at 24 oC. The absorbance of the equilibrium solution was recorded, and the [FeSCN2+] was determined graphically to be 7.58 x 10-5 M. Part A: Calculate the number of moles of Fe3+ initially added to the solution. Part B: Calculate the number of moles of FeSCN2+ formed in the solution at equilibrium....
Table A. Preparation of Standard solutions of FeSCN2+ 1.0 M HNO3 0.002 M 0.200 M Solution KSCN (mL) Fe(NO3)3 (mL) 0.5 5 [FeSCN2+] (mol/L)* 1 4.0x10^-5 Add 1.0 M 2 1.0 5 8.0x10^-5 HNO3 3 1.5 5 1.2x10^-10 4 2.0 5 1.6x10-4 to each to adjust the volume to 25 mL. 5 2.5 5 2.0x10-4 * Calculate the concentrations of FeSCN2+ in each beaker, assuming that all SCN-ions exist as FeSCN2+. In other words, [FeSCN2+] (in Soln 1) = [SCN-]...
1. You prepare a mixture to use to create a colorimetry calibration curve for FeSCN2+ by mixing these things in a 25.00 mL volumetric flask and then diluting to the volume of the flask with 0.3 M HNO3. 5.00 mL 0.00200 M NaSCN 10.00 mL 0.30 M Fe(NO3)3 What is the concentration of FeSCN2+ in this mixture? [Pay attention to the values to determine which reactant is being driven to completely react...] 2. You prepare a mixture to use to...
Determination of an Equilibrium Constant 1) If 20.0 mL of 0.00200 M Fe(No3)3 is diluted to 50.0 mL, what is the concentration of Fe^+3 in the diluted solution? 2) Write the equilibrium for the following reaction. Co^+2 +4SCN^-1 <--> Co(SCN)4 ^-2 3) How many mmoles of SCN^-1 ion are there in 3.0 mL of 0.00200 M KSCN?
A student made solution #3 using the experimental method in this lab, and measured an absorbance of 0.559. The starting reagents are 2.00 x 10-3 M Fe(NO3)3 and 2.00 x 10-3 M KSCN. The amount of absorption is proportional to the concentration of FeSCN2+. This relationship – true for many solutions – is called “Beer’s Law”, and has the simple equation: A = bc where “A” is the absorption, “b” is 5174.6 for FeSCN2+ and “c” is molarity Make Five...