Given below is the detailed mechanism for the reduction of ester and ketone by LiAlH4
(a) Here ester is getting reduced to an primary alcohol. the first step is attack of hydride and loss of a OEt- group from the ester to form an aldehyde. the aldehyde is then attacked by a hydride. the intermediate is then broken down by basic aqueous solution to form the alcohol.
(b) Here a ketone is getting reduced to an secondary alcohol. The hydride attacks the carbonyl carbon to form an oxo species. Three more molecules of ketone gets attacked by the remaining hydrides on Al. Basic workup in aqueous medium yields the desired end product.
please the mechanism...
4. Draw the mechanisms for the following reactions to nredict the products. CI clue AICI,
draw the major product and mechanisms for each of the
following reactions
1) LiAl(OBu)3H 2) H30+ он 1) SOCl2 pyridine 2) Me Culi
1) LiAl(OBu)3H 2) H30+ он 1) SOCl2 pyridine 2) Me Culi
Draw the mechanisms and products of the following reactions. Do not
forget to add lone pairs as needed. Proton transfer (PT) steps are
explicitly indicated for you. You should not include any more.
Draw the mechanisms and products of the following reactions. Do not forget to add lone pairs as needed. Proton Transfer (PT) steps are explicitly indicated for you. You should not include any more. 1) The base promoted hydrate formation i OH H2O 2) The acid catalyzed acetal...
Draw the reaction mechanisms of the following reactions: a) Adipic acid with NaOH b) Adipic Acid with Sodium Bicarbonate c) Adpic Acid with HCl
Draw The arrow pushing mechanisms of the following reactions: (6pts
each, 18 pts total)
U Draw the arrow-pushing mechanism of the following reactions: (6pts each, 18pts total) U Question 8 6 pts ОН OH Upload Choose a File Question 9 6 pts H,09 Brz Upload Choose a File Question 10 6 pts KOH + Lo & MeOH, Heat Upload Choose a File
Can someone explain the mechanisms + products for these
reactions?
1. (3p) Draw the mechanism and the expected reaction product for the following reaction: ? 2. (3p). Draw the mechanism and the expected Nucleophilic Substitution Reaction Product for the following reaction: ? OH
Propose a mechanism for the following reaction:
11. Propose mechanisms for the following reactions. Draw all arrows, lone pairs, formal charges, counter ions, and label all reaction steps (e.g. proton transfer, loss of leaving group, etc.). A. (13 pts) CH:NH 2 N N - CH3 Cl
Draw the structures of the produce(s) formed in the alkylation reactions, showing the mechanisms
2. Draw mechanisms for the following reactions (a. 3 points, b. 2 points). a) من ΕΙΟ, ΕΙΟΗ Phi, Eto Bro Ph Et Ph Ph. NaOH, H20 sono go OH
General Organic Chemistry Homework I) Draw mechanisms and products for the following SN2 reactions. Use arrows to show electron movement. The reaction of 1-bromobutane with: a) OH- b) CH,CH2OK Na d) e) NH