1. (a) Give the systematic IUPAC names for each of the following complexes/ions (1) (NH4) [NiCl4]...
Nomenclature Coordinate Complexes | <Br< SCN < Cl< O=N-0 <F <OH <C:0-(oxalato) < 0,2-<H2O <SCN <NH; <en (H2NCH2CH2NH2) NO2 <CN <CO Formula Name # of lone de [Cr. (NH3)3 (+20)})( triamminetriaquachromium(III) chloride [Fe(NH3).](NO2) hexaammineiron (111) nitrate [pt leng (12232 dithicyanodi(ethylenediamine)platinum(IV) chloride [Co(C204)(CO)]* Owlbunyoleation contu) lon ammonium tetraiodicuprate(II) INHO), [LUIGI Ke[Fe(ONO).] [ Fel NH3)6] hexaammineiron(III) hexahydroxochromate(III) [Co(H2NCH2CH2NH3)4](SO4)3 | +r15 4+ hy • he ºlfa wine) ¢e bal} (1) v10a4e pentaaquahydroxoiron(III) ion [Fe(H2E), GH) +2. (NH4)[Ni(O2)2(H2O)2] ammunium cinquabiscova lato) nickelate CI) AN...
2. Give a systematic name for each of the following compounds, and give the number of d electrons for the transition metal: a. Cs2[FeCl4] b. W(CO)6 c. Na2[Cr(CO)5] d. [Ni(NH3)2(en)2](PF6)2 (PF6 is a (1-) ion, and is named as if phosphorus were a metal) e. [Ru(CN)6]3– f. K[OsF6]
1. Name the following transition metal complexes AND give the coordination number for each metal in the complex ion: Name Coordination # (a) K[Fe(CN).] (b)Ks[Fe(ox).] (c) Cr(en).]C13 (d) (Cr(NH3):(HO)](NO3) (e)ky [Cr(NH3),Cla]
Please answer all of the following: a) Give the correct IUPAC name and sketch the structure of the transition metal complex for each of the following compounds. If multiple stereoisomers are possible, give both names and structures: 1) [Pt(NH3)2Cl2] 2) [Cr(NMe3)4Br2]PF6 3) K[Co(edta)], where H4(edta) = ethylenediaminetetraacetic acid 4) [Ir(CO)Cl(PPh3)2] 5) Hg[Co(NCO)4] 6) [Fe(acac)3], where H(acac) = acetylacetone 7) [Co(NH3)6]3+[Cr(CN)6]3- 8) [{Co(NH3)5}2(μ-OH)]Cl5 9) [TiCl3(thf)3], where thf = tetrahydrofuran 10) [Ru(bpy)2Cl2], where bpy = 2,2’-bipyridine 11) V(O)(acac)2, where H(acac) = acetylacetone...
2) Give systematic IUPAC names for each of the following; 4 points a) CI OH
3. Assign a systematic name to each of the following chemical compounds: (a) NH4[Cr(NH3)2(NCS)4] (b) [Tc(CO)s]I (c) K[Mn(CN)s] (d) [CO(NH3)4(OH2)Cl]Br2
4. Give chemical names for the following coordination complexes a) [Cu(NH3)4]**. b) [P (NH3)3Cs]" c) [Mn(CN) . d) (Co(en) (PPha).]PO4 e) [Ni(bipy))(NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(lll). c) Tris(acetylacetonato)iron(III). d) Tri--carbonylbis(tricarbonyliron(0)). e) #-oxo-bis(pentaamminechromium(III)).
1. Give systematic IUPAC names for each of the following: CH3CH2C(CH3)2CH(CH2CH3)CH3 CH3C(CH3)CH2 CH2O CH3CH(NH2)CH3 CH3OCH2CH2CH3 CH(CH3)2COOH For the list above I currently put the following as the IUPAC names. If any are wrong can you please correct them! Give systematic IUPAC names for each of the following: CH3CH2C(CH3)2CH(CH2CH3)CH3 IUPAC Name: 3,3,4-trimethylhexane IUPAC Name: 3-methyl-4-ol-heptane CH3C(CH3)CH2 IUPAC Name: 2-methylpropene CH2O IUPAC Name: methanal CH3CH(NH2)CH3 IUPAC Name: isopropylamine CH3OCH2CH2CH3 IUPAC Name: methoxyethane (ethyl methyl ether) CH(CH3)2COOH IUPAC Name: 2-methylpropanoic acid
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...