Compare and rationalize the rate constants for the aquation reactions of the following trans-cobalt(III) complexes: [Co(NH3)Br(en)2]2+...
Compare and rationalize the rate constants for the aquation reactions of the following trans-cobalt(III) complexes:
[Co(NH3)Br(en)2]2+ + H2O ? [Co(NH3)(H2O)(en)2]3+ + Br- k = 1.2 x 10-6 s-1
[CoBr2(en)2]+ + H2O ? [Co(H2O)Br(en)2]2+ + Br- k= 1.4 x 10-4 s-1
Homework Answers
the water molecules can be easily replaced bromine in the second complex very fast than the first complex.this we can be explained based on the rate constant values higher rate constant represent faster the reaction.The second aqua complex formation has higher rate constant value
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Compare and rationalize the rate constants for the
aquation reactions of the following trans-cobalt(III)
complexes:
[Co(NH3)Br(en)2]2+...
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and...
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and [Fe(NH3)6][Cr(CN)] (c) [CoBr(NH3)sSO4 and [CrSO4(NH3)s]Br (d) [Co(NO2)(NH3)s]Cl2 and [Cr(ONO)(NH3)s] Cl2 (e) Both (b) and (c) Review your answer (CIRCLE): Are you (1) confident; (2) somewhat confident; or (3) unsure/guessing?
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and [Fe(NH3)6][Cr(CN)] (c) [CoBr(NH3)sSO4 and [CrSO4(NH3)s]Br (d) [Co(NO2)(NH3)s]Cl2 and [Cr(ONO)(NH3)s] Cl2 (e) Both (b) and (c) Review your answer (CIRCLE):...
Name the following metal complexes or complex ions: formula name [ZnF] (en)2] [ TiBrz(co)] [c: (OH)(NH3),...
Name the following metal complexes or complex ions: formula name [ZnF] (en)2] [ TiBrz(co)] [c: (OH)(NH3), )* x 6 ?
Consider the following reactions: [Co(NH3)4] * + 6[H,O] → [Co(H2O) lt + 6[NH]" [Co(NH3)6]2+ + 6[H2O]*...
Consider the following reactions: [Co(NH3)4] * + 6[H,O] → [Co(H2O) lt + 6[NH]" [Co(NH3)6]2+ + 6[H2O]* $ [Co(H2O).]2+ +6[NH.] The first reaction proceeds over weeks (even when Kca= 1064) while the second reaction proceeds over seconds. Rationalize the difference in rates.
experiment on the synthesis of trans-dichlorobis(ethylenediamine)cobalt(iii)chloride 8.0 POST LAB QUESTIONS 1. How...
experiment on the synthesis of
trans-dichlorobis(ethylenediamine)cobalt(iii)chloride
8.0 POST LAB QUESTIONS 1. How will the Percentage Yield of your Product be affected if the product is a little damp when weighed? 2. Determine the Oxidation State and the Coordination Number of the Transition Metal lon in each of the following Complex lons: a) [Ni(H20).] b) [Mn(CN).* c) [CuCl] d) [Cr(NH3)* 3. Write a chemical equation representing what happens when each of the following water soluble Coordination Compounds dissolves in water. a)...
Nomenclature Coordinate Complexes | <Br< SCN < Cl< O=N-0 <F <OH <C:0-(oxalato) < 0,2-<H2O <SCN <NH;...
Nomenclature Coordinate Complexes | <Br< SCN < Cl< O=N-0 <F <OH <C:0-(oxalato) < 0,2-<H2O <SCN <NH; <en (H2NCH2CH2NH2) NO2 <CN <CO Formula Name # of lone de [Cr. (NH3)3 (+20)})( triamminetriaquachromium(III) chloride [Fe(NH3).](NO2) hexaammineiron (111) nitrate [pt leng (12232 dithicyanodi(ethylenediamine)platinum(IV) chloride [Co(C204)(CO)]* Owlbunyoleation contu) lon ammonium tetraiodicuprate(II) INHO), [LUIGI Ke[Fe(ONO).] [ Fel NH3)6] hexaammineiron(III) hexahydroxochromate(III) [Co(H2NCH2CH2NH3)4](SO4)3 | +r15 4+ hy • he ºlfa wine) ¢e bal} (1) v10a4e pentaaquahydroxoiron(III) ion [Fe(H2E), GH) +2. (NH4)[Ni(O2)2(H2O)2] ammunium cinquabiscova lato) nickelate CI) AN...
For each of the following complexes, draw the molecular structure and determine the effective ato...
please do answer all the questions below. thank you
For each of the following complexes, draw the molecular structure and determine the effective atomic numbers. (i) Na[Fe(CN)s(NH3)3l (i) [Cr(H2O)2(NH3)2(en)]Cl (ii) [Co(o-phen)2(NHs)(NCS))CI (iv) (n3-C3Hs)Co(CO)2] (v) [Fe(diphos)(CO)sl in which diphos Ph2PCH2CH2PPh2 and Ph CsHs (10 marks) (i)/ The K for Fe(OH)4]2-is found to be higher than that found in (5 marks) Zn(OH)4]2-and [Cr(OHM. Explain . Cho and coworkers used the following ligand to react with cobalt. Predict how this ligand would bind...
