Draw the structure of solid precipitate that forms when sulfuric acid is added to the solution of p-aminobenzoic acid in ethanol, "before the Esterification reaction" occurs.
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Draw the structure of solid precipitate that forms
when sulfuric acid is added to the solution...
b: Before neutralization the solution (is acidic/is basic) and the (protonated amino group/deprotonated amino group/protonated ester...
b: Before neutralization the solution (is
acidic/is basic) and the (protonated amino group/deprotonated amino
group/protonated ester group) makes benzocaine soluble in the
aqueous solution. When the sodium carbonate is added, the (amino
group is deprotonated/amino group is protonated/ester group is
deprotonated) and the neutral benzocaine produced has a (low
solubility in water/high solubility in water/higher density than
water).
The local anesthetic, benzocaine, can be prepared by the direct esterification of p-aminobenzoic acid with ethanol, using sulfuric acid as the catalyst....
What is the mechanism for this reaction Chapter 20 Carboxylic Acids and Their Derivatives 655 O2H...
What is the mechanism for this reaction
Chapter 20 Carboxylic Acids and Their Derivatives 655 O2H O2CH2CH3 + CH CH20H onc. HSO4 (catalyst) + H2O (20.4) NH2 16 p-Aminobenzoic acid NH2 17 Ethyl p-aminobenzoate (benzocaine) The equlibrium between the starting materials and products is readily estab- lished by heating a mixture of 16 and ethanol under reflux in the presence of a cata- lytic amout of sulfuric acid to give 17 and water (Eq. 20.4). However, if a microwave apparatus...
I need help with calculating the percent yield of an experiment. 1.0 g of p-aminobenzoic acid...
I need help with calculating the percent yield of an experiment. 1.0 g of p-aminobenzoic acid (MW=137.14 g/mol) was mixed with 10.0 mL of absolute ethanol (MW=46.07 g/mol) and after solid dissoved 1.0 mL of conc. sulfuric acid was added (MW=98.07 g/mol). The crude product of benzocaine (MW=165.19 g/mol) weighed 2.289 grams. What is the theoretical yield? What is the percent yield?
Why is sulfuric acid added in an Esterification reaction? (SELECT ALL THAT APPLY) a. It neutralizes...
Why is sulfuric acid added in an Esterification reaction? (SELECT ALL THAT APPLY) a. It neutralizes base produced in the reaction. b. It pushes the reaction to completion by dehydrating the product. c. It is used as a polar protic solvent d. It activates the carbonyl of p-aminobenzoic acid making it more reactive. e. A low pH is needed for the reaction to occur Which following statement statements is wrong for Benzocaine? (SELECT ALL THAT APPLY) A. It is an...
EXPERIMENT XVII - SYNTHESIS OF BENZOCAINE Benzocaine is prepared by the of a carboxylic acid with...
AAnswer supplementary questions:
1 to 3
EXPERIMENT XVII - SYNTHESIS OF BENZOCAINE Benzocaine is prepared by the of a carboxylic acid with cthanol. The reaction is: 0 OCH2CH3 + CH CH OH NH NH and Non-Standard Equipment Chemicals absolute ethanol vacuum filter set-up stirring bans concentrated sulfuric acid boiling stones litmus paper 10% sodium carbonate Procedure Dissolve 1.2 g of p-aminobenzoic acid and 12 mL of absolute ethanol in a 100 mL round bottom flask. While swirling, add 1.0 mL...
When you write the answers, please write the page number for which the question is located....
When you write the answers, please write the page number for
which the question is located. Thank you!
Experiment 8 Name: Double Replacement Reactions Background: Some reactions have the net effect of causing the cation of cach reactant to trade places, forming a compound with the other anion. These reactions are known as double replacement reactions. In the example below (unbalanced equation), the barium and sodium cations switch places so that barium forms a product with sulfate while sodium forms...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification Reactions Q: Calculate the expected mass of both methyl salicylate and aspirin assuming 100% yield. EXPERIMENT7 PREPARATION OF PHARMACEUTICALS...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification
Reactions
Q: Calculate the expected mass of both methyl salicylate and
aspirin assuming 100% yield.
EXPERIMENT7 PREPARATION OF PHARMACEUTICALS Fischer Esterification Reactions Almost 2500 years ago, physicians such as Hippocrates recommended that patients chew on the bark of the willow to alleviate pain. The active ingredient in willow bark was found to be salicin, a compound made of a molecule of salicyl alcohol bonded to a p-D-glucose molecule. In the stomach, the bond between...
