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1. A voltaic cell is constructed from a Al/Al half-cell (Ered -1.66 V) and a Fe/Fe? half- cell (Ered-0.44V) Give the oxidation half reaction and Eox, the reduction half reaction and Ered, and the overall reaction and Ecell: Oxidation: Reduction: red E cell Overall Reaction: 2. For the cell Fe(s) Fe2+ | Pb* | Pb), the standard cell potential is +0.31 V. A cell using these reagents was made, and the observed potential was +0.37 V at 25°C. A) What is the overall reaction occurring in this cel? B) Which of the following is a possible explanation for the observed voltage? a) The Fe electrode is twice as large as the Pb ekectrode c) The Pb 2 concentration is smaller than the Fe2 concentration. d) The concentrations are the same, but the volume of the Pb2 solution is larger than the volume of the Fe solution. e) The concentrations are the same, but the volume of the Fe solution is larger than the volume of the Pb+ solution. C) Calculate the Fe2+ concentration in the above cell, given that the Pb2+concentration is 0.30M
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