What is the coordination number for each of the following complexes or compounds? [Co(NH3)4Cl2]+ [Ca(EDTA)]2− [Pt(NH3)4]2+...
What is the coordination number for each of the following
complexes or compounds?
[Co(NH3)4Cl2]+
[Ca(EDTA)]2−
[Pt(NH3)4]2+
Na[Ag(CN)2]
Enter the coordination numbers, in the order that the complexes
are listed, as four integers separated by commas (e.g.,
1,2,3,4).
What is the charge on each of the following complex ions?
hexaaquairon(II), [Fe(H2O)6]?
tris(carbonato)aluminate(III), [Al(CO3)3]?
amminepentachloroplatinate(IV), [Pt(NH3)Cl5]?
Express the charges numerically, in the order that the complexes
are listed, separated by commas. For a nonzero charge, be sure to
include the sign (e.g.,...
can anyone confirm my answers for all of 2 and all of 4? 1. Name following...
can
anyone confirm my answers for all of 2 and all of 4?
1. Name following coordination complexes. (a) K][PdC1] (b) [Co(H2O),(NH3)4]2+ (b) [Mn(NH3),(En)]2+ (c) [CrCl,(NH3)4]CI, 2. State the coordination number and oxidation state of the following catalysts. (a) [Pt(CO) PPhz] (b) [Ni(C1).]2- (c) [Ir(Cl) (CO)En(PPhz)2]3+ (d)Liz[AuClo] 3. Define the following. (a) Ligand (b) Coordination number (c) Polydentate ligand (d) Primary valency 4. Write the formula of following coordination complexes. (a) Tris(ethylenediammine)cobalt(III) nitrate (b) Hexacyanomolybdate(II) (c) Tetrahydroxocuprate(II) (d) Sodium dibromidodichloridonickelate
1. (a) Give the systematic IUPAC names for each of the following complexes/ions (1) (NH4) [NiCl4]...
1. (a) Give the systematic IUPAC names for each of the following complexes/ions (1) (NH4) [NiCl4] (ii) [Cr(H204(NH3)2]2+ (iii) [Ru(en)(OH)2]* (iv) Nas[Co(ONO)5] (v) [Rh(ONO)(OX)2]* (vi) [FeBrz(en)2]* (vii) [Ag(y)][AgCl4] (viii) K[Pt(ONO)3(NO2)3] (ix) [Co(SO4)(NH3)s]* (x) Naz[PdCl4]
please do answer all the questions below. thank you For each of the following complexes, draw...
please do answer all the questions below. thank you
For each of the following complexes, draw the molecular structure and determine the effective atomic numbers. (i) Na[Fe(CN)s(NH3)3l (i) [Cr(H2O)2(NH3)2(en)]Cl (ii) [Co(o-phen)2(NHs)(NCS))CI (iv) (n3-C3Hs)Co(CO)2] (v) [Fe(diphos)(CO)sl in which diphos Ph2PCH2CH2PPh2 and Ph CsHs (10 marks) (i)/ The K for Fe(OH)4]2-is found to be higher than that found in (5 marks) Zn(OH)4]2-and [Cr(OHM. Explain . Cho and coworkers used the following ligand to react with cobalt. Predict how this ligand would bind...
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and [Fe(NH3)6][Cr(CN)] (c) [CoBr(NH3)sSO4 and [CrSO4(NH3)s]Br (d) [Co(NO2)(NH3)s]Cl2 and [Cr(ONO)(NH3)s] Cl2 (e) Both (b) and (c) Review your answer (CIRCLE): Are you (1) confident; (2) somewhat confident; or (3) unsure/guessing?
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and [Fe(NH3)6][Cr(CN)] (c) [CoBr(NH3)sSO4 and [CrSO4(NH3)s]Br (d) [Co(NO2)(NH3)s]Cl2 and [Cr(ONO)(NH3)s] Cl2 (e) Both (b) and (c) Review your answer (CIRCLE):...
Name the following metal complexes or complex ions: formula name [ZnF] (en)2] [ TiBrz(co)] [c: (OH)(NH3), )* x 6 ?
Consider the following reactions: [Co(NH3)4] * + 6[H,O] → [Co(H2O) lt + 6[NH]" [Co(NH3)6]2+ + 6[H2O]* $ [Co(H2O).]2+ +6[NH.] The first reaction proceeds over weeks (even when Kca= 1064) while the second reaction proceeds over seconds. Rationalize the difference in rates.
experiment on the synthesis of
trans-dichlorobis(ethylenediamine)cobalt(iii)chloride
8.0 POST LAB QUESTIONS 1. How will the Percentage Yield of your Product be affected if the product is a little damp when weighed? 2. Determine the Oxidation State and the Coordination Number of the Transition Metal lon in each of the following Complex lons: a) [Ni(H20).] b) [Mn(CN).* c) [CuCl] d) [Cr(NH3)* 3. Write a chemical equation representing what happens when each of the following water soluble Coordination Compounds dissolves in water. a)...