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an...
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an amine e. no reaction c. an aldehyde Which of the following combinations will react spontaneously? A. 12 + Cu2+ B. Pb2+ + Ag C. Zn2+ + Mg D. Sn2+ + Ni2+ The general formula for a cycloalkane can be represented by which of the following? a. C,H, C. CH b. C.H2n+2 d. C.H21-2 In a certain reaction AH =-136 kJ and E, = 96...
4.30. Using solubility rules, predict the solubility in water of the following ionic compounds. a. AI(OH) b. CaN...
4.30. Using solubility rules, predict the solubility in water of the following ionic compounds. a. AI(OH) b. CaN C. NH4CI d. KOH 4.32. Using solubility rules, decide whether the following ionic solids are soluble or insoluble in water. If they are soluble, write the chemical equation for dissolving in water and indicate what ions you would expect to be present in solution. (NE SO b. BaCO c. Pb(NOs)2 d. Ca(OH) 4.34. Write net ionic equations for the following molecular equations....
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23,...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
b: Before neutralization the solution (is
acidic/is basic) and the (protonated amino group/deprotonated amino
group/protonated ester group) makes benzocaine soluble in the
aqueous solution. When the sodium carbonate is added, the (amino
group is deprotonated/amino group is protonated/ester group is
deprotonated) and the neutral benzocaine produced has a (low
solubility in water/high solubility in water/higher density than
water).
The local anesthetic, benzocaine, can be prepared by the direct esterification of p-aminobenzoic acid with ethanol, using sulfuric acid as the catalyst....
What is the mechanism for this reaction
Chapter 20 Carboxylic Acids and Their Derivatives 655 O2H O2CH2CH3 + CH CH20H onc. HSO4 (catalyst) + H2O (20.4) NH2 16 p-Aminobenzoic acid NH2 17 Ethyl p-aminobenzoate (benzocaine) The equlibrium between the starting materials and products is readily estab- lished by heating a mixture of 16 and ethanol under reflux in the presence of a cata- lytic amout of sulfuric acid to give 17 and water (Eq. 20.4). However, if a microwave apparatus...
AAnswer supplementary questions:
1 to 3
EXPERIMENT XVII - SYNTHESIS OF BENZOCAINE Benzocaine is prepared by the of a carboxylic acid with cthanol. The reaction is: 0 OCH2CH3 + CH CH OH NH NH and Non-Standard Equipment Chemicals absolute ethanol vacuum filter set-up stirring bans concentrated sulfuric acid boiling stones litmus paper 10% sodium carbonate Procedure Dissolve 1.2 g of p-aminobenzoic acid and 12 mL of absolute ethanol in a 100 mL round bottom flask. While swirling, add 1.0 mL...
When you write the answers, please write the page number for
which the question is located. Thank you!
Experiment 8 Name: Double Replacement Reactions Background: Some reactions have the net effect of causing the cation of cach reactant to trade places, forming a compound with the other anion. These reactions are known as double replacement reactions. In the example below (unbalanced equation), the barium and sodium cations switch places so that barium forms a product with sulfate while sodium forms...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification
Reactions
Q: Calculate the expected mass of both methyl salicylate and
aspirin assuming 100% yield.
EXPERIMENT7 PREPARATION OF PHARMACEUTICALS Fischer Esterification Reactions Almost 2500 years ago, physicians such as Hippocrates recommended that patients chew on the bark of the willow to alleviate pain. The active ingredient in willow bark was found to be salicin, a compound made of a molecule of salicyl alcohol bonded to a p-D-glucose molecule. In the stomach, the bond between...
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an amine e. no reaction c. an aldehyde Which of the following combinations will react spontaneously? A. 12 + Cu2+ B. Pb2+ + Ag C. Zn2+ + Mg D. Sn2+ + Ni2+ The general formula for a cycloalkane can be represented by which of the following? a. C,H, C. CH b. C.H2n+2 d. C.H21-2 In a certain reaction AH =-136 kJ and E, = 96...
4.30. Using solubility rules, predict the solubility in water of the following ionic compounds. a. AI(OH) b. CaN C. NH4CI d. KOH 4.32. Using solubility rules, decide whether the following ionic solids are soluble or insoluble in water. If they are soluble, write the chemical equation for dissolving in water and indicate what ions you would expect to be present in solution. (NE SO b. BaCO c. Pb(NOs)2 d. Ca(OH) 4.34. Write net ionic equations for the following molecular equations....
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
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