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Question 20 (5 points) Using the following standard reduction potentials: PbO2 + 4H+ + SO42- +...
Question 20 (5 points) Using the following standard reduction potentials: PbO2 + 4H+ + SO42- + 2e → PbSO4(s) + 2H20 E° = +1.69 V PbO2 + 4H+ + 2e Pb2+ + 2H20 E° = +1.46 V is The standard cell voltage for the reaction PbSO4(s) → Pb2+ + SO42- V. Please enter your answer in decimal form, such as 2.5, and keep the correct number of significant figures.
Question 22 (5 points) Given the following half reactions: PbO2 + 4H+ + SO42- + 2e → PbSO4(s) + 2H20 E° = 1.69V PbO2 + 4H+ + 2e- → Pb2+ + 2H2O E° = 1 .46V Calculate the Ksp for PbSO4 at 25 degrees C. Please enter your answer in scientific notation, such as 1.2E10 or 1.2E-10 and keep two significant figures.
You want to make a battery using the following reactions: PbO2 + 4H+ + SO42- + 2e ---> PbSO4(s) + 2H20 Ni2+ + 2e ---> Ni ° = +1.69 E° = -0.25 Which is being reduced? Which is being oxidized? Which is the anode? Which is the cathode? What is the formula to calculate Eºcell? What is Eºcell?
The standard half-cell reactions of lead acid battery is: 2) ЕФN Half-cell reduction reaction form: red PbOo2.(s) 4H+ + so2 4, (aq) PbSO4,()+2H20 Red 2e 1.69 Рo) + So?- 4.(aq) -Ox -0.36 Pbs04.(s)2e Pb()PbO2,(s)+ 2H2SO4,(ag) 2P6SO4.(6) +2H20D 2.05 Tot. a) Determine the full cell reaction of lead acid batter and the total cell potential when discharging the battery b) The half-cell potentials are given according to a reference potential. Describe this reference potential. What is the point of a reference...
The standard half-cell reactions of lead acid battery is: 2) Half-cell reduction reaction form: red 1.69 +4Ht +so +2ePbSO4,()+2H2O) РЬОог.0) Red (aq) -Ox. PbSO4.()+2e Pb)+SO -0.36 4.(aq) Pb()+PbO2.(s)+2H2SO4.(ag) Tot. 2PBSO4.()+ 2H20() 2.05 a) Determine the full cell reaction of lead acid batter and the total cell potential when discharging the battery. I b) The half-cell potentials are given according to a reference potential. Describe this reference potential. What is the point of a reference potential?
5. A lead storage battery involves the following two half-reactions: PbSO4(s) + 2e → Pb(s) + SO42- (aq); E = -0.36 V PbO2(s) + 4H*(aq) + SO42 (aq) + 2e → PbSO4(s) + 2H2O(1); E° = 1.69 V In the lead battery during the discharge reaction: A) PbSO4 is the cathode. B) PbSO4 is the anode. C) Pb is the anode. D) PbO, is the anode. E) H2SO4 is the cathode.
For all of the following experiments, under standard conditions, which species could be spontaneously produced? A lead wire is placed in a solution containing Cu2+ yes no Cu yes no PbO2 yes no No reaction Crystals of I2 are added to a solution of NaCl. yes no I- yes no No reaction yes no Cl2 A silver wire is placed in a solution containing Cu2+ no yes Cu no yes No reaction no yes Ag+ Half-Reaction 8° (V) Half-Reaction 8° (V) 2.87 1.99 1.82 1.78 1.70 1.69 1.68 1.60...
Use the galvanic cell notation to describe the Daniell cell. (4 marks) Using the reduction potential table calculate Eº for the Daniel cell. 12 marks) Calculate the equilibrium constant K for the reaction Cu2+ + Zn → Cu + Zn²+, at 25 °C. (4 marks) Standard Potentials at 25°C Half Reaction Potential Potential +2.87 V 0.000 V +2.07 V -0.04 V +2.05 V -0.13 V -1.69 V -0.14 V +1.69 V -0.23 V +1.67 V -0.26 V +1.63 v -0.28...
Selective Reduction The standard reduction potential for the half-reaction: Sn4+ + 2e - Sn2+ is +0.15 V. Consider data from the table of standard reduction potentials for common half-reactions, in your text. For a galvanic cell under standard conditions, which of the following anodic half reactions would produce, at the cathode a spontaneous reduction of Sn4+ to Sn2+ but not Sn2+ to Sn. no yes yes yes yes yes Fe — Fe2+ + 2e- Sn2+ Sn4+ + 2e- Sn Sn2+...
Calculate the maximum amount of work that can be obtained at 25°C from an electrochemical cell using Cd and PbO2 electrodes. HINT: Write a balanced chemical reaction first. Reduction Half Reaction Standard Reduction Potential (E"[v] PbO2(s) + 4H(aq) + 2e-Pb2+ (aq) + 2H2010 1.46 V Ca2+ (aq) + 2e + Ca(s) -0.40 V 179) 205 k) 0 102 kJ 0 359K 673 kJ