6. (10 points) Give the structures of compounds A through Hin the following series of reactions....
Write complete equations (using structures) to the following sequence of reactions and give the structures of compounds A through I. Neatness counts B AICI, HNO3 A H2SO4 Zn(Hg) HCI KMnO4 с (hot, concd.) D NH, Br₂ hv NH (CH),COK Heat Cyclopentadiene/Heat G H E | NaOCH F Write complete equations (use structures) for each of the following conversions. Include appropriate reagents.
Write complete equations (using structures) to the following sequence of reactions and give the structures of compounds A through I. Neatness counts B AICI, HNO H2SO4 Zn(Hg) HCI KMnO с (hot, coned.) D NH BIZ NH, hv (CH3),COK E Heat NaOCH Cyclopentadiene/Heat G H F
Write complete equations (using structures) to the following sequence of reactions and give the structures of compounds A through I. Neatness counts اد B AICI, HNO, H SO Zn(Hg) HCI KMnO С (hot, concd.) D NH Br2 hv NH, Cyclopentadiene/Heat G H (CH3),CO-K E Heat NaOCH, 1 F
Write complete equations (using structures) to the following sequence of reactions and give the structures of compounds A through 1. Neatness counts B AICI, D ΗΝΟ, H,SO Za(Hg) HCI KMnO с hot, concd.) Brz (CH),COK E Heat NaOCH, NH NH Cyclopentadiene/Heat G F Write complete equations (use structures) for each of the following conversions. Include appropriate reagents. Benzene -> A A-> Ac C->D C->E E->G G-> E-> F E-> 1 => React with (CH.CO),0, N(C2Hs)
1. Predict the major product for the following reaction. (12 points) CN Zn(Hg/HCI 1. LIAIHA 2. H3O+ a 1. LIAIH mCPBA NaN3 b 2. H20 + enantiomer С. NH2 N,CI CN COOH d NaCN 1. LIAIHA Br 2. H20 e. (CH3)2NH H2SO4 2. H30*
1. Draw the product(s) of the following reactions HeCrO4 1. CH,COCVAICI 2. Zn (Hg)HCI 3. NBS (light) 1. KMnO4/H2SO4 og er CH3 NaNH2 NH3(0) 2. Show how you would synthesize the following compounds from toluene. OH O он Br
Draw the final product for the following reactions 6. Draw the final product for the following reactions 19 AICI 2) Zn, HCI 3) Brz, light (1 eq.) 4) NaOH, heat 1) KMnO4, hot 2) HNO3, H2SO4 3) LiAIHA 4) Hot 1) AICI3, tai 2) mCPBA 3) Jones Reagent
1. Write structures for the lettered organic product(s) in the following reactions: (4 pts each) H, CH2OH A 1) CHCI B 2) OH OH O== + с D + E Conc. KMnO4 OH/H,0 OH PBrz F CH2CH MgBr CH3MgBr H H30 1) 03 2) Zn, H20 2Eq. HBT H3C-CEC-H NaH H3C-C=C-H K
1. Predict the major product for the following reaction. (12 points) CN Zn(Hg) HCI 1. LIAH 2. H30+ 1. LIAIHA mCPBA NaN, 2. H₂O + enantiomer NH2 ON & CN COOH NaCN 1. LIAIH 2. H20 Br (CH3)2NH H2SO4 2. H30*
Which of following is the best starting material for the reaction below? 1. (CH3)2NH ? 2. LIAIHA 3. H20 'N NK CN NH2 What is the major product in the following reaction? 1. DIBAL 2. H20 O H O OH OH СІ Which reaction sequence would accomplish this transformation? CN H2SO4/HNO3 Br2 NaNO2/HCI CuCN O Br2/FeBr3 H2SO4/HNO3 KF NaNO2/HCI O H2SO4/HNO3 Zn(Hg)/HCI NaNO2/HCI CuCN o H2SO4/HNO3 Zn(Hg/HCI NaNO2/HCI HBF4