1. What is the major product of the following sequence of reactions? a. 1. Li 1....
Are these right? 18.-22. Starting with benzene, what is the major product of each reaction sequence? Answer may be repeated. 18. /AICI3, Cl2/Fecla, H2NNH2/ OH 19. Cl2/Fecla, /AICI b. 20 /AICI 3, HS (CH2)2SH/H", H2/Ni, cl2/Fecl3 21. HNO3/ H2SO4, /AICI 3, H2/Pd, NaNO2/HCI, Cuc 22. /AICI3, Zn/HCI, H2SO4, Cl2/FeCla, H20 e. not a.-d.
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) qichs). 11. -Н БРОН baoн Ысмин 1) Phcci, АІСІ, Combonuga e eдoldee ca 2) EtNH, H2, Raney-Ni, heat - расидонорые до ÇO Me 12. лесно 1) EtMgBr (2 equiv.) Pronta cowbong 2) H20, H,0* C сенин Ысник | SHO 13. CNH21) Bra, NaOH, H2O о існсненин 2) (CH3)2CHCCI, pour de plano pyridine D) Бензин CHO 14. Кsus-и HO EH н+он...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 o 11. 1) PhČCI, AICI 2) EtANH, H2, Raney-Ni, heat 12. ÇO Me 1) EtMgBr (2 equiv.) 2) H20, H30* 13. o CNH2 1) Brą, NaOH, H20 o 2) (CH3)2CHCCI, pyridine 14. CHO HO+H H-OH Br2, H20 H-HOH HO+H CH2OH
What reagent would best accomplish the following transformation? H3CO ل H3CO DA H2NNH2, KOH, H20 B. H2, Pd LiAIH4 D. Zn(Hg), HCI
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) o 11. Ç(CH3)3 1) CH3CCI, AICI: 2) (CH3)2NH H2, Raney-Ni, heat 12. CO2Me 1) PhMgBr (2 equiv.) 2) H20, H30+ O 13. CNH2 1) Brą, NaOH, H20 o 2) CH3CCI, pyridine 14. HNO3 CHO HOEH НЕОН H OH HO+H CH2OH 4
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 11. 1) PhČCI, AICI 2) EtNH, H2, Raney-Ni, heat 12. ço Me 1) EtMgBr (2 equiv.) 2) H20, H30*
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 0 11. 1) PhCCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. co Me 1) EtMgBr (2 equiv.) 2) H2O, H30* 13. o CNH, 1) Bra, NaOH, HẠO o 2) (CH3)CHČCI, pyridine 14. CHO Но+н HTOH Br2, H20 н+ОН НО-НН CH OH 4
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 0 11. 1) PhCCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. co Me 1) EtMgBr (2 equiv.) 2) H2O, H30* 13. o CNH, 1) Bra, NaOH, HẠO o 2) (CH3)CHČCI, pyridine 14. CHO Но+н HTOH Br2, H20 н+ОН НО-НН CH OH 4
II. Draw the structure for the major organic product of each of the following reactions. 11. Ç(CH3) 30 1) PhČCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. ÇO2Me 1) EtMgBr (2 equiv.) 2) H20, H30+ 13. o CNH2 1) Br2, NaOH, H20 O 2) (CH3)2CHČCI, pyridine 14. Br2, H20 CHO HOEH H -OH H-OH HOEH CH2OH