Variation of the rate constant with temperature for the first-order reaction 2N2(g) + O(g) → 2N2O4(g) is given in the following table. Determine the activation energy and pre-exponential factor for the reaction. What would be the rate constant at 350 K?
Temperature / K | Rate Constant / s-1 |
273 | 7.87 x 103 |
298 | 3.46 x 105 |
318 | 4.98 x 106 |
338 | 4.87 x 107 |
What is the activation energy in kJ/mol? Do not enter the units with your answer.
What is the pre-exponential factor?
What is the rate constant at 350 K?
Variation of the rate constant with temperature for the first-order reaction 2N2(g) + O(g) → 2N2O4(g)...
3(12) The first-order reaction, 2N2O(g) + 2N2(g) + O2(g), has a rate constant of 0.76 s at 1000K. (a) Calculate the half-life of this reaction at 1000K. (b) How long will it take for the concentration of N20 to fall to 25% of its initial value at 1000K (c) How long will it take for reaction to be 90% complete? (d) If the half-life of the same reaction is 29 min at 800K, what is the rate constant at 800K?...
#14 Rate Constant and Temperature 1. The rate constant (k) for a reaction was measured as a function of temperature. A plot of lnk versus 1/T (in K) is linear and has a slope of -1.01 x 104 K. Calculate the activation energy for this reaction. 2. The rate constant of a reaction at 32.0oC is 0.0550 s-1. If the frequency factor is 1.20 x 1013 s-1, what is the activation energy? 3. A reaction has a rate constant of...
Question 6 2 pts The variation of the rate constant with temperature for the decomposition of HI to H2 and 12 is given here. What is the activation energy for this reaction? 2 HI(g) -> H2 (8) + 12 (8) Temperature (K) Rate constant, 555 3.52 x 107 781 3.95 x 10-2 ho 1.1 x 10J/mol O 1.8 x 10$/mol 179 J/mol O 2.0x 10J/mol
The rate of a certain reaction was studied at various temperatures. The table shows temperature (T) and rate constant (k) data collected during the experiments. Plot the data, and then answer the following questions. What is value of the activation energy, Ea, for this reaction? What is the value of the pre-exponential factor (sometimes called the frequency factor), A, for this reaction?
the Arrhenius Equation for the rate constant ka zpe is the number of collisions per second, and p is the orientation factor For the reaction A B , z = 1012 collision per second, and p = 0.5. At a temperature T 300.0 K, how many effective collisions occur per second CASO SO,000 17. The rate constant (ka) of a reaction is 3.46 X 102/sec at 298 K. What is the rate constant (kz) at 350.0 K, if the activation...
The rate constant for the reaction of nitrogen with oxygen was determined at four temperatures. N2(g) + O2(g) + 2NO(g) T(K) 250 275 k(cm3/moleculeos) 7.18 x 10-8 1.36 x 10-7 2.31x 10-7 3.46 x 10-7 300 325 Calculate the activation energy of the reaction. kJ/mol Part 2 (2 points) Calculate the frequency factor A for the reaction. x 10 cm3/moleculeos +
1) The rate constant for the reaction 2 N,Os(9) = 4 NO (9) + O2(9) is reported in units of sl. What is the overall order of the reaction? 2) The rate law for a reaction was reported as rate=k[A] [B][C] with molar concentrations in moles per cubic decimetre and time in seconds. What are the units of k? 3) The rate constant for the pseudo first-order acid- catalysed hydrolysis of glucose is 4.07' 10-s. Calculate the half-life for the...
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If a first-order reaction has a rate constant of 2.11 x 10-1 s-1 at a temperature of 22.3°C, what would the value of k be if the reaction temperature has changed to 43.4 °C given the activation energy is 52.9 kJ/mol?
Reaction Rates and Temperature 31 Review Constants i Peric The rate constant of a chemical reaction increased from 0.100 - 2005 - pon raising the temperature from 250 C 350 C Learning Goal To use the Athenius equation to calculate the activation energy As temperature rises, the average kinetic energy of molecules increases. In a chemical reaction, this means at a higher percentage of the molecules possess the required activation energy and the reaction goes faster. This relationship is shown...