Provide the structure of the major organic product of the reactions below.
This is wittig reaction [You asked for only major product]
1) the first step is nucelophilic substitution in alkyl halide with triphenylphosphine
2) the second step is abstraction of hydrogen by the base (sodium ethoxide) to give phosphorous Ylide.
3) The ylide attacks on the carbonyl carbon as nucelophile and finally rearrange to give alkene.
The reactions will be
a)
b)
Provide the structure of the major organic product of the reactions below. a. b. Br 1....
Which of the compounds shown below would be the major organic product of the set of reactions shown? 0 Eto V 1) NaOEt 0 2) Br OEt 3) H3O+/A. Но HO Eto Eto C
Provide the major product(s) for the following Provide the major product(s) for the following reactions. Be sure to note stereochemistry and racemic mixtures. NaOH, H29 2 100 °Ç ? NaOH, H2O H 0°C H W H CCl3 OC (provide product of both steps) H a. Hn b. CHEM 370 W13 Homework Page 1 of 2 giorel Noot Hoi solu NOEL IN DER NaOH, H2O 100 °C Hv NaOET, H OEt EtOH 8. Eto- i. LDA, -78°C NaO Me MeOH Оме...
E2 reactions major product Provide the structure of the major organic product of the reaction be CH3 NaOCH,CH CH3CH2OH Br
QUESTION 4 Which of the compounds shown below would be the major organic product of the set of reactions shown? 1) NaOEt 2)~ Br Eto V OEt 3) H2O+IA Ι Eo Eto B Ο Ο Ο Ο
1. For each of the following reactions, provide the structure of the major organic product(s). Show all the relevent stereochemistry clearly. who CH2OH reflux CH2CH3 Na SET Br DMSO, 20 °C I- A to CH2CH3 CH3 H- EtOH OTS 20 °C Me NaNH2 NH2 DMSO dilute solution of substrate 2. Complete each of the following reaction by providing reagents and conditions (solvent. temperature, concentration, etc.) so that the product shown will be the major one. Note: for c), two steps...
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3) KOtBu 2) O 1) NaOH on. Br 2) O o
3. Give the major organic product(s) of each of the following reactions or sequences of reactions. Br2 CH3COOH OH 1. Bry, PB 2. H2O CH, III 13, NaOH (excess) HC-C-C- CH H20 CH; 1.2 equiv. NaOet, EtOH VOE2.AAB O= OE: + (CH),CHCHCH,Br 1. NOE! EtOH 2.H20, heat
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3) KOtBu 2) O 1) NaOH on. Br 2) O o 1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он...
3. (5) Complete the following reactions by drawing the structure of the principal organic product formed Ph Cl trace NaOH EtOH heat Br,Zn, THF Ph H dil dil Hyo at H,SO beatTHF (workup) HgClh, H20 CaCO3, CHCN BuLi, THFH NaH, OCHs dil H O heat (1.0equv) (workup) 0 NaOEt trace NaOEt EtOH, heat EtOH
1. Draw the major product formed from the following elimination reactions. (4 pts) NaOET EtOH, heat 85% H3PO4 १ 80°C heat Y Br + BOKBLOH host + t-BUOKA-BOH EtOH TH + Naget 55°C