Nomenclature Coordinate Complexes | <Br< SCN < Cl< O=N-0 <F <OH <C:0-(oxalato) < 0,2-<H2O <SCN <NH; <en (H2NCH2CH2NH2) NO2 <CN <CO Formula Name # of lone de [Cr. (NH3)3 (+20)})( triamminetriaquachromium(III) chloride [Fe(NH3).](NO2) hexaammineiron (111) nitrate [pt leng (12232 dithicyanodi(ethylenediamine)platinum(IV) chloride [Co(C204)(CO)]* Owlbunyoleation contu) lon ammonium tetraiodicuprate(II) INHO), [LUIGI Ke[Fe(ONO).] [ Fel NH3)6] hexaammineiron(III) hexahydroxochromate(III) [Co(H2NCH2CH2NH3)4](SO4)3 | +r15 4+ hy • he ºlfa wine) ¢e bal} (1) v10a4e pentaaquahydroxoiron(III) ion [Fe(H2E), GH) +2. (NH4)[Ni(O2)2(H2O)2] ammunium cinquabiscova lato) nickelate CI) AN...
please do answer all the questions below. thank you
For each of the following complexes, draw the molecular structure and determine the effective atomic numbers. (i) Na[Fe(CN)s(NH3)3l (i) [Cr(H2O)2(NH3)2(en)]Cl (ii) [Co(o-phen)2(NHs)(NCS))CI (iv) (n3-C3Hs)Co(CO)2] (v) [Fe(diphos)(CO)sl in which diphos Ph2PCH2CH2PPh2 and Ph CsHs (10 marks) (i)/ The K for Fe(OH)4]2-is found to be higher than that found in (5 marks) Zn(OH)4]2-and [Cr(OHM. Explain . Cho and coworkers used the following ligand to react with cobalt. Predict how this ligand would bind...
What is the coordination number for each of the following
complexes or compounds?
[Co(NH3)4Cl2]+
[Ca(EDTA)]2−
[Pt(NH3)4]2+
Na[Ag(CN)2]
Enter the coordination numbers, in the order that the complexes
are listed, as four integers separated by commas (e.g.,
1,2,3,4).
What is the charge on each of the following complex ions?
hexaaquairon(II), [Fe(H2O)6]?
tris(carbonato)aluminate(III), [Al(CO3)3]?
amminepentachloroplatinate(IV), [Pt(NH3)Cl5]?
Express the charges numerically, in the order that the complexes
are listed, separated by commas. For a nonzero charge, be sure to
include the sign (e.g.,...
can
anyone confirm my answers for all of 2 and all of 4?
1. Name following coordination complexes. (a) K][PdC1] (b) [Co(H2O),(NH3)4]2+ (b) [Mn(NH3),(En)]2+ (c) [CrCl,(NH3)4]CI, 2. State the coordination number and oxidation state of the following catalysts. (a) [Pt(CO) PPhz] (b) [Ni(C1).]2- (c) [Ir(Cl) (CO)En(PPhz)2]3+ (d)Liz[AuClo] 3. Define the following. (a) Ligand (b) Coordination number (c) Polydentate ligand (d) Primary valency 4. Write the formula of following coordination complexes. (a) Tris(ethylenediammine)cobalt(III) nitrate (b) Hexacyanomolybdate(II) (c) Tetrahydroxocuprate(II) (d) Sodium dibromidodichloridonickelate
1. (a) Give the systematic IUPAC names for each of the following complexes/ions (1) (NH4) [NiCl4] (ii) [Cr(H204(NH3)2]2+ (iii) [Ru(en)(OH)2]* (iv) Nas[Co(ONO)5] (v) [Rh(ONO)(OX)2]* (vi) [FeBrz(en)2]* (vii) [Ag(y)][AgCl4] (viii) K[Pt(ONO)3(NO2)3] (ix) [Co(SO4)(NH3)s]* (x) Naz[PdCl4]
please do answer all the questions below. thank you
For each of the following complexes, draw the molecular structure and determine the effective atomic numbers. (i) Na[Fe(CN)s(NH3)3l (i) [Cr(H2O)2(NH3)2(en)]Cl (ii) [Co(o-phen)2(NHs)(NCS))CI (iv) (n3-C3Hs)Co(CO)2] (v) [Fe(diphos)(CO)sl in which diphos Ph2PCH2CH2PPh2 and Ph CsHs (10 marks) (i)/ The K for Fe(OH)4]2-is found to be higher than that found in (5 marks) Zn(OH)4]2-and [Cr(OHM. Explain . Cho and coworkers used the following ligand to react with cobalt. Predict how this ligand would bind...